Citation: Li Qiang Su, Shi Qiao, Wei Bing Zhang. Studies on the synthesis and properties of malachite green imprinted polymer[J]. Chinese Chemical Letters, ;2007, 18(2): 229-232. doi: 10.1016/j.cclet.2006.12.013 shu

Studies on the synthesis and properties of malachite green imprinted polymer

a College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, China;
b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012, China

Received Date: 14 September 2006

Fund Project: Thanks for the financial support from the National Basic Priorities Program "973" (No. 2001CB510202) and the National Natural Science Foundation of China (Nos. 20375040 and 0175029).

A new molecularly imprinted polymer was synthesized with malachite green (MG) as molecular template, methacrylic acid (MAA) as functional monomer, ethylene dimethacrylate (EDMA) as crosslinker, and azobisisobutyronitrile (AIBN) as initiator.Recognition properties of the MG imprinted polymer were studied by equilibrium adsorption and HPLC. The results showed that the imprinted polymer had good affinity and marked selectivity for MG, and can separate MG with its analogue commendably. The new polymer can be used for the enrichment of MG in complex sample, and can work as separation media to separate and detect MG by HPLC.
- Molecular imprinting,
- Malachite green,
- Functional monomer,
- HPLC
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