Citation: Hong Wei Yu, Qing Song Tong, Yi Ru Peng, Li Jia, Ji Cheng Shi, Zi Lin Jin. Preparation of polymer-supported phosphine from ferrocene for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions[J]. Chinese Chemical Letters, ;2007, 18(1): 37-40. doi: 10.1016/j.cclet.2006.11.030 shu

Preparation of polymer-supported phosphine from ferrocene for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions

Hong Wei Yu ^a,b, ,
Qing Song Tong ^c ,
Yi Ru Peng ^c ,
Li Jia ^c ,
Ji Cheng Shi ^b,c ,
Zi Lin Jin ^a

a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China;
b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
c College of Chemistry and Materials Science, Fujian Provincial Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou 350007, China

Received Date: 12 June 2006

Fund Project: This work was financially supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (DICP R200309), the National Basic Research Program of China (2003CB61615803), the National Natural Science Foundation of China (No. 20473089).

Polymer-supported phosphine ligand 3b derived from ferrocene was prepared, and applied in palladium-catalyzed Suzuki-Miyaura reactions. A range of aryl bromides can couple with phenylboronic acid to obtain corresponding biaryls in excellent yields.The recycling of the polymer-bound catalyst was tested without adding palladium.
- Immobilization,
- Palladium,
- Suzuki-Miyaura reaction,
- Biaryl,
- Catalysis
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