WO3/In2S3 S型异质结中通过W-S键的界面电子转移增强光催化产H2O2

引用本文: 朱文君, 施锦, 张勇, 闫盼盼, 李猛, 别传彪. WO₃/In₂S₃ S型异质结中通过W-S键的界面电子转移增强光催化产H₂O₂[J]. 物理化学学报, 2026, 42(11): 100357. doi: 10.1016/j.actphy.2026.100357 shu

Citation: Wenjun Zhu, Jin Shi, Yong Zhang, Panpan Yan, Meng Li, Chuanbiao Bie. WO₃/In₂S₃ S型异质结中通过W-S键的界面电子转移增强光催化产H₂O₂[J]. Acta Physico-Chimica Sinica, 2026, 42(11): 100357. doi: 10.1016/j.actphy.2026.100357 shu

WO₃/In₂S₃ S型异质结中通过W-S键的界面电子转移增强光催化产H₂O₂

朱文君 ^1, ,
施锦 ^1, ,
张勇 ^1, ,
闫盼盼 ^2, ,
李猛 ^{3,
,} ,
别传彪 ^{2,
,}

1.
湖北理工学院新材料与绿色化工学院, 矿区环境污染控制与修复湖北省重点实验室, 湖北黄石 435003;
2.
中国地质大学太阳燃料实验室, 材料与化学学院, 湖北武汉 430078;
3.
南宁师范大学广西天然高分子化学与物理重点实验室, 广西壮族自治区南宁 530001

通讯作者: 李猛,E-mail:limeng_2016@126.com; 别传彪,E-mail:biechuanbiao@cug.edu.cn

基金项目:
本研究得到了湖北理工学院人才引进计划(编号：24xjz12R)；湖北省教育厅研究项目(编号：Q20244508)；湖北省自然科学基金创新发展联合基金黄石重点项目(编号：2025AFD004)；国家自然科学基金(项目批准号：22378103和52272290)；湖北省自然科学基金(编号：2025AFB492)以及中国地质大学(武汉)人才岗位科研启动经费资助(项目编号：2025097)的资助。

摘要: 梯型(S型)异质结因其独特的电荷转移机制以及最大化光生电子和空穴的氧化还原能力而脱颖而出，已被广泛用于应对日益严峻的能源危机和环境挑战。本文通过界面W-S配位键在多孔WO₃纳米纤维上生长In₂S₃纳米片，开发了无贵金属的WO₃/In₂S₃ S型异质结。在WO₃/In₂S₃异质界面形成的W-S键构建了快速电荷传输通道，加速了载流子分离，并促进了光催化H₂O₂的生成。优化后的WO₃/In₂S₃复合材料(WI-25)实现了1349.2 μmol g^-1 h^-1的优异光催化H₂O₂产率。原位辐照X射线光电子能谱(ISI-XPS)、偏态密度(PDOS)计算、电子顺磁共振(EPR)和飞秒瞬态吸收光谱(fs-TAS)共同验证了由界面配位键介导的S型电荷转移路径。本研究为构建具有界面配位键的S型异质结以提高光催化性能提供了一种合理策略。

关键词:

English

WO₃/In₂S₃ S型异质结中通过W-S键的界面电子转移增强光催化产H₂O₂

Wenjun Zhu ^1, ,
Jin Shi ^1, ,
Yong Zhang ^1, ,
Panpan Yan ^2, ,
Meng Li ^{3,
,} ,
Chuanbiao Bie ^{2,
,}

1.
School of Advanced Materials and Green Chemical Engineering, Hubei Key Laboratory of Mine Environmental Pollution Control & Remediation, Hubei Polytechnic University, Huangshi 435003, Hubei Province, China;
2.
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430078, Hubei Province, China;
3.
Guangxi Key Laboratory of Natural Polymer Chemistry and Physics, Nanning Normal University, Nanning 530001, Guangxi Zhuang Autonomous Region, China

Corresponding author: Meng Li, ; Chuanbiao Bie,

Received Date: 07 June 2026
Accepted Date: 02 July 2026
Revised Date: 27 June 2026

Abstract: 梯型(S型)异质结因其独特的电荷转移机制以及最大化光生电子和空穴的氧化还原能力而脱颖而出，已被广泛用于应对日益严峻的能源危机和环境挑战。本文通过界面W-S配位键在多孔WO₃纳米纤维上生长In₂S₃纳米片，开发了无贵金属的WO₃/In₂S₃ S型异质结。在WO₃/In₂S₃异质界面形成的W-S键构建了快速电荷传输通道，加速了载流子分离，并促进了光催化H₂O₂的生成。优化后的WO₃/In₂S₃复合材料(WI-25)实现了1349.2 μmol g^-1 h^-1的优异光催化H₂O₂产率。原位辐照X射线光电子能谱(ISI-XPS)、偏态密度(PDOS)计算、电子顺磁共振(EPR)和飞秒瞬态吸收光谱(fs-TAS)共同验证了由界面配位键介导的S型电荷转移路径。本研究为构建具有界面配位键的S型异质结以提高光催化性能提供了一种合理策略。

