引用本文:
Xiao Tong Li, Sheng Hua Li, Si Ping Pang, Yong Zhong Yu, Yun Jun Luo. A new efficient route for the synthesis of 4,4',6,6'-tetra (azido) azo-1,3,5-triazine[J]. Chinese Chemical Letters,
2007, 18(9): 1037-1039.
doi:
10.1016/j.cclet.2007.06.028
Citation: Xiao Tong Li, Sheng Hua Li, Si Ping Pang, Yong Zhong Yu, Yun Jun Luo. A new efficient route for the synthesis of 4,4',6,6'-tetra (azido) azo-1,3,5-triazine[J]. Chinese Chemical Letters, 2007, 18(9): 1037-1039. doi: 10.1016/j.cclet.2007.06.028
Citation: Xiao Tong Li, Sheng Hua Li, Si Ping Pang, Yong Zhong Yu, Yun Jun Luo. A new efficient route for the synthesis of 4,4',6,6'-tetra (azido) azo-1,3,5-triazine[J]. Chinese Chemical Letters, 2007, 18(9): 1037-1039. doi: 10.1016/j.cclet.2007.06.028
A new efficient route for the synthesis of 4,4',6,6'-tetra (azido) azo-1,3,5-triazine
摘要:
A new method for the synthesis of 4, 4', 6, 6'-tetra (azido) azo-1, 3, 5-triazine (TAAT) is described. The key intermediate 4, 4', 6, 6'-tetra (azido) hydrazo-1, 3, 5-triazine (THAT) was synthesized by nucleophilic substitution in the case of sodium azide as nucleophile. N-Bromosuccinide (NBS) was used as oxidant to oxidize THAT by a tractable operation under mild reaction condition. The target compound TAAT was obtained with a facile process and high overall yield of 81%. The structures of TAAT and its intermediates were identified by spectroscopic methods.
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关键词:
- High-nitrogen compounds
- / Azide
- / Triazine
- / Synthesis
English
A new efficient route for the synthesis of 4,4',6,6'-tetra (azido) azo-1,3,5-triazine
Abstract:
A new method for the synthesis of 4, 4', 6, 6'-tetra (azido) azo-1, 3, 5-triazine (TAAT) is described. The key intermediate 4, 4', 6, 6'-tetra (azido) hydrazo-1, 3, 5-triazine (THAT) was synthesized by nucleophilic substitution in the case of sodium azide as nucleophile. N-Bromosuccinide (NBS) was used as oxidant to oxidize THAT by a tractable operation under mild reaction condition. The target compound TAAT was obtained with a facile process and high overall yield of 81%. The structures of TAAT and its intermediates were identified by spectroscopic methods.
-
Key words:
- High-nitrogen compounds
- / Azide
- / Triazine
- / Synthesis
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