Preparation of nanometer FeCuP alloy and its application in decomposition of PH3

Chang Xiu Han Ji Li Ren Xue Jiao Tang Bao Gui Zhang

引用本文: Chang Xiu Han,  Ji Li Ren,  Xue Jiao Tang,  Bao Gui Zhang. Preparation of nanometer FeCuP alloy and its application in decomposition of PH3[J]. Chinese Chemical Letters, 2007, 18(10): 1285-1288. doi: 10.1016/j.cclet.2007.08.005 shu
Citation:  Chang Xiu Han,  Ji Li Ren,  Xue Jiao Tang,  Bao Gui Zhang. Preparation of nanometer FeCuP alloy and its application in decomposition of PH3[J]. Chinese Chemical Letters, 2007, 18(10): 1285-1288. doi: 10.1016/j.cclet.2007.08.005 shu

Preparation of nanometer FeCuP alloy and its application in decomposition of PH3

  • 基金项目:

    This work was supported by the Tianjin Natural Science Foundation (No.043801311).

摘要: A new ternary Fe-based alloy catalyst FeCuP applied to decompose PH3 was prepared with low-cost material by chemical reduction deposition method. The properties of it were characterized by XRD, ICP and SEM. Its catalytic activity on the decomposition of PH3 and the decomposition conditions were studied. FeCuP alloy exhibits high thermal stabilities and high catalytic activity. Using it as catalyst, the decomposition temperature of phosphine decreases from over 800℃ to 400-500℃. The decomposition rate of phosphine achieved 100%.

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  • 收稿日期:  2007-03-13
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