Key words:

1. [1]
  J. Song, C. Li, X. Zhang, P. Ma, K. Zheng, ACS Catal. 15(2025) 9058, https://doi.org/10.1021/acscatal.5c01609.J. Song, C. Li, X. Zhang, P. Ma, K. Zheng, ACS Catal. 15(2025) 9058, https://doi.org/10.1021/acscatal.5c01609.
2. [2]
  L. Wang, J. Zhao, J. Mater. Sci. Technol. 241(2026) 18, https://doi.org/10.1016/j.jmst.2025.04.009.L. Wang, J. Zhao, J. Mater. Sci. Technol. 241(2026) 18, https://doi.org/10.1016/j.jmst.2025.04.009.
3. [3]
  Z. Jiang, J. Zhang, B. Cheng, Y. Zhang, J. Yu, L. Zhang, Small 21(2025) 2409079, https://doi.org/10.1002/smll.202409079.Z. Jiang, J. Zhang, B. Cheng, Y. Zhang, J. Yu, L. Zhang, Small 21(2025) 2409079, https://doi.org/10.1002/smll.202409079.
4. [4]
  Y. Zhao, Y. Zhang, H. Tan, C. Ai, J. J. Materiomics 11(2025) 100970, https://doi.org/10.1016/j.jmat.2024.100970.Y. Zhao, Y. Zhang, H. Tan, C. Ai, J. J. Materiomics 11(2025) 100970, https://doi.org/10.1016/j.jmat.2024.100970.
5. [5]
  X. Li, Z. Wang, Acta Phys. Chim. Sin. 41(2025) 100080, https://doi.org/10.1016/j.actphy.2025.100080.X. Li, Z. Wang, Acta Phys. Chim. Sin. 41(2025) 100080, https://doi.org/10.1016/j.actphy.2025.100080.
6. [6]
  B. Liu, J. Zhang, H. Li, B. Cheng, C. Bie, Acta Phys. Chim. Sin. 41(2025) 100121, https://doi.org/10.1016/j.actphy.2025.100121.B. Liu, J. Zhang, H. Li, B. Cheng, C. Bie, Acta Phys. Chim. Sin. 41(2025) 100121, https://doi.org/10.1016/j.actphy.2025.100121.
7. [7]
  Y. Zhao, Y. Zhang, L. Wang, C. Ai, J. Zhang, J. Mater. Sci. Technol. 229(2025) 213, https://doi.org/10.1016/j.jmst.2024.12.040.Y. Zhao, Y. Zhang, L. Wang, C. Ai, J. Zhang, J. Mater. Sci. Technol. 229(2025) 213, https://doi.org/10.1016/j.jmst.2024.12.040.
8. [8]
  Y. Liu, M. Li, T. Liu, Z. Wu, L. Zhang, J. Mater. Sci. Technol. 233(2025) 201, https://doi.org/10.1016/j.jmst.2025.03.005.Y. Liu, M. Li, T. Liu, Z. Wu, L. Zhang, J. Mater. Sci. Technol. 233(2025) 201, https://doi.org/10.1016/j.jmst.2025.03.005.
9. [9]
  X. Zhou, S. Yang, X. Wang, Z. Wu, Y. Huo, J. Zhang, J. Mater. Sci. Technol. 234(2025) 60, https://doi.org/10.1016/j.jmst.2025.02.027.X. Zhou, S. Yang, X. Wang, Z. Wu, Y. Huo, J. Zhang, J. Mater. Sci. Technol. 234(2025) 60, https://doi.org/10.1016/j.jmst.2025.02.027.
10. [10]
  X. Zhou, C. Bie, X. Wang, Z. Wu, Y. Huo, J. Zhang, J. Yu, Appl. Catal. B 397(2026) 126930, https://doi.org/10.1016/j.apcatb.2026.126930.X. Zhou, C. Bie, X. Wang, Z. Wu, Y. Huo, J. Zhang, J. Yu, Appl. Catal. B 397(2026) 126930, https://doi.org/10.1016/j.apcatb.2026.126930.
11. [11]
  H. Hirakawa, S. Shiota, Y. Shiraishi, H. Sakamoto, S. Ichikawa, T. Hirai, ACS Catal. 6(2016) 4976, https://doi.org/10.1021/acscatal.6b01187.H. Hirakawa, S. Shiota, Y. Shiraishi, H. Sakamoto, S. Ichikawa, T. Hirai, ACS Catal. 6(2016) 4976, https://doi.org/10.1021/acscatal.6b01187.
12. [12]
  Q. Zhang, C. Dong, C. Xue, H. Che, K. Zhang, Y. Ao, Angew. Chem. Int. Ed. 64(2024) e202417591, https://doi.org/10.1002/anie.202417591.Q. Zhang, C. Dong, C. Xue, H. Che, K. Zhang, Y. Ao, Angew. Chem. Int. Ed. 64(2024) e202417591, https://doi.org/10.1002/anie.202417591.
13. [13]
