Citation: Ke Liu, Qi Gao, Haifeng Li, Lipeng Diao, Xuegang Chen, Daohao Li, Guanglei Wu. Hydrogen-bonding intermolecular interaction between graphene oxide and polytetrafluoroethylene enhanced creep resistance[J]. Acta Physico-Chimica Sinica, ;2026, 42(8): 100315. doi: 10.1016/j.actphy.2026.100315 shu

Hydrogen-bonding intermolecular interaction between graphene oxide and polytetrafluoroethylene enhanced creep resistance

Ke Liu ^{1, 2, 3} ,
Qi Gao ⁴ ,
Haifeng Li ² ,
Lipeng Diao ^{1, 3, 4,,} ,
Xuegang Chen ^{1, 3, 4,,} ,
Daohao Li ¹ ,
Guanglei Wu ^1,,

1.
State Key Laboratory of Bio-fibers and Eco-textiles, College of Materials Science and Engineering, Qingdao University, Qingdao 266071, Shandong Province, China
2.
School of Automotive Materials, Hubei University of Automotive Technology, Shiyan 442002, Hubei Province, China
3.
Ningbo Yokey Precision Technology Co., Ltd, Ningbo 315400, Zhejiang Province, China
4.
Qingdao Hanxing New Material Co., Ltd, Qingdao 266109, Shandong Province, China

Corresponding author: Lipeng Diao, diaolipeng@qdhanxing.com Xuegang Chen, chenxuegang.cool@163.com Guanglei Wu, wuguanglei@qdu.edu.cn; wuguanglei@mail.xjtu.edu.cn
Received Date: 31 January 2026
Revised Date: 4 May 2026
Accepted Date: 6 May 2026

Polytetrafluoroethylene (PTFE) is widely used due to its excellent thermal stability, electrical insulation, and low friction characteristics. However, its significant creep behavior greatly limits its application range. Inorganic fillers can effectively improve the creep resistance of PTFE-based materials, and the interaction between the filler and the PTFE matrix plays a key role in the modification effect. This study employs two-dimensional monolayer graphene oxide (GO) as a reinforcing filler to prepare graphene oxide-polytetrafluoroethylene (GO-PTFE) composites, achieving a significant enhancement in creep resistance. The surface of graphene oxide is rich in oxygen-containing functional groups, which can form strong interfacial hydrogen bonds with fluorine atoms in the PTFE matrix. Theoretical calculations and molecular dynamics simulations indicate that there is a strong intermolecular interaction in GO-PTFE composites. This interaction effectively restricts the movement of PTFE molecular chains, reduces their slippage and deformation under external forces, and thereby decreases the material's creep extent.
- Hydrogen bonding,
- Filling modification,
- Polytetrafluoroethylene,
- Creep resistance
1. [1]
  O. Ayurova, V. Kornopoltsev, A. Khagleev, R. Kurbatov, U. Mishigdorzhiyn, A. Dyakonov, D. Mognonov, Lubricants 12 (2024) 29, https://doi.org/10.3390/lubricants12020029. doi: 10.3390/lubricants12020029
2. [2]
