Citation: Zhen Feng Liu, Xian Fang Yue, Qiang Wei, Ke Li Han. Rh(Ⅱ) carbene S-H insertion into H₂S via the stepwise mechanism[J]. Chinese Chemical Letters, ;2007, 18(1): 107-110. doi: 10.1016/j.cclet.2006.11.012 shu

Rh(Ⅱ) carbene S-H insertion into H₂S via the stepwise mechanism

State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Received Date: 21 April 2006

The mechanism of Rh(Ⅱ) carbene S-H insertion into H₂S in gas phase has been studied by B3LYP functional. Calculation results showed that the Rh(Ⅱ) carbene S-H insertion into H₂S took only stepwise channels and no concerted channels had been located,which was different from the Rh(Ⅱ) carbene C-H and O-H insertions.
- Sulfonium ylides,
- 1,2-Hydrogen shift,
- Density functional calculations,
- Dirhodium(Ⅱ) carbene
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