Citation: Min Wang, Zhi Guo Song, Hong Gong, Heng Jiang. Copper methanesulfonate-acetic acid as a novel catalytic system for tetrahydropyranylation of alcohols and phenols[J]. Chinese Chemical Letters, ;2007, 18(7): 799-802. doi: 10.1016/j.cclet.2007.05.001 shu

Copper methanesulfonate-acetic acid as a novel catalytic system for tetrahydropyranylation of alcohols and phenols

a College of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121000, China;
b Center for Science & Technology Experiment, Bohai University, Jinzhou 121000, China;
c School of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China

Received Date: 22 December 2006

A synergistic catalytic effect between copper methanesulfonate and acetic acid in tetrahydropyranylation of alcohols and phenol at room temperature under solvent free condition has been described. Both alcohols (primary, secondary and tertiary) and phenols reacted with 3, 4-dihydro-2H-pyran smoothly to afford the corresponding tetrahydropyranyl ethers in good yields.
- Tetrahydropyranylation,
- Synergistic effect,
- Copper methanesulfonate,
- Acetic acid
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