  Y. Cheng, X. Liu, J. Ren, X. Xu, D. Lan, G. Wu, S. Zhang, Z. Gao, Z. Jia, G. Wu, Carbon 239 (2025) 120325, https://doi.org/10.1016/j.Carbon2025.120325. doi: 10.1016/j.Carbon2025.120325
3. [3]
  H. Ren, H. Zhao, J. Ning, Mech. Mater. 189 (2024) 104871, https://doi.org/10.1016/j.mechmat.2023.104871. doi: 10.1016/j.mechmat.2023.104871
4. [4]
  P. T. Xie, H. K. Wu, Z. X. Cheng, M. X. Liu, Y. Liu, W. K. Pang, R. H. Fan, Y. Liu, Adv. Mater. 38 (2026) e16951, https://doi.org/10.1002/adma.202516951. doi: 10.1002/adma.202516951
5. [5]
  J. Chai, G. Wang, A. Zhang, X. Li, Z. Xu, J. Zhao, G. Zhao, Chem. Eng. J. 461 (2023) 141971, https://doi.org/10.1016/j.cej.2023.141971. doi: 10.1016/j.cej.2023.141971
6. [6]
  Y. Y. Gu, J. Shi, D. Nematov, A. Q. Liu, Y. R. Yin, H. L. Dai, L. Bi, Mater. Sci. Eng. B 327 (2026) 119260, https://doi.org/10.1016/j.mseb.2026.119260. doi: 10.1016/j.mseb.2026.119260
7. [7]
  S. Yang, Y. R. Yin, S. Boulfrad, H. L. Dai, S. F. Yu, Y. Y. Gu, L. Bi, Adv. Funct. Mater. (2026) e74539, https://doi.org/10.1002/adfm.74539. doi: 10.1002/adfm.74539
8. [8]
  D. Lan, J. Wang, Y. Wang, X. Guo, D. Du, C. Zhang, G. Wu, Carbon 253 (2026) 121416, https://doi.org/10.1016/j.Carbon2026.121416. doi: 10.1016/j.Carbon2026.121416
9. [9]
  S. Song, B. Zheng, L. Chen, H. Shu, D. Gao, D. Lan, T. Li, X. Liu, Y. Ma, J. Energy Storage 134 (2025) 118282, https://doi.org/10.1016/j.est.2025.118282. doi: 10.1016/j.est.2025.118282
10. [10]
  P. Qiao, J. Dai, Z. Niu, Y. Li, D. Lan, Y. Yi, Y. Cao, Y. Wang, L. Chen, J. Polym. Res. 33 (2026) 49, https://doi.org/10.1007/s10965-026-04773-1. doi: 10.1007/s10965-026-04773-1
11. [11]
  L. Zhou, Y. R. Yin, D. Nematov, H. L. Dai, Y. Y. Gu, S. F. Yu, L. Bi, Sustain. Mater. Technol. 48 (2026) e01936, https://doi.org/10.1016/j.susmat.2026.e01936. doi: 10.1016/j.susmat.2026.e01936
12. [12]
  W. Lv, T. Wang, Q. Wang, K. K. Yap, F. Song, C. Wang, Polymers 16 (2024) 894, https://doi.org/10.3390/polym16070894. doi: 10.3390/polym16070894
13. [13]
  X. Chen, C. Dai, T. Zhang, P. Xu, W. Ke, J. Wu, M. Qiu, K. Fu, Y. Fan, Chem. Eng. J. 425 (2022) 134972, https://doi.org/10.1016/j.cej.2022.134972. doi: 10.1016/j.cej.2022.134972
14. [14]
  W. H. Song, X. C. Dong, Y. R. Yin, S. F. Yu, Y. Y. Gu, L. Bi, J. Adv. Ceram. 15 (2026) 9221262, https://doi.org/10.26599/JAC.2026.9221262. doi: 10.26599/JAC.2026.9221262
15. [15]
  M. Ma, D. Lan, L. Zhang, Y. Wang, Z. Jia, Z. Gao, H. Qiu, G. Wu, J. Mater. Sci. Technol. 273 (2026) 69, https://doi.org/10.1016/j.jmst.2026.03.014. doi: 10.1016/j.jmst.2026.03.014
16. [16]
  A. P. Vasilev, T. S. Struchkova, L. A. Nikiforov, A. A. Okhlopkova, P. N. Grakovich, E. L. Shim, J. H. Cho, Molecules 24 (2019) 224, https://doi.org/10.3390/molecules24020224. doi: 10.3390/molecules24020224
17. [17]
