构建基于Fe<sub>3</sub>O<sub>4</sub>@ZIF-67的柔性多功能水凝胶及其电磁干扰屏蔽与应变传感性能

引用本文: 刘晓南, 雷智, 卢茂霞, 马冬威, 王川, 吴泽宏, 张道海. 构建基于Fe₃O₄@ZIF-67的柔性多功能水凝胶及其电磁干扰屏蔽与应变传感性能[J]. 物理化学学报, 2026, 42(10): 100354. doi: 10.1016/j.actphy.2026.100354 shu

Citation: Xiaonan Liu, Zhi Lei, Maoxia Lu, Dongwei Ma, Chuan Wang, Zehong Wu, Daohai Zhang. Construction of Fe₃O₄@ZIF-67 based flexible multifunctional hydrogels for electromagnetic interference shielding and strain sensing[J]. Acta Physico-Chimica Sinica, 2026, 42(10): 100354. doi: 10.1016/j.actphy.2026.100354 shu

构建基于Fe₃O₄@ZIF-67的柔性多功能水凝胶及其电磁干扰屏蔽与应变传感性能

刘晓南 ^1, ,
雷智 ^2, ,
卢茂霞 ^2, ,
马冬威 ^3, ,
王川 ^{4,
,} ,
吴泽宏 ^5, ,
张道海 ^{2,
,}

1.
贵州医科大学附属医院医院感染科, 贵州贵阳 550025;
2.
贵州民族大学化学工程学院, 贵州贵阳 550025;
3.
湖北汽车工业学院汽车材料学院, 湖北十堰 442002;
4.
贵州医科大学附属医院骨科, 贵州贵阳 550025;
5.
贵州医科大学临床医学院, 贵州贵阳 550025

通讯作者: 王川,E-mail:wangchuan@gmc.edu.cn; 张道海,E-mail:zhangdaohai6235@163.com

基金项目:
本研究得到了国家自然科学基金项目(52163001)、贵州省科技计划项目(黔科合平台人才-GCC[2022]010-2、黔科合中引地[2024]、黔科合基础-ZK[2024]YB488、黔科合中引地(2025)013、黔科合成果[2025]、黔科合人才XKBF(2025)005)、贵州省科学家工作站(黔科合平台KXJZ[2024]022)、贵阳市白云区科技计划项目(白科合[2025]号、白科合[2025]号)以及贵州省卫生健康委员会科学基金(gzwkj2023-177)的资助。

摘要: 传统电磁屏蔽材料已难以满足现代柔性电子设备与先进信息技术的快速发展需求。水凝胶凭借其优异的柔韧性、粘附性、快速响应性、易加工和功能修饰等特点，为开发柔性可穿戴电子设备提供了广阔前景。本研究通过反向生长策略和一锅聚合法制备了PAM/CMC/Fe₃O₄@ZIF-67多功能复合水凝胶。首先，利用乙二醇辅助溶剂热法制备花状微球结构的Fe₃O₄，随后将其整合到ZIF-67表面，获得Fe₃O₄@ZIF-67复合材料。随后，将复合材料引入含有PAM/CMC的三维网络中，形成兼具柔韧性、高含水量与导电磁性协同效应的多功能水凝胶。实验结果表明：PCZF-2水凝胶的平均电磁干扰屏蔽效能(EMI SE)为36.08 dB，电导率为0.93 S m^-1，压缩模量为398.0 kPa，压缩变形率为64.1%，含水量为625.72%，吸水率为240.82%。优异的附着能力和和高灵敏度(0-100%，GF=1.40，R²=0.995)，实现了水凝胶人机交互友好的应变传感。本研究为开发兼具电磁屏蔽能效和传感功能的一体化韧性多功能材料提供了一种有效策略。

关键词:

English

Construction of Fe₃O₄@ZIF-67 based flexible multifunctional hydrogels for electromagnetic interference shielding and strain sensing

Xiaonan Liu ^1, ,
Zhi Lei ^2, ,
Maoxia Lu ^2, ,
Dongwei Ma ^3, ,
Chuan Wang ^{4,
,} ,
Zehong Wu ^5, ,
Daohai Zhang ^{2,
,}

1.
Department of Hospital Infection Management, Affiliated Hospital of Guizhou Medical University, Guiyang 550025, Guizhou Province, China;
2.
School of Chemical Engineering, Guizhou Minzu University, Guiyang 550025, Guizhou Province, China;
3.
School of Automotive Materials, Hubei University of Automotive Technology, Shiyan 442002, Hubei Province, China;
4.
Department of Orthopedics, Affiliated Hospital of Guizhou Medical University, Guiyang 550025, Guizhou Province, China;
5.
Clinical Medical College, Guizhou Medical University, Guiyang 550025, Guizhou Province, China

Corresponding author: Chuan Wang, ; Daohai Zhang,

Received Date: 03 May 2026
Accepted Date: 29 June 2026
Revised Date: 15 June 2026

Abstract: Traditional electromagnetic shielding materials can no longer meet the rapidly growing demands of modern flexible electronic devices and advanced information technologies. Owing to their excellent flexibility, adhesion, stimuli responsiveness, and ease of processing and functional modification, hydrogels offer promising opportunities for developing flexible wearable electronic devices. In this study, PAM/CMC/Fe₃O₄@ZIF-67 multifunctional composite hydrogels were fabricated through a reverse-growth strategy combined with a one-pot polymerization method. First, flower-like Fe₃O₄ microspheres were prepared via an ethylene glycol-assisted solvothermal method and subsequently coupled with ZIF-67 through a reverse-growth strategy to obtain the Fe₃O₄@ZIF-67 composite. Subsequently, the composites were introduced into a PAM/CMC-based three-dimensional network, forming a multifunctional hydrogel that integrates flexibility, high water content, and synergistic conductive-magnetic effects. The experimental results showed that the 3 mm-thick PCZF-2 hydrogels achieved an average EMI SE of 36.08 dB. It also exhibited a conductivity of 0.93 S m^-1, a compressive modulus of 398.0 kPa, a compressive strain of 64.1%, a water content of 625.72%, and a swelling ratio of 240.82%. The hydrogel also exhibited excellent adhesion capability and high sensitivity (GF = 1.40 within the strain range of 0-100%, R² = 0.995), enabling human-machine-interaction-friendly strain sensing. This study provides an effective strategy for constructing tough multifunctional materials with integrated electromagnetic interference shielding and strain-sensing functionalities.

Key words:

Fe₃O₄
/ ZIF-67
/ Reverse-growth method
/ Hydrogel
/ Electromagnetic interference shielding

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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 王川,E-mail:wangchuan@gmc.edu.cn; 张道海,E-mail:zhangdaohai6235@163.com

English

Construction of Fe₃O₄@ZIF-67 based flexible multifunctional hydrogels for electromagnetic interference shielding and strain sensing

Corresponding author: Chuan Wang, ; Daohai Zhang,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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中国化学会秘书处

构建基于Fe3O4@ZIF-67的柔性多功能水凝胶及其电磁干扰屏蔽与应变传感性能

通讯作者: 王川,E-mail:wangchuan@gmc.edu.cn; 张道海,E-mail:zhangdaohai6235@163.com

English

Construction of Fe3O4@ZIF-67 based flexible multifunctional hydrogels for electromagnetic interference shielding and strain sensing

Corresponding author: Chuan Wang, ; Daohai Zhang,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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构建基于Fe₃O₄@ZIF-67的柔性多功能水凝胶及其电磁干扰屏蔽与应变传感性能

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