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纳米材料相工程：从基础理论到应用前沿

毕帅 ,  王习习 ,  翟伟 ,  史振宇 ,  李子健 ,  翟傈 ,  张安 ,  田玉辉 ,  程婷 ,  姚尧 ,  吴直颖 ,  刘佳玮 ,  张华

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引用本文: 毕帅, 王习习, 翟伟, 史振宇, 李子健, 翟傈, 张安, 田玉辉, 程婷, 姚尧, 吴直颖, 刘佳玮, 张华. 纳米材料相工程：从基础理论到应用前沿[J]. 物理化学学报, 2026, 42(3): 100188. doi: 10.1016/j.actphy.2025.100188 shu
Citation:  Shuai Bi, Xixi Wang, Wei Zhai, Zhenyu Shi, Zijian Li, Li Zhai, An Zhang, Yuhui Tian, Ting Cheng, Yao Yao, Zhiying Wu, Jiawei Liu, Hua Zhang. Phase engineering of nanomaterials: from fundamentals to application frontiers[J]. Acta Physico-Chimica Sinica, 2026, 42(3): 100188. doi: 10.1016/j.actphy.2025.100188 shu

纳米材料相工程：从基础理论到应用前沿

  • 1.

    香港城市大学, 化学系, 香港

  • 2.

    香港科技大学, 化学与生物工程系, 香港 九龙清水湾

  • 3.

    香港城市大学, 香港清洁能源研究院, 香港

  • 4.

    香港城市大学, 国家贵金属材料工程研究中心香港分中心, 香港

  • 5.

    香港城市大学, 深圳研究院, 广东 深圳 518057

    • 通讯作者: Email: hua.zhang@cityu.edu.hk (张华)
摘要: 纳米材料的“相”(即原子排列方式)是决定其物理化学性质及功能的核心因素之一。近年来，纳米材料相工程(phase engineering of nanomaterials, PEN)已经成为材料科学领域新兴的研究方向。通过精确调控原子排列方式，PEN不仅能够突破材料常规的热力学稳定相的限制，还能赋予新的非常规相材料独特的物理化学性质和功能，为开发新型功能纳米材料提供了全新策略。本文系统综述了利用PEN策略来制备新的非常规相贵金属和过渡金属二硫族化合物(TMDs)，总结了直接合成、诱导相变等关键制备方法，阐明了其相依赖的性质和催化性能，强调了相对其功能和应用的显著影响。同时，本文深入分析了当前研究中存在的挑战，提出了未来发展方向，包括合成机制的研究、非常规相材料的稳定性提升以及人工智能辅助设计等，以期为纳米材料相工程的基础研究与实际应用提供理论指导和技术参考。

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