Non-oxidative aromatization of C1 to C3 hydrocarbons over Pd-promoted Ga/HZSM-5 catalyst under mild conditions

Xiao Chun Shen Hui Lou Kai Hu Xiao Ming Zheng

引用本文: Xiao Chun Shen,  Hui Lou,  Kai Hu,  Xiao Ming Zheng. Non-oxidative aromatization of C1 to C3 hydrocarbons over Pd-promoted Ga/HZSM-5 catalyst under mild conditions[J]. Chinese Chemical Letters, 2007, 18(4): 479-482. doi: 10.1016/j.cclet.2007.01.044 shu
Citation:  Xiao Chun Shen,  Hui Lou,  Kai Hu,  Xiao Ming Zheng. Non-oxidative aromatization of C1 to C3 hydrocarbons over Pd-promoted Ga/HZSM-5 catalyst under mild conditions[J]. Chinese Chemical Letters, 2007, 18(4): 479-482. doi: 10.1016/j.cclet.2007.01.044 shu

Non-oxidative aromatization of C1 to C3 hydrocarbons over Pd-promoted Ga/HZSM-5 catalyst under mild conditions

  • 基金项目:

    Financial supports from the National Natural Science Foundation of China (No. 20343002,20433030) and from PetroChina are gratefully acknowledged.

摘要: The Pd-promoted Ga/HZSM-5 catalyst was prepared by impregnation method and its catalytic activity for non-oxidative aromatization of C1 to C3 hydrocarbons was assessed using a microreactor-GC system operated with temperature at 823 K and space velocity at 410 h-1. The catalyst is more catalytically active for methane conversion than Ga/HZSM-5. The mass spectroscopy analyses confirmed that 13CH4 was converted to aromatic products.

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  • 收稿日期:  2006-10-16
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