引用本文:
Juan Li, Song Lin Zhang, Chuan Zhou Tao, Yao Fu, Qing Xiang Guo. Cu-catalyzed arylation of phosphinic amide facilitated by (±)-trans-cyclohexane-1,2-diamine[J]. Chinese Chemical Letters,
2007, 18(9): 1033-1036.
doi:
10.1016/j.cclet.2007.07.028
Citation: Juan Li, Song Lin Zhang, Chuan Zhou Tao, Yao Fu, Qing Xiang Guo. Cu-catalyzed arylation of phosphinic amide facilitated by (±)-trans-cyclohexane-1,2-diamine[J]. Chinese Chemical Letters, 2007, 18(9): 1033-1036. doi: 10.1016/j.cclet.2007.07.028
Citation: Juan Li, Song Lin Zhang, Chuan Zhou Tao, Yao Fu, Qing Xiang Guo. Cu-catalyzed arylation of phosphinic amide facilitated by (±)-trans-cyclohexane-1,2-diamine[J]. Chinese Chemical Letters, 2007, 18(9): 1033-1036. doi: 10.1016/j.cclet.2007.07.028
Cu-catalyzed arylation of phosphinic amide facilitated by (±)-trans-cyclohexane-1,2-diamine
摘要:
Cu-catalyzed cross coupling between phosphinic amides and aryl halides was accomplished for the first time by using (±)-trans-cyclohexane-1, 2-diamine as the ligand. This reaction provided a novel approach for synthesizing arylated phosphinic amides. Both kinetic measurement and theoretical calculation indicated that phosphinic amides were much less reactive than amides by about 10times in Cu-catalyzed cross coupling.
-
关键词:
- Phosphinic amide
- / Copper
- / Catalyst
- / Cross coupling
English
Cu-catalyzed arylation of phosphinic amide facilitated by (±)-trans-cyclohexane-1,2-diamine
Abstract:
Cu-catalyzed cross coupling between phosphinic amides and aryl halides was accomplished for the first time by using (±)-trans-cyclohexane-1, 2-diamine as the ligand. This reaction provided a novel approach for synthesizing arylated phosphinic amides. Both kinetic measurement and theoretical calculation indicated that phosphinic amides were much less reactive than amides by about 10times in Cu-catalyzed cross coupling.
-
Key words:
- Phosphinic amide
- / Copper
- / Catalyst
- / Cross coupling
扫一扫看文章
计量
- PDF下载量: 1
- 文章访问数: 1451
- HTML全文浏览量: 38
下载:
