引用本文:
Pei Ming Gu, Yu Ming Zhao, Yong Qiang Tu, Min Wang, Shu Yu Zhang. An alternative synthetic approach towards erythrinan and homoerythrinan alkaloids by tandem semipinacol/intramolecular Schmidt reaction[J]. Chinese Chemical Letters,
2007, 18(8): 917-919.
doi:
10.1016/j.cclet.2007.05.029
Citation: Pei Ming Gu, Yu Ming Zhao, Yong Qiang Tu, Min Wang, Shu Yu Zhang. An alternative synthetic approach towards erythrinan and homoerythrinan alkaloids by tandem semipinacol/intramolecular Schmidt reaction[J]. Chinese Chemical Letters, 2007, 18(8): 917-919. doi: 10.1016/j.cclet.2007.05.029
Citation: Pei Ming Gu, Yu Ming Zhao, Yong Qiang Tu, Min Wang, Shu Yu Zhang. An alternative synthetic approach towards erythrinan and homoerythrinan alkaloids by tandem semipinacol/intramolecular Schmidt reaction[J]. Chinese Chemical Letters, 2007, 18(8): 917-919. doi: 10.1016/j.cclet.2007.05.029
An alternative synthetic approach towards erythrinan and homoerythrinan alkaloids by tandem semipinacol/intramolecular Schmidt reaction
摘要:
An alternative construction of A-B-D ting-system of erythrinan and homoerythrinan alkaloids by TiCl4-mediated tandem semipinacol/intramolecular Schmidt reaction of α-siloxyepoxyazide was addressed and the unusual epoxidation stereoselectivity was observed in preparation of the substrate once again.
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关键词:
- Tandem
- / Intramolecular Schmidt reaction
- / Semipinacol
- / Alkaloid
English
An alternative synthetic approach towards erythrinan and homoerythrinan alkaloids by tandem semipinacol/intramolecular Schmidt reaction
Abstract:
An alternative construction of A-B-D ting-system of erythrinan and homoerythrinan alkaloids by TiCl4-mediated tandem semipinacol/intramolecular Schmidt reaction of α-siloxyepoxyazide was addressed and the unusual epoxidation stereoselectivity was observed in preparation of the substrate once again.
-
Key words:
- Tandem
- / Intramolecular Schmidt reaction
- / Semipinacol
- / Alkaloid
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