  M. Sayed, H. Li, C. Bie, Acta Phys. Chim. Sin. 41(2025) 100117, https://doi.org/10.1016/j.actphy.2025.100117.M. Sayed, H. Li, C. Bie, Acta Phys. Chim. Sin. 41(2025) 100117, https://doi.org/10.1016/j.actphy.2025.100117.
14. [14]
  K. Meng, J. Zhang, B. Zhu, C. Jiang, H. García, J. Yu, Adv. Mater. 37(2025) 2505088, https://doi.org/10.1002/adma.202505088.K. Meng, J. Zhang, B. Zhu, C. Jiang, H. García, J. Yu, Adv. Mater. 37(2025) 2505088, https://doi.org/10.1002/adma.202505088.
15. [15]
  J. Li, Y. Huang, C. Zhao, K. Wang, Chin. J. Struct. Chem. 45(2026) 100869, https://doi.org/10.1016/j.cjsc.2026.100869.J. Li, Y. Huang, C. Zhao, K. Wang, Chin. J. Struct. Chem. 45(2026) 100869, https://doi.org/10.1016/j.cjsc.2026.100869.
16. [16]
  H. Qin, L. Wang, Y. Tang, W. Shi, C. Lu, Chin. J. Struct. Chem. 45(2026) 100858, https://doi.org/10.1016/j.cjsc.2025.100858.H. Qin, L. Wang, Y. Tang, W. Shi, C. Lu, Chin. J. Struct. Chem. 45(2026) 100858, https://doi.org/10.1016/j.cjsc.2025.100858.
17. [17]
  H. Toan, D. Nguyen, P. Phan, N. Anh, P. Ly, M. Pham, S. Hur, T. Ung, D. Bich, M. Nguyen, et al., ACS Appl. Mater. Interfaces 16(2024) 29421, https://doi.org/10.1021/acsami.4c04387.H. Toan, D. Nguyen, P. Phan, N. Anh, P. Ly, M. Pham, S. Hur, T. Ung, D. Bich, M. Nguyen, et al., ACS Appl. Mater. Interfaces 16(2024) 29421, https://doi.org/10.1021/acsami.4c04387.
18. [18]
  D. Sahoo, L. Paramanik, K. Das, A. Majhi, K. Parida, K. Parida, ACS Appl. Energy Mater. 9(2026) 657, https://doi.org/10.1021/acsaem.5c03464.D. Sahoo, L. Paramanik, K. Das, A. Majhi, K. Parida, K. Parida, ACS Appl. Energy Mater. 9(2026) 657, https://doi.org/10.1021/acsaem.5c03464.
19. [19]
  M. Malefane, M. Managa, T. Nkambule, A. Kuvarega, ChemSusChem 18(2025) e202401471, https://doi.org/10.1002/cssc.202401471.M. Malefane, M. Managa, T. Nkambule, A. Kuvarega, ChemSusChem 18(2025) e202401471, https://doi.org/10.1002/cssc.202401471.
20. [20]
  L. Biswal, D. Sahoo, U. Mohanty, K. Parida, Langmuir 41(2025) 23182, https://doi.org/10.1021/acs.langmuir.5c03086.L. Biswal, D. Sahoo, U. Mohanty, K. Parida, Langmuir 41(2025) 23182, https://doi.org/10.1021/acs.langmuir.5c03086.
21. [21]
  S. Mishra, V. Gadore, M. Ahmaruzzaman, Nano Energy 128(2024) 109820, https://doi.org/10.1016/j.nanoen.2024.109820.S. Mishra, V. Gadore, M. Ahmaruzzaman, Nano Energy 128(2024) 109820, https://doi.org/10.1016/j.nanoen.2024.109820.
22. [22]
  K. Xu, W. Zhu, M. Sayed, S. Han, Chin. J. Catal. 83(2026) 24, https://doi.org/10.1016/S1872-2067(26)64988-1.K. Xu, W. Zhu, M. Sayed, S. Han, Chin. J. Catal. 83(2026) 24, https://doi.org/10.1016/S1872-2067(26)64988-1.
23. [23]
  Y. Yang, B. Cheng, J. Yu, L. Wang, W. Ho, Nano Res. 16(2023) 4506, https://doi.org/10.1007/s12274-021-3733-0.Y. Yang, B. Cheng, J. Yu, L. Wang, W. Ho, Nano Res. 16(2023) 4506, https://doi.org/10.1007/s12274-021-3733-0.
24. [24]
  Q. Zhang, H. Miao, J. Wang, T. Sun, E. Liu, Chin. J. Catal. 63(2024) 176, https://doi.org/10.1016/S1872-2067(24)60077-X.Q. Zhang, H. Miao, J. Wang, T. Sun, E. Liu, Chin. J. Catal. 63(2024) 176, https://doi.org/10.1016/S1872-2067(24)60077-X.
25. [25]
  G. Liu, R. Chen, B. Xia, Z. Wu, S. Liu, A. Talebian-Kiakalaieh, J. Ran, Chin. J. Catal. 61(2024) 79, https://doi.org/10.1016/S1872-2067(24)60014-8.G. Liu, R. Chen, B. Xia, Z. Wu, S. Liu, A. Talebian-Kiakalaieh, J. Ran, Chin. J. Catal. 61(2024) 79, https://doi.org/10.1016/S1872-2067(24)60014-8.
