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分子偶极工程调控MXene/ZnO异质结构的介电性能

王嘉浩 ,  蔡博 ,  孙博文 ,  侯志灵 ,  杨树豪 ,  杨青林 ,  赵培炎 ,  李文萍 ,  张宇 ,  王广胜

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引用本文: 王嘉浩, 蔡博, 孙博文, 侯志灵, 杨树豪, 杨青林, 赵培炎, 李文萍, 张宇, 王广胜. 分子偶极工程调控MXene/ZnO异质结构的介电性能[J]. 物理化学学报, 2026, 42(6): 100271. doi: 10.1016/j.actphy.2026.100271 shu
Citation:  Jia-Hao Wang, Bo Cai, Bowen Sun, Zhi-Ling Hou, Shu-Hao Yang, Qinglin Yang, Pei-Yan Zhao, Wen-Ping Li, Yu Zhang, Guang-Sheng Wang. Molecular dipole engineering for tailored dielectric properties in MXene/ZnO heterostructures[J]. Acta Physico-Chimica Sinica, 2026, 42(6): 100271. doi: 10.1016/j.actphy.2026.100271 shu

分子偶极工程调控MXene/ZnO异质结构的介电性能

  • 1.

    北京航空航天大学国际创新研究院(北京航空航天大学国际创新学院), 浙江 杭州 311115

  • 2.

    北京航空航天大学化学学院, 北京 100191

  • 3.

    北京工业大学物理与光电工程学院, 北京 100124

  • 4.

    北京航空航天大学物理学院, 北京 100191

  • 5.

    西北工业大学化学与化工学院, 陕西 西安 710072

    • 通讯作者: Email: sunbw@buaa.edu.cn (孙博文); liwp@buaa.edu.cn (李文萍); wanggsh@buaa.edu.cn (王广胜)
摘要: 由于异质材料的结构较为复杂，通过调控其极化效应来优化介电性能仍具有挑战性。本研究通过分子接枝诱导偶极子重新取向，实现了对界面极化强度的精准调控。实验证明，这些偶极子的取向可以有效调节界面极化：–CF3基团增强了电荷转移和极化损耗，而–NH2基团则抑制这些效应。经–CF3修饰优化的MXene/ZnO复合材料最小反射损耗达到−66.7 dB，有效吸收带宽为5.05 GHz，表现出了卓越的电磁波吸收性能。该工作通过界面偶极子工程展示了一种精确调控电磁参数的新策略，为先进吸波材料的设计提供了新思路。

English

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