引用本文:
Hai Yan Wang, Da Xiong Han. A new method of immobilizing ionic liquids into layered zirconium phosphates[J]. Chinese Chemical Letters,
2007, 18(6): 764-767.
doi:
10.1016/j.cclet.2007.04.021
Citation: Hai Yan Wang, Da Xiong Han. A new method of immobilizing ionic liquids into layered zirconium phosphates[J]. Chinese Chemical Letters, 2007, 18(6): 764-767. doi: 10.1016/j.cclet.2007.04.021
Citation: Hai Yan Wang, Da Xiong Han. A new method of immobilizing ionic liquids into layered zirconium phosphates[J]. Chinese Chemical Letters, 2007, 18(6): 764-767. doi: 10.1016/j.cclet.2007.04.021
A new method of immobilizing ionic liquids into layered zirconium phosphates
摘要:
In this work, a new method of a series of ion liquids (ILs) l-alkyl-3-methylimidazolium chloride[Cnmim]Cl (n=2, 4, 6, 8) intercalation into layered zirconium phosphates was investigated.It was found that the α-ZrP-2BA (i.e.pre-intercalated BA was arranged in a bilayer mode in the galleries ofα-ZrP) was a suitable host for intercalation ILs:ILs was inserted through exchanging pre-intercalated BA.And the intercalation orientation was investigated by use of X-ray diffraction (XRD) experiments and molecular modeling calculation.
English
A new method of immobilizing ionic liquids into layered zirconium phosphates
Abstract:
In this work, a new method of a series of ion liquids (ILs) l-alkyl-3-methylimidazolium chloride[Cnmim]Cl (n=2, 4, 6, 8) intercalation into layered zirconium phosphates was investigated.It was found that the α-ZrP-2BA (i.e.pre-intercalated BA was arranged in a bilayer mode in the galleries ofα-ZrP) was a suitable host for intercalation ILs:ILs was inserted through exchanging pre-intercalated BA.And the intercalation orientation was investigated by use of X-ray diffraction (XRD) experiments and molecular modeling calculation.
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Key words:
- Ionic liquids
- / Zirconium phosphates
- / Intercalation
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