26. [26]
  P. Shandilya, S. Sambyal, R. Sharma, P. Mandyal, B. Fang, J. Hazard. Mater. 428(2022) 128218, https://doi.org/10.1016/j.jhazmat.2022.128218.P. Shandilya, S. Sambyal, R. Sharma, P. Mandyal, B. Fang, J. Hazard. Mater. 428(2022) 128218, https://doi.org/10.1016/j.jhazmat.2022.128218.
27. [27]
  Z. Yang, S. Yang, H. Yang, J. Zhang, J. Yu, Small 21(2025) e08960, https://doi.org/10.1002/smll.202508960.Z. Yang, S. Yang, H. Yang, J. Zhang, J. Yu, Small 21(2025) e08960, https://doi.org/10.1002/smll.202508960.
28. [28]
  A. Dhakshinamoorthy, Z. Li, S. Yang, H. Garcia, Chem. Soc. Rev. 53(2024) 3002, https://doi.org/10.1039/D3CS00205E.A. Dhakshinamoorthy, Z. Li, S. Yang, H. Garcia, Chem. Soc. Rev. 53(2024) 3002, https://doi.org/10.1039/D3CS00205E.
29. [29]
  R. He, D. Xu, M. Sayed, J. Materiomics 11(2025) 100989, https://doi.org/10.1016/j.jmat.2024.100989.R. He, D. Xu, M. Sayed, J. Materiomics 11(2025) 100989, https://doi.org/10.1016/j.jmat.2024.100989.
30. [30]
  J. Liang, A. Labidi, B. Rhimi, N. Blidi, M. Padervand, D. Bahnemann, C. Wang, J. Energy Chem. 118(2026) 631, https://doi.org/10.1016/j.jechem.2026.03.048.J. Liang, A. Labidi, B. Rhimi, N. Blidi, M. Padervand, D. Bahnemann, C. Wang, J. Energy Chem. 118(2026) 631, https://doi.org/10.1016/j.jechem.2026.03.048.
31. [31]
  W. Hu, Y. Shi, J. Yu, H. Shi, Y. Huang, R. Li, Chin. J. Struct. Chem. 45(2026) 100832, https://doi.org/10.1016/j.cjsc.2025.100832.W. Hu, Y. Shi, J. Yu, H. Shi, Y. Huang, R. Li, Chin. J. Struct. Chem. 45(2026) 100832, https://doi.org/10.1016/j.cjsc.2025.100832.
32. [32]
  R. Manju, G. Masilamani, B. Neppolian, Chin. J. Struct. Chem. 45(2026) 100845, https://doi.org/10.1016/j.cjsc.2025.100845.R. Manju, G. Masilamani, B. Neppolian, Chin. J. Struct. Chem. 45(2026) 100845, https://doi.org/10.1016/j.cjsc.2025.100845.
33. [33]
  A. Meng, Z. Li, G. Xiong, Z. Li, J. Zhang, Chin. J. Struct. Chem. 45(2026) 100867, https://doi.org/10.1016/j.cjsc.2026.100867.A. Meng, Z. Li, G. Xiong, Z. Li, J. Zhang, Chin. J. Struct. Chem. 45(2026) 100867, https://doi.org/10.1016/j.cjsc.2026.100867.
34. [34]
  X. Wu, M. Sayed, G. Wang, W. Yu, B. Zhu, Adv. Mater. 38(2026) e11322, https://doi.org/10.1002/adma.202511322.X. Wu, M. Sayed, G. Wang, W. Yu, B. Zhu, Adv. Mater. 38(2026) e11322, https://doi.org/10.1002/adma.202511322.
35. [35]
  G. Tang, J. Zhang, C. Bie, X. Zheng, C. Jiang, J. Yu, Adv. Mater. 37(2025) e14576, https://doi.org/10.1002/adma.202514576.G. Tang, J. Zhang, C. Bie, X. Zheng, C. Jiang, J. Yu, Adv. Mater. 37(2025) e14576, https://doi.org/10.1002/adma.202514576.
36. [36]
  J. Sun, H. Liu, S. Wang, Y. Zhang, C. Bie, L. J. Materiomics 11(2025) 100975, https://doi.org/10.1016/j.jmat.2024.100975.J. Sun, H. Liu, S. Wang, Y. Zhang, C. Bie, L. J. Materiomics 11(2025) 100975, https://doi.org/10.1016/j.jmat.2024.100975.
37. [37]
  L. Zhang, J. Zhang, J. Yu, H. García, Nat. Rev. Chem. 9(2025) 328, https://doi.org/10.1038/s41570-025-00698-3.L. Zhang, J. Zhang, J. Yu, H. García, Nat. Rev. Chem. 9(2025) 328, https://doi.org/10.1038/s41570-025-00698-3.