  T. Zhao, X. Guo, Z. Gao, Z. Jia, D. Lan, G. Wu, Carbon 254 (2026) 121509, https://doi.org/10.1016/j.Carbon2026.121509. doi: 10.1016/j.Carbon2026.121509
18. [18]
  X. Wang, B. Liu, G. Zhang, L. Liu, Q. Chen, W. Chen, X. Li, Surf. Interface Anal. 49 (2017) 112, https://doi.org/10.1002/sia.6066. doi: 10.1002/sia.6066
19. [19]
  G. Zhao, C. Wu, L. Zhang, J. Song, Q. Ding, Polym. Adv. Technol. 29 (2018) 1487, https://doi.org/10.1002/pat.4260. doi: 10.1002/pat.4260
20. [20]
  B. Liang, Y. Zhao, S. Wang, S. Huang, F. Zhou, C. Zhang, Y. Wang, X. Guo, Acta Phys. -Chim. Sin. 42 (2026) 100285, https://doi.org/10.1016/j.actphy.2026.100285. doi: 10.1016/j.actphy.2026.100285
21. [21]
  Z. L. Cheng, X. Y. Chang, Z. Liu, D. Z. Qin, Micro Nano Lett. 14 (2019) 91, https://doi.org/10.1049/mnl.2018.5195. doi: 10.1049/mnl.2018.5195
22. [22]
  F. Wang, J. Ci, J. Fan, Polymers 14 (2022) 3903, https://doi.org/10.3390/polym14153093. doi: 10.3390/polym14153093
23. [23]
  Y. Lu, X. Li, C. Wu, S. J. Xu, J. Alloy. Compd. 750 (2018) 197, https://doi.org/10.1016/j.jallcom.2018.03.301. doi: 10.1016/j.jallcom.2018.03.301
24. [24]
  X. Liu, X. Ma, L. Zhu, L. Zhu, Ind. Crops. Prod. 164 (2021) 113352, https://doi.org/10.1016/j.indcrop.2021.113352. doi: 10.1016/j.indcrop.2021.113352
25. [25]
  L. M. Ramaniah, C. Kamal, R. J. Kshirsagar, A. Chakrabarti, A. Banerjee, Mol. Phys. 111 (2013) 3067, https://doi.org/10.1080/00268976.2013.770174. doi: 10.1080/00268976.2013.770174
26. [26]
  X. Gao, Y. Liu, H. Li, J. Bian, Y. Zhao, Y. Cao, Y. Mao, X. Li, Y. Xu, Y. Ozaki, et al., Mol. Struct. 1040 (2013) 122, https://doi.org/10.1016/j.molstruc.2013.02.017. doi: 10.1016/j.molstruc.2013.02.017
27. [27]
  S. Mao, R. Miao, D. Lan, S. Zhang, J. Zhou, X. Liu, S. Du, Z. Zhao, G. Wu, Acta Phys. -Chim. Sin. 42 (2026) 100279, https://doi.org/10.1016/j.actphy.2026.100279. doi: 10.1016/j.actphy.2026.100279
28. [28]
  N. Verma, Y. Tao, E. Kraka, J. Phys. Chem. B 125 (2021) 2551, https://doi.org/10.1021/acs.jpcb.0c11392. doi: 10.1021/acs.jpcb.0c11392
29. [29]
  R. Delmelle, P. Ngene, B. Dam, D. Bleiner, A. Borgschulte, ChemCatChem 8 (2016) 1646, https://doi.org/10.1002/cctc.201600168. doi: 10.1002/cctc.201600168
30. [30]
  A. Palov, H. Fujii, Y. Mankelevich, T. Rakhimova, M. Baklanov, Polym. Degrad. Stab. 97 (2012) 802, https://doi.org/10.1016/j.polymdegradstab.2012.01.027. doi: 10.1016/j.polymdegradstab.2012.01.027
31. [31]
  G. J. Zhang, K. Yang, W. B. Zhao, Z. Yan, Appl. Surf. Sci. 253 (2006) 1995, https://doi.org/10.1016/j.apsusc.2006.03.082. doi: 10.1016/j.apsusc.2006.03.082
32. [32]
  L. Diao, Q. Gao, N. Zhang, Q. Dai, X. Zhang, D. Li, D. Yang, X. She, Compos. Commun. 39 (2023) 101533, https://doi.org/10.1016/j.coco.2023.101533. doi: 10.1016/j.coco.2023.101533
33. [33]
