Citation: Yi Xu, Shi Lei Zhang, Wen Hu Duan. A new radical way to N, N-dimethylaniline hydroperoxide (DMAHP) and its application in organic synthesis[J]. Chinese Chemical Letters, ;2007, 18(7): 807-810. doi: 10.1016/j.cclet.2007.05.036 shu

A new radical way to N, N-dimethylaniline hydroperoxide (DMAHP) and its application in organic synthesis

Shanghai Institute of Materia Medica, Shanghai Institutes of Biological Sciences, Chinese Academy of Sciences, Graduate School of the Chinese Academy of Sciences, Shanghai 201203, China

Received Date: 26 February 2007

Fund Project: We are grateful to Shanghai Science and Technology Commission (No. 06JC14080) for financial support of this work.

N, N-Dimethylaniline hydroperoxide was obtained when treating N, N-dimethylaniline with NHPI/Co(OAc)₂/O₂ via a radical reaction mechanism. This intermediate has potential application in the synthesis of some important chemical scaffolds.
- Aerobic oxidation,
- NHPI,
- N, N-Dimethylaniline
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