38. [38]
  Y. Huo, X. Zhou, F. Zhao, C. Ai, Z. Wu, Z. Chang, B. Zhu, Acta Phys. Chim. Sin. 41(2025) 100148, https://doi.org/10.1016/j.actphy.2025.100148.Y. Huo, X. Zhou, F. Zhao, C. Ai, Z. Wu, Z. Chang, B. Zhu, Acta Phys. Chim. Sin. 41(2025) 100148, https://doi.org/10.1016/j.actphy.2025.100148.
39. [39]
  C. Jiang, C. Yuan, K. Xu, X. Zhou, C. Bie, J. Mater. Sci. Technol. 231(2025) 36, https://doi.org/10.1016/j.jmst.2024.12.071.C. Jiang, C. Yuan, K. Xu, X. Zhou, C. Bie, J. Mater. Sci. Technol. 231(2025) 36, https://doi.org/10.1016/j.jmst.2024.12.071.
40. [40]
  M. Sayed, K. Qi, X. Wu, L. Zhang, H. García, J. Yu, Chem. Soc. Rev. 54(2025) 4874, https://doi.org/10.1039/D4CS01091D.M. Sayed, K. Qi, X. Wu, L. Zhang, H. García, J. Yu, Chem. Soc. Rev. 54(2025) 4874, https://doi.org/10.1039/D4CS01091D.
41. [41]
  W. Yu, Chin. J. Catal. 73(2025) 8, https://doi.org/10.1016/S1872-2067(25)60706-1.W. Yu, Chin. J. Catal. 73(2025) 8, https://doi.org/10.1016/S1872-2067(25)60706-1.
42. [42]
  J. Qiu, K. Meng, Y. Zhang, B. Cheng, J. Zhang, L. Wang, J. Yu, Adv. Mater. 36(2024) 2400288, https://doi.org/10.1002/adma.202400288.J. Qiu, K. Meng, Y. Zhang, B. Cheng, J. Zhang, L. Wang, J. Yu, Adv. Mater. 36(2024) 2400288, https://doi.org/10.1002/adma.202400288.
43. [43]
  M. Li, X. Li, J. Ghasemi, Chin. J. Catal. 73(2025) 12, https://doi.org/10.1016/S1872-2067(25)64709-7.M. Li, X. Li, J. Ghasemi, Chin. J. Catal. 73(2025) 12, https://doi.org/10.1016/S1872-2067(25)64709-7.
44. [44]
  H. Liu, J. Peng, X. Zhang, K. Zheng, L. Zheng, K. Lv, Q. Li, P. Zhou, Chem. Eng. J. 504(2025) 504618, https://doi.org/10.1016/j.cej.2024.158618.H. Liu, J. Peng, X. Zhang, K. Zheng, L. Zheng, K. Lv, Q. Li, P. Zhou, Chem. Eng. J. 504(2025) 504618, https://doi.org/10.1016/j.cej.2024.158618.
45. [45]
  L. Zhang, Q. Shen, F. Huang, L. Jiang, J. Liu, J. Sheng, Y. Li, H. Yang, Appl. Surf. Sci. 608(2023) 155064, https://doi.org/10.1016/j.apsusc.2022.155064.L. Zhang, Q. Shen, F. Huang, L. Jiang, J. Liu, J. Sheng, Y. Li, H. Yang, Appl. Surf. Sci. 608(2023) 155064, https://doi.org/10.1016/j.apsusc.2022.155064.
46. [46]
  A. Meng, X. Wu, Z. Lu, M. Gu, W. Zhong, Y. Su, J. Yu, Angew. Chem. Int. Ed. 65(2026) e25871, https://doi.org/10.1002/anie.202525871.A. Meng, X. Wu, Z. Lu, M. Gu, W. Zhong, Y. Su, J. Yu, Angew. Chem. Int. Ed. 65(2026) e25871, https://doi.org/10.1002/anie.202525871.
47. [47]
  S. Zhang, Y. Wang, Z. Wang, L. Wang, C. An, D. Xu, Acta Phys. Chim. Sin. 41(2025) 100136, https://doi.org/10.1016/j.actphy.2025.100136.S. Zhang, Y. Wang, Z. Wang, L. Wang, C. An, D. Xu, Acta Phys. Chim. Sin. 41(2025) 100136, https://doi.org/10.1016/j.actphy.2025.100136.
48. [48]
  N. Dhenadhayalan, NPJ Clean Water 8(2025) 77, https://doi.org/10.1038/s41545-025-00469-z.N. Dhenadhayalan, NPJ Clean Water 8(2025) 77, https://doi.org/10.1038/s41545-025-00469-z.
49. [49]
  W. Zhu, C. Ai, K. Xu, Y. Zhou, X. Zhang, Y. Zhang, Acta Phys. Chim. Sin. 42(2026) 100184, https://doi.org/10.1016/j.actphy.2025.100184.W. Zhu, C. Ai, K. Xu, Y. Zhou, X. Zhang, Y. Zhang, Acta Phys. Chim. Sin. 42(2026) 100184, https://doi.org/10.1016/j.actphy.2025.100184.
50. [50]
