双金属MOFs中精确设计的异质界面实现多尺度极化协同效应用于高效电磁衰减

引用本文: 杨世豪, 郭志强, 贾梓睿, 刘翌, 王丁硕, 李增超, 李海丰, 邱华, 吴广磊. 双金属MOFs中精确设计的异质界面实现多尺度极化协同效应用于高效电磁衰减[J]. 物理化学学报, 2026, 42(9): 100348. doi: 10.1016/j.actphy.2026.100348 shu

Citation: Shihao Yang, Zhiqiang Guo, Zirui Jia, Yi Liu, Dingshuo Wang, Zengchao Li, Haifeng Li, Hua Qiu, Guanglei Wu. Precisely engineered heterointerfaces in bimetallic MOFs enable multiscale polarization synergy for efficient electromagnetic attenuation[J]. Acta Physico-Chimica Sinica, 2026, 42(9): 100348. doi: 10.1016/j.actphy.2026.100348 shu

双金属MOFs中精确设计的异质界面实现多尺度极化协同效应用于高效电磁衰减

杨世豪 ^{1, †,} ,
郭志强 ^{1, †,
,} ,
贾梓睿 ^{1,
,} ,
刘翌 ^1, ,
王丁硕 ^1, ,
李增超 ^1, ,
李海丰 ^2, ,
邱华 ^3, ,
吴广磊 ^{1,
,}

1.
青岛大学材料科学与工程学院, 山东省低维材料与聚合物复合材料重点实验室, 山东青岛 266071
2.
湖北汽车工业学院汽车材料学院, 湖北十堰 442002
3.
西北工业大学化学与化工学院, 陕西西安 710072

通讯作者: Email: guozq2022@163.com (郭志强); jiazirui@qdu.edu.cn (贾梓睿); wuguanglei@mail.xjtu.edu.cn/wuguanglei@mail.xjtu.edu.cn (吴广磊)

摘要: 基于金属有机框架(MOF)衍生物的多组分界面工程在实现高性能电磁波(EMW)吸收方面具有巨大潜力。然而，精确控制异质界面构型及其相关极化机制仍是一个重大科技难题。本研究开发了一种基于双金属MOF前驱体的可控热解-硒化策略，用于制备ZnSe/Cu₂Se多相复合材料。通过前驱体结构设计和硒化程度的精准调控，实现了形貌与异质界面的双重精确控制。多尺度表征、有限元模拟和密度泛函理论(DFT)计算共同表明：Cu₂Se在碳骨架内形成了高效导电网络，产生显著传导损耗；同时两种金属硒化物的共存构建了大量异质界面，极大增强了界面极化损耗。此外，缺陷诱导极化和偶极子极化产生了活性位点，实现多尺度极化协同耗散电磁波。最终优化后的复合材料展现出卓越的电磁波吸收性能，其最小反射损耗(RL_min)达−52.63 dB，最大有效吸收带宽(EAB_max)为8.64 GHz。本研究提出了一种精确调控基于MOF衍生的双金属硒化物异质界面的策略，为理解高效衰减电磁波所需的多尺度极化协同机制提供了理论基础。

关键词:

English

Precisely engineered heterointerfaces in bimetallic MOFs enable multiscale polarization synergy for efficient electromagnetic attenuation

Shihao Yang ^{1, †,} ,
Zhiqiang Guo ^{1, †,
,} ,
Zirui Jia ^{1,
,} ,
Yi Liu ^1, ,
Dingshuo Wang ^1, ,
Zengchao Li ^1, ,
Haifeng Li ^2, ,
Hua Qiu ^3, ,
Guanglei Wu ^{1,
,}

1.
College of Materials Science and Engineering, Shandong Key Laboratory of Low Dimensional Materials and Polymer Composites, Qingdao University, Qingdao 266071, Shandong Province, China
2.
School of Automotive Materials, Hubei University of Automotive Technology, Shiyan 442002, Hubei Province, China
3.
School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an 710072, Shaanxi Province, China

Corresponding author: Email: guozq2022@163.com (Zhiqiang Guo); jiazirui@qdu.edu.cn (Zirui Jia); wuguanglei@mail.xjtu.edu.cn/wuguanglei@mail.xjtu.edu.cn (Guanglei Wu)

Received Date: 02 April 2026
Accepted Date: 11 June 2026
Revised Date: 11 June 2026
Available Online: 15 September 2026

Abstract: Multicomponent interface engineering based on metal-organic framework (MOF) derivatives holds great potential for achieving high-performance electromagnetic wave (EMW) absorption. However, precisely controlling heterointerface configurations and their associated polarization mechanisms remains a significant scientific and technical hurdle. In this study, a controlled pyrolysis-selenization strategy based on bimetallic MOF precursors was developed to prepare ZnSe/Cu₂Se multiphase composites. The rational engineering of precursor architecture and selenization degree achieves precise dual-control over morphology and heterointerfaces. Multiscale characterization, finite element simulations, and density functional theory (DFT) calculations collectively demonstrate that Cu₂Se forms an efficient conductive network within the carbon framework, leading to significant conductive loss. Simultaneously, the coexistence of the two metallic selenides creates numerous heterointerfaces which greatly enhance interfacial polarization losses. Additionally, defect-induced and dipole polarizations generate active sites that dissipate EMW through multiscale polarization synergy. Ultimately, the optimized composite exhibits outstanding EMW absorption performance, with a minimum reflection loss (RL_min) of −52.63 dB and a maximum effective absorption bandwidth (EAB_max) of 8.64 GHz. This study introduces a precise strategy for engineering heterointerfaces in MOF-derived bimetallic selenides, offering fundamental insights into the multiscale polarization synergy crucial for efficient EMW attenuation.

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

双金属MOFs中精确设计的异质界面实现多尺度极化协同效应用于高效电磁衰减

通讯作者: Email: guozq2022@163.com (郭志强); jiazirui@qdu.edu.cn (贾梓睿); wuguanglei@mail.xjtu.edu.cn/wuguanglei@mail.xjtu.edu.cn (吴广磊)

English

Precisely engineered heterointerfaces in bimetallic MOFs enable multiscale polarization synergy for efficient electromagnetic attenuation

Corresponding author: Email: guozq2022@163.com (Zhiqiang Guo); jiazirui@qdu.edu.cn (Zirui Jia); wuguanglei@mail.xjtu.edu.cn/wuguanglei@mail.xjtu.edu.cn (Guanglei Wu)

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

双金属MOFs中精确设计的异质界面实现多尺度极化协同效应用于高效电磁衰减

通讯作者: Email: guozq2022@163.com (郭志强); jiazirui@qdu.edu.cn (贾梓睿); wuguanglei@mail.xjtu.edu.cn/wuguanglei@mail.xjtu.edu.cn (吴广磊)

English

Precisely engineered heterointerfaces in bimetallic MOFs enable multiscale polarization synergy for efficient electromagnetic attenuation

Corresponding author: Email: guozq2022@163.com (Zhiqiang Guo); jiazirui@qdu.edu.cn (Zirui Jia); wuguanglei@mail.xjtu.edu.cn/wuguanglei@mail.xjtu.edu.cn (Guanglei Wu)

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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