Citation: Shou Ri Sheng, Ming Gang Hu, Qin Xin, Xiao Ling Liu, Xian Huang. Solid-phase synthesis of (Z)-allyl iodides from 3-acetoxy-2-methylene-alkanoates with recyclable polymer-supported selenium bromide[J]. Chinese Chemical Letters, ;2007, 18(4): 377-379. doi: 10.1016/j.cclet.2007.01.045 shu

Solid-phase synthesis of (Z)-allyl iodides from 3-acetoxy-2-methylene-alkanoates with recyclable polymer-supported selenium bromide

a College of Chemistry and Chemical Engineering, Jiangxi Normal University, 330027 Nanchang, China;
b Department of Chemistry, Zhejiang University, Xixi Campus, 310028 Hangzhou, China

Fund Project: We thank the National Natural Science Foundation of China (No. 20562005) and NSF of Jiangxi Province (No. 0620021) for financial support.

Reaction of polystyrene-supported lithium selenide with 3-acetoxy-2-methylene-aikanoates afforded the corresponding allyl selenide resins and subsequent cleavage from the polymer by treating with methyl iodide to furnish (Z)-allyl iodides in good yields and high purities. The polymeric selenium reagent can be regenerated and reused. So it is a environmentally benign reagent.
- Solid phase organic synthesis,
- Polystyrene-supported selenium bromide,
- (Z)-Allyl iodide
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