  E. Alamoudi, A. Timoumi, Results Phys. 40(2022) 105858, https://doi.org/10.1016/j.rinp.2022.105858.E. Alamoudi, A. Timoumi, Results Phys. 40(2022) 105858, https://doi.org/10.1016/j.rinp.2022.105858.
51. [51]
  J. Singh, R. Soni, J. Kim, J. Alloy. Compd. 911(2022) 165099, https://doi.org/10.1016/j.jallcom.2022.165099.J. Singh, R. Soni, J. Kim, J. Alloy. Compd. 911(2022) 165099, https://doi.org/10.1016/j.jallcom.2022.165099.
52. [52]
  S. Zhang, C. Bie, Rare Met. 44(2025) 9289, https://doi.org/10.1007/s12598-025-03584-5.S. Zhang, C. Bie, Rare Met. 44(2025) 9289, https://doi.org/10.1007/s12598-025-03584-5.
53. [53]
  S. Cao, B. Zhong, C. Bie, B. Cheng, F. Xu, Acta Phys. Chim. Sin. 40(2024) 2307016, https://doi.org/10.3866/PKU.WHXB202307016.S. Cao, B. Zhong, C. Bie, B. Cheng, F. Xu, Acta Phys. Chim. Sin. 40(2024) 2307016, https://doi.org/10.3866/PKU.WHXB202307016.
54. [54]
  F. He, A. Meng, B. Cheng, W. Ho, J. Yu, Chin. J. Catal. 41(2020) 9, https://doi.org/10.1016/S1872-2067(19)63382-6.F. He, A. Meng, B. Cheng, W. Ho, J. Yu, Chin. J. Catal. 41(2020) 9, https://doi.org/10.1016/S1872-2067(19)63382-6.
55. [55]
  Y. Wang, J. Cai, M. Wu, J. Chen, W. Zhao, Y. Tian, T. Ding, J. Zhang, Z. Jiang, X. Li, Appl. Catal. B 239(2018) 398, https://doi.org/10.1016/j.apcatb.2018.08.029.Y. Wang, J. Cai, M. Wu, J. Chen, W. Zhao, Y. Tian, T. Ding, J. Zhang, Z. Jiang, X. Li, Appl. Catal. B 239(2018) 398, https://doi.org/10.1016/j.apcatb.2018.08.029.
56. [56]
  H. Liu, F. Zhang, H. Wang, J. Xue, Y. Guo, Q. Qian, G. Zhang, Energy Environ. Sci. 14(2021) 5339, https://doi.org/10.1039/D1EE01397A.H. Liu, F. Zhang, H. Wang, J. Xue, Y. Guo, Q. Qian, G. Zhang, Energy Environ. Sci. 14(2021) 5339, https://doi.org/10.1039/D1EE01397A.
57. [57]
  J. Cai, B. Liu, S. Zhang, L. Wang, Z. Wu, J. Zhang, B. Cheng, J. Mater. Sci. Technol. 197(2024) 183, https://doi.org/10.1016/j.jmst.2024.02.012.J. Cai, B. Liu, S. Zhang, L. Wang, Z. Wu, J. Zhang, B. Cheng, J. Mater. Sci. Technol. 197(2024) 183, https://doi.org/10.1016/j.jmst.2024.02.012.
58. [58]
  K. Das, S. Mansingh, D. Sahoo, R. Mohanty, K. Parida, New J. Chem. 46(2022) 5785, https://doi.org/10.1039/D2NJ00067A.K. Das, S. Mansingh, D. Sahoo, R. Mohanty, K. Parida, New J. Chem. 46(2022) 5785, https://doi.org/10.1039/D2NJ00067A.
59. [59]
  Q. Xu, S. Wageh, A. Al-Ghamdi, X. Li, J. Mater. Sci. Technol. 124(2022) 171, https://doi.org/10.1016/j.jmst.2022.02.016.Q. Xu, S. Wageh, A. Al-Ghamdi, X. Li, J. Mater. Sci. Technol. 124(2022) 171, https://doi.org/10.1016/j.jmst.2022.02.016.
60. [60]
  W. Yu, C. Bie, Acta Phys. Chim. Sin. 40(2024) 2307022, https://doi.org/10.3866/PKU.WHXB202307022.W. Yu, C. Bie, Acta Phys. Chim. Sin. 40(2024) 2307022, https://doi.org/10.3866/PKU.WHXB202307022.
61. [61]
  M. Sayed, L. Zhang, H. Garcia, H. Yu, J. Yu, Acc. Chem. Res. 59(2026) 1138, https://doi.org/10.1021/acs.accounts.5c00899.M. Sayed, L. Zhang, H. Garcia, H. Yu, J. Yu, Acc. Chem. Res. 59(2026) 1138, https://doi.org/10.1021/acs.accounts.5c00899.
62. [62]
  L. Liang, X. Li, Y. Sun, Y. Tan, X. Jiao, H. Ju, Z. Qi, J. Zhu, Y. Xie, Joule 2(2018) 1004, https://doi.org/10.1016/j.joule.2018.02.019.L. Liang, X. Li, Y. Sun, Y. Tan, X. Jiao, H. Ju, Z. Qi, J. Zhu, Y. Xie, Joule 2(2018) 1004, https://doi.org/10.1016/j.joule.2018.02.019.
