Citation: Wenjun Zhu, Chenbin Ai, Kaiqiang Xu, Yatai Zhou, Xidong Zhang, Yong Zhang. WO₃@TP inorganic@organic S-scheme photocatalyst for boosting H₂O₂ production[J]. Acta Physico-Chimica Sinica, ;2026, 42(3): 100184. doi: 10.1016/j.actphy.2025.100184 shu

WO₃@TP inorganic@organic S-scheme photocatalyst for boosting H₂O₂ production

Wenjun Zhu ¹ ,
Chenbin Ai ² ,
Kaiqiang Xu ^3,, ,
Yatai Zhou ² ,
Xidong Zhang ² ,
Yong Zhang ^1,,

1.
School of Advanced Materials and Green Chemical Engineering, Hubei Key Laboratory of Mine Environmental Pollution Control & Remediation, Hubei Polytechnic University, Huangshi 435003, Hubei Province, China
2.
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences (Wuhan), Wuhan 430078, Hubei Province, China
3.
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai, 201418, China

Corresponding author: Kaiqiang Xu, xukaiqiang24@sit.edu.cn Yong Zhang, zy0340907@163.com
Received Date: 3 August 2025
Revised Date: 6 September 2025
Accepted Date: 8 September 2025

Photocatalysis of H₂O₂ production using O₂ and water is a cost-effective and environmental process, but developing high-performance photocatalysts is still a challenge. Herein, a WO₃@polymer S-scheme photocatalyst was synthesized by in situ growing the Schiff-base polymer, tris-(4-aminophenyl)amine (TAPA)-terephthaldicarboxaldehyde (PDA) (labeled as TP) on the surface of WO₃ nanofibers (WO₃@TP) at room temperature. The obtained WO₃@TP S-scheme heterojunction exhibited rapid carrier separation ability and short photogenerated carriers transfer distance. The optimal WO₃@TP composite (WT-10) realized the H₂O₂ evolution rate of 3242 μmol g⁻¹ h⁻¹, which was 137.3 and 4.6-fold higher than bare WO₃ and TP, respectively. The combination of advanced characterizations regarding in situ irradiated X-ray photoelectron spectroscopy (ISI-XPS), theoretical calculation, and femtosecond transient absorption spectroscopy (fs-TAS) validates the charge transfer mechanism within the WO₃@TP S-scheme heterojunction. The occurrence of a dual-channel pathway (O₂ reduction reaction (ORR) and water oxidation reaction (WOR) within the reaction system has been confirmed via electron paramagnetic resonance (EPR) and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), thereby contributing to the highly efficient H₂O₂ evolution. This study not only gives an in-depth understanding of the ultrafast charge migration behavior in S-scheme heterojunction but also offers the rational design of inorganic@organic photocatalysts applied to solar-driven H₂O₂ production.
- Photocatalytic H₂O₂ evolution,
- S-scheme heterojunction,
- Polymers,
- Ultrafast charge transfer,
- WO₃ nanofibers
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沈阳化工大学材料科学与工程学院沈阳 110142

WO3@TP inorganic@organic S-scheme photocatalyst for boosting H2O2 production

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WO₃@TP inorganic@organic S-scheme photocatalyst for boosting H₂O₂ production