Citation: Xue Song Chen, Shi Jun Da, Li Hong Yang, Bo Yan Xu, Zhi Xiang Xie, Ying Li. A new convenient asymmetric approach to herbarumin Ⅲ[J]. Chinese Chemical Letters, ;2007, 18(3): 255-257. doi: 10.1016/j.cclet.2007.01.035 shu

A new convenient asymmetric approach to herbarumin Ⅲ

The State Key Laboratory of Applied Organic Chemistry, Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000, China

Received Date: 6 November 2006

Fund Project: The project was supported by the National Natural Science Foundation of China (No. 20672050).

The asymmetric total synthesis of herbarumin Ⅲ 3, a naturally occurred phytotoxin, along with 8-epi-herbarumin Ⅲ 22, was succeeded in 12 steps from n-butyraldehyde based on Brown's asymmetric allylation, taking modified Julia olefination and Yamaguchi's macro-lactonization as key steps.
- Herbarumin Ⅲ,
- Asymmetric allylation,
- Modified Julia olefination,
- Yamaguchi's macro-lactonization
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