63. [63]
  M. Gu, J. Zhang, I. Kurganskii, A. Poryvaev, M. Fedin, B. Cheng, J. Yu, L. Zhang, Adv. Mater. 37(2025) 2414803, https://doi.org/10.1002/adma.202414803.M. Gu, J. Zhang, I. Kurganskii, A. Poryvaev, M. Fedin, B. Cheng, J. Yu, L. Zhang, Adv. Mater. 37(2025) 2414803, https://doi.org/10.1002/adma.202414803.
64. [64]
  F. Qaraah, S. Mahyoub, A. Hezam, A. Qaraah, Q. Drmosh, G. Xiu, Chin. J. Catal. 43(2022) 2637, https://doi.org/10.1016/S1872-2067(21)64038-X.F. Qaraah, S. Mahyoub, A. Hezam, A. Qaraah, Q. Drmosh, G. Xiu, Chin. J. Catal. 43(2022) 2637, https://doi.org/10.1016/S1872-2067(21)64038-X.
65. [65]
  Y. Ma, S. Wang, Y. Zhang, B. Cheng, L. Zhang, J. Materiomics 11(2025) 100978. https://doi.org/10.1016/j.jmat.2024.100978.Y. Ma, S. Wang, Y. Zhang, B. Cheng, L. Zhang, J. Materiomics 11(2025) 100978. https://doi.org/10.1016/j.jmat.2024.100978.
66. [66]
  F. Fu, Y. Li, Chin. J. Catal. 78(2025) 4, https://doi.org/10.1016/S1872-2067(25)64809-1.F. Fu, Y. Li, Chin. J. Catal. 78(2025) 4, https://doi.org/10.1016/S1872-2067(25)64809-1.
67. [67]
  S. Yang, C. Bie, Y. Wu, W. Xia, K. Xu, J. Zhang, J. Yu, Small 22(2026) e72654, https://doi.org/10.1002/smll.72654.S. Yang, C. Bie, Y. Wu, W. Xia, K. Xu, J. Zhang, J. Yu, Small 22(2026) e72654, https://doi.org/10.1002/smll.72654.
68. [68]
  J. Yang, C. Bie, Chem. Synth. 5(2025) 12, https://doi.org/10.20517/cs.2024.105.J. Yang, C. Bie, Chem. Synth. 5(2025) 12, https://doi.org/10.20517/cs.2024.105.
69. [69]
  S. Khan, M. Qaiser, W. Qureshi, Y. Xu, J. Li, H. Li, L. Sun, S. Haider, B. Zhu, L. Wang, et al., ACS Appl. Mater. Interfaces 17(2025) 6249, https://doi.org/10.1021/acsami.4c17246.S. Khan, M. Qaiser, W. Qureshi, Y. Xu, J. Li, H. Li, L. Sun, S. Haider, B. Zhu, L. Wang, et al., ACS Appl. Mater. Interfaces 17(2025) 6249, https://doi.org/10.1021/acsami.4c17246.
70. [70]
  H. Ling, H. Sun, L. Lu, J. Zhang, L. Liao, J. Wang, X. Zhang, Y. Lan, R. Li, W. Lu, et al., Nat. Commun. 15(2024) 9505, https://doi.org/10.1038/s41467-024-53896-w.H. Ling, H. Sun, L. Lu, J. Zhang, L. Liao, J. Wang, X. Zhang, Y. Lan, R. Li, W. Lu, et al., Nat. Commun. 15(2024) 9505, https://doi.org/10.1038/s41467-024-53896-w.
71. [71]
  W. Zhong, A. Meng, Y. Su, H. Yu, P. Han, J. Yu, Angew. Chem. Int. Ed. 64(2025) e202425038, https://doi.org/10.1002/anie.202425038.W. Zhong, A. Meng, Y. Su, H. Yu, P. Han, J. Yu, Angew. Chem. Int. Ed. 64(2025) e202425038, https://doi.org/10.1002/anie.202425038.
72. [72]
  Y. Yang, X. Zhou, M. Gu, B. Cheng, Z. Wu, J. Zhang, Acta Phys. Chim. Sin. 41(2025) 100064, https://doi.org/10.1016/j.actphy.2025.100064.Y. Yang, X. Zhou, M. Gu, B. Cheng, Z. Wu, J. Zhang, Acta Phys. Chim. Sin. 41(2025) 100064, https://doi.org/10.1016/j.actphy.2025.100064.
73. [73]
  J. Qiu, C. Cheng, H. García, G. Liang, B. Zhu, L. Zhang, J. Yu, Angew. Chem. Int. Ed. 64(2026) e202515898, https://doi.org/10.1002/anie.202515898.J. Qiu, C. Cheng, H. García, G. Liang, B. Zhu, L. Zhang, J. Yu, Angew. Chem. Int. Ed. 64(2026) e202515898, https://doi.org/10.1002/anie.202515898.
74. [74]
