引用本文:
Jun Wang, Zhi Yong Chen, Mei Ping Zhao, Yuan Zong Li. Catalytical oxidation of styrene by molecularly imprinted polymer with phenylacetic acid as template and hemin as co-monomer[J]. Chinese Chemical Letters,
2007, 18(8): 981-984.
doi:
10.1016/j.cclet.2007.06.009
Citation: Jun Wang, Zhi Yong Chen, Mei Ping Zhao, Yuan Zong Li. Catalytical oxidation of styrene by molecularly imprinted polymer with phenylacetic acid as template and hemin as co-monomer[J]. Chinese Chemical Letters, 2007, 18(8): 981-984. doi: 10.1016/j.cclet.2007.06.009
Citation: Jun Wang, Zhi Yong Chen, Mei Ping Zhao, Yuan Zong Li. Catalytical oxidation of styrene by molecularly imprinted polymer with phenylacetic acid as template and hemin as co-monomer[J]. Chinese Chemical Letters, 2007, 18(8): 981-984. doi: 10.1016/j.cclet.2007.06.009
Catalytical oxidation of styrene by molecularly imprinted polymer with phenylacetic acid as template and hemin as co-monomer
摘要:
This letter used the molecular imprinting technology to build up the microenvironment around co-monomer hemin to mimic the cytochrome P450 catalyzing the epoxidation of styrene. The results showed that the conversion rates of products were obviously enhanced by molecularly imprinted polymers, compared to free hemin solution, using three kinds of oxidants. The used axial ligand in polymers synthesis also improved the total conversion rates.
English
Catalytical oxidation of styrene by molecularly imprinted polymer with phenylacetic acid as template and hemin as co-monomer
Abstract:
This letter used the molecular imprinting technology to build up the microenvironment around co-monomer hemin to mimic the cytochrome P450 catalyzing the epoxidation of styrene. The results showed that the conversion rates of products were obviously enhanced by molecularly imprinted polymers, compared to free hemin solution, using three kinds of oxidants. The used axial ligand in polymers synthesis also improved the total conversion rates.
-
Key words:
- Molecularly imprinted polymers
- / Enzyme mimic
- / Cytochrome P450
- / Styrene
- / Epoxidation
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 778
- HTML全文浏览量: 23
下载:
