Citation: Hong Wei Wang, Ying Ping Jia, Da Bin Gao, Jing Mei Yin, Guang Yun Zhou, Shen Min Li. Photo-promoted carbonylation of chloroalkanes with carbon monoxide by non-precious metal catalysts[J]. Chinese Chemical Letters, ;2007, 18(7): 795-798. doi: 10.1016/j.cclet.2007.05.012 shu

Photo-promoted carbonylation of chloroalkanes with carbon monoxide by non-precious metal catalysts

Liaoning Key Laboratory of Bio-Organic Chemistry, Dalian University, Dalian 116622, China

Received Date: 4 January 2007

Fund Project: We appreciate the National Natural Science Foundation of China (No. 20372012) for the generous financial support.

The photo-promoted carbonylation of chloroalkanes with carbon monoxide was carried out under ambient conditions with copper and cadmium salts catalysts. The results indicated that the corresponding esters were produced with three salt catalysts, i.e. CuBr₂, CuCl₂ and CdI₂. Among these catalysts, CdI₂ was the most efficient in terms of ester yield and selectivity, particularly, 60% yield and 75% selectivity in the carbonylation of chlorocyclohexane were achieved. Furthermore, the yield and selectivity of the ester can be improved greatly by adding tri-n-butylamine in the CuBr₂ and CuCl₂ catalyst systems. On the other hand, the additive. As a result, we suggest that iodide ion plays an important role in the catalyst system of the cadmium salts.
- Cadmium salts,
- Copper salts,
- Chloroalkanes,
- Photo-promoted carbonylation
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