Citation: Yu Chuan Li, Si Ping Pang, Yong Zhong Yu. Studies on the cyclization reaction of D-aspartic acid[J]. Chinese Chemical Letters, ;2007, 18(5): 516-518. doi: 10.1016/j.cclet.2007.03.013 shu

Studies on the cyclization reaction of D-aspartic acid

School of Life Science and Technology, Beijing Institute of Technology, Beijing 100083, China

Received Date: 8 December 2006

Fund Project: This work is supported by the National Natural Science Foundation of China (No. 20442004 10576002)

The cyclization reaction of D-aspartic acid was studied, the carboxyl groups of D-aspartic acid were protected by benzyl alcohol to give compound D-dibenzyl aspartate. Then (4R)-benzyl azetidine-2-one-4-carboxylate and meso-3, 6-disubstituted piperazine2, 5-diones were synthesized via intramolecular cyclization and intermolecular cyclization of D-dibenzyl aspartate, respectively, and their structures were confirmed by ¹H NMR and MS. Both cyclization reaction conditions were also investigated in detail.
- D-Aspartic acid,
- Cyclization reaction,
- Azetidine-2-ones,
- 3, 6-Disubstituted piperazine-2, 5-diones
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