  H. Liu, Q. Li, X, Zhang, K, Zheng, Y. Dong, C. Wu, Y. Tang, Y. Zhou, H. Yu, K. Lv, et al., ACS Catal. 16(2026) 1386, https://doi.org/10.1021/acscatal.5c07274.H. Liu, Q. Li, X, Zhang, K, Zheng, Y. Dong, C. Wu, Y. Tang, Y. Zhou, H. Yu, K. Lv, et al., ACS Catal. 16(2026) 1386, https://doi.org/10.1021/acscatal.5c07274.
75. [75]
  L. Zhang, J. Zhang, J. Yu, Chem 12(2026) 102719, https://doi.org/10.1016/j.chempr.2025.102719.L. Zhang, J. Zhang, J. Yu, Chem 12(2026) 102719, https://doi.org/10.1016/j.chempr.2025.102719.
76. [76]
  W. Zhu, R. Zhang, X. Li, X. Li, Y. Zhang, X. Wang, X. Deng, S. Bao, X. Zuo, J. Alloy. Compd. 1039(2025) 183009, https://doi.org/10.1016/j.jallcom.2025.183009.W. Zhu, R. Zhang, X. Li, X. Li, Y. Zhang, X. Wang, X. Deng, S. Bao, X. Zuo, J. Alloy. Compd. 1039(2025) 183009, https://doi.org/10.1016/j.jallcom.2025.183009.
77. [77]
  A. Hayat, Z. Ajmal, A. Alzahrani, S. Moussa, M. Khered, N. Almuqati, A. Alshammari, Y. Al-Hadeethi, H. Ali, Y. Orooji, Coord. Chem. Rev. 522(2025) 216218, https://doi.org/10.1016/j.ccr.2024.216218.A. Hayat, Z. Ajmal, A. Alzahrani, S. Moussa, M. Khered, N. Almuqati, A. Alshammari, Y. Al-Hadeethi, H. Ali, Y. Orooji, Coord. Chem. Rev. 522(2025) 216218, https://doi.org/10.1016/j.ccr.2024.216218.
78. [78]
  S. Mao, R. He, S. Song, Chin. J. Catal. 64(2024) 1, https://doi.org/10.1016/S1872-2067(24)60102-6.S. Mao, R. He, S. Song, Chin. J. Catal. 64(2024) 1, https://doi.org/10.1016/S1872-2067(24)60102-6.
79. [79]
  Y. Zhang, J. Qiu, B. Zhu, G. Sun, B. Cheng, L. Wang, Chin. J. Catal. 57(2024) 143, https://doi.org/10.1016/S1872-2067(23)64580-2.Y. Zhang, J. Qiu, B. Zhu, G. Sun, B. Cheng, L. Wang, Chin. J. Catal. 57(2024) 143, https://doi.org/10.1016/S1872-2067(23)64580-2.
80. [80]
  Y. Zhang, Y. Wang, Y. Liu, S. Zhang, Y. Zhao, J. Zhang, J. Materiomics 11(2025) 100985, https://doi.org/10.1016/j.jmat.2024.100985.Y. Zhang, Y. Wang, Y. Liu, S. Zhang, Y. Zhao, J. Zhang, J. Materiomics 11(2025) 100985, https://doi.org/10.1016/j.jmat.2024.100985.
81. [81]
  X. Zhou, C. Ai, X. Wang, Z. Wu, J. Zhang, J. Materiomics 11(2025) 100974, https://doi.org/10.1016/j.jmat.2024.100974.X. Zhou, C. Ai, X. Wang, Z. Wu, J. Zhang, J. Materiomics 11(2025) 100974, https://doi.org/10.1016/j.jmat.2024.100974.
82. [82]
  M. Gu, Y. Yang, B. Cheng, L. Zhang, P. Xiao, T. Chen, Chin. J. Catal. 59(2024) 185, https://doi.org/10.1016/S1872-2067(23)64610-8.M. Gu, Y. Yang, B. Cheng, L. Zhang, P. Xiao, T. Chen, Chin. J. Catal. 59(2024) 185, https://doi.org/10.1016/S1872-2067(23)64610-8.
83. [83]
  Y. Wu, C. Cheng, K. Qi, B. Cheng, J. Zhang, J. Yu, L. Zhang, Acta Phys. Chim. Sin. 40(2024) 2406027, https://doi.org/10.3866/PKU.WHXB202406027.Y. Wu, C. Cheng, K. Qi, B. Cheng, J. Zhang, J. Yu, L. Zhang, Acta Phys. Chim. Sin. 40(2024) 2406027, https://doi.org/10.3866/PKU.WHXB202406027.

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 50
HTML全文浏览量: 8

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

WO₃/In₂S₃ S型异质结中通过W-S键的界面电子转移增强光催化产H₂O₂

通讯作者: 李猛,E-mail:limeng_2016@126.com; 别传彪,E-mail:biechuanbiao@cug.edu.cn

English

WO₃/In₂S₃ S型异质结中通过W-S键的界面电子转移增强光催化产H₂O₂

Corresponding author: Meng Li, ; Chuanbiao Bie,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处