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Citation:
Yan Fei Liu, Ke Long Huang, Dong Ming Peng, Su Qin Liu, Hong Wu. Synthesis and properties of novel aliphatic polycarbonate from carbon dioxide with 1,2-butylene oxide and ε-caprolactone[J]. Chinese Chemical Letters,
;2007, 18(2): 209-212.
doi:
10.1016/j.cclet.2006.12.002
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A new degradable aliphatic poly(butylene-co-ε-caprolactone carbonate) (PBCL) was synthesized through the terpolymerization of carbon dioxide, 1,2-butylene oxide (BO) and ε-caprolactone (CL), a polymer supported bimetallic complex (PBM) was used as a catalyst. The terpolymers prepared were characterized by FT-IR, 1H NMR, 13C NMR, WXRD and DSC. The hydrolysis tests were carried out to appraise the degradability of the copolymers.
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Keywords:
- Terpolymerization,
- Aliphatic polycarbonate,
- Degradability
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