  J. Fan, M. Yan, J. Huang, L. Cao, Y. Chen, Ind. Eng. Chem. Res. 58 (2019) 15199, https://doi.org/10.1021/acs.iecr.9b03028. doi: 10.1021/acs.iecr.9b03028
34. [34]
  M. Maroufkhani, A. Katbab, W. Liu, J. Zhang, Polymer 115 (2017) 37, https://doi.org/10.1016/j.polymer.2017.03.025. doi: 10.1016/j.polymer.2017.03.025
35. [35]
  Y. Liu, X. Su, D. Lan, J. Liu, W. Ma, Y. Liu, Acta Phys. -Chim. Sin. 42 (2026) 100276, https://doi.org/10.1016/j.actphy.2026.100276. doi: 10.1016/j.actphy.2026.100276
36. [36]
  S. Schöche, N. Hong, M. Khorasaninejad, A. Ambrosio, E. Orabona, E. Maddalena, P. Capasso, Appl. Surf. Sci. 421 (2017) 778, https://doi.org/10.1016/j.apsusc.2017.01.035. doi: 10.1016/j.apsusc.2017.01.035
37. [37]
  P. Kumar, M. Šilhavík, Z. A. Zafar, J. Červenka, J. Phys. Chem. C 127 (2023) 10599, https://doi.org/10.1021/acs.jpcc.3c01534. doi: 10.1021/acs.jpcc.3c01534
38. [38]
  A. Stefanović, D. Kepić, M. Momčilović, J. L. Mead, M. Huskić, K. Haddadi, M. Sebbache, B. T. Marković, S. Jovanović, Nanomaterials 14 (2024) 912, https://doi.org/10.3390/nano14110912. doi: 10.3390/nano14110912
39. [39]
  Y. Bu, K. Li, F. Guo, Z. Liang, J. Zhang, Appl. Surf. Sci. 606 (2022) 154920, https://doi.org/10.1016/j.apsusc.2022.154920. doi: 10.1016/j.apsusc.2022.154920
40. [40]
  S. W. Pattinson, R. E. Diaz, N. A. Stelmashenko, A. H. Windle, C. Ducati, E. A. Stach, K. K. K. Koziol, Chem. Mater. 25 (2013) 2921, https://doi.org/10.1021/cm401216q. doi: 10.1021/cm401216q
41. [41]
  A. Atta, E. Abdeltwab, A. Bek, Surf. Topogr. 9 (2021) 025013, https://doi.org/10.1088/2051-672X/abf9f5. doi: 10.1088/2051-672X/abf9f5
42. [42]
  W. Sun, X. Liu, K. Liu, J. Xu, Y. Lu, J. Ye, Carbon 184 (2021) 312, https://doi.org/10.1016/j.Carbon2021.08.042. doi: 10.1016/j.Carbon2021.08.042
43. [43]
  Z. Wang, Z. Gao, Z. Jia, D. Lan, G. Wu, Carbon 255 (2026) 121535, https://doi.org/10.1016/j.Carbon2026.121535. doi: 10.1016/j.Carbon2026.121535
44. [44]
  S. Zhao, X. Guo, Z. Gao, Z. Jia, D. Lan, G. Wu, Carbon 254 (2025) 121509, https://doi.org/10.1016/j.Carbon2026.121509. doi: 10.1016/j.Carbon2026.121509
45. [45]
  R. Feng, C. Fan, D. Lan, L. Liu, Q. He, Y. Wang, Acta Phys. -Chim. Sin. 42 (2026) 100301, https://doi.org/10.1016/j.actphy.2026.100301. doi: 10.1016/j.actphy.2026.100301
46. [46]
  K. Endo, S. Shimada, N. Kato, T. Ida, J. Mol. Struct. 1122 (2016) 341, https://doi.org/10.1016/j.molstruc.2016.04.087. doi: 10.1016/j.molstruc.2016.04.087
47. [47]
  K. Liu, S. Yang, W. Li, Y. Wang, C. Sun, L. Peng, H. Garcia, Fuel. 337 (2023) 126840, https://doi.org/10.1016/j.fuel.2022.126840. doi: 10.1016/j.fuel.2022.126840
48. [48]
  M. Keramatinia, B. Ramezanzadeh, M. Mahdavian, G. Bahlakeh, Chem. Eng. J. 437 (2022) 135241, https://doi.org/10.1016/j.cej.2022.135241. doi: 10.1016/j.cej.2022.135241
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