Citation: Ruiyun Liu, Ping Wang, Xuefei Wang, Feng Chen, Huogen Yu. Work-function-engineered Mo 4d electronic structure modulation in Mo₂C MXene cocatalyst for efficient photocatalytic H₂ evolution[J]. Acta Physico-Chimica Sinica, ;2025, 41(11): 100137. doi: 10.1016/j.actphy.2025.100137 shu

Work-function-engineered Mo 4d electronic structure modulation in Mo₂C MXene cocatalyst for efficient photocatalytic H₂ evolution

Ruiyun Liu ¹ ,
Ping Wang ^1,, ,
Xuefei Wang ¹ ,
Feng Chen ¹ ,
Huogen Yu ^2,,

1.
School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, Hubei Province, China
2.
Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, Hubei Province, China

Corresponding author: Ping Wang, wangping0904@whut.edu.cn Huogen Yu, yuhuogen@cug.edu.cn
Received Date: 29 June 2025
Revised Date: 22 July 2025
Accepted Date: 24 July 2025

Fund Project: the National Natural Science Foundation of China 22472127the National Natural Science Foundation of China 22178275the National Natural Science Foundation of China U22A20147the Natural Science Foundation of Hubei Province of China 2022CFA001

Mo₂C MXene (Mo₂CT_x) exhibits exceptional hydrogen-evolution potential in photocatalysis due to the Pt-like electronic structure of surface Mo active sites. However, the Mo sites in Mo₂CT_x usually show excessively strong H-adsorption during HER, significantly limiting the intrinsic catalytic activity of Mo₂CT_x. To weaken the H-adsorption capacity of Mo active sites, a strategy of modulating d-orbital electron is implemented via in-situ constructing MoC-Mo₂C MXene heterojunction by a work-function-induced effect. The MoC-Mo₂CT_x heterojunction was synthesized by in situ conversion of Mo₂C MXene into MoC via a Co-induced molten salt method, followed by coupling with TiO₂ through a simple ultrasonication-assisted method to prepare the MoC-Mo₂CT_x/TiO₂ photocatalyst. Photocatalytic tests showed that the optimal MoC-Mo₂CT_x/TiO₂ sample achieves an excellent hydrogen production rate of 1886 μmol∙h⁻¹∙g⁻¹, representing 117.9 and 3.9 fold enhancements over TiO₂ and Mo₂CF_X/TiO₂ (Mo₂CF₂ prepared by a conventional etchant NH₄F+HCl), respectively. Experimental and theoretical calculations substantiate that the work-function gradient between MoC and Mo₂C MXene induces electron transfer from MoC to Mo₂C MXene to weaken the H-adsorption of Mo active sites in Mo₂CT_x cocatalyst, thereby enhancing its HER activity. This research provides a new strategy of in situ constructing Mo₂C MXene-based heterojunction for adjusting the H-adsorption capacity of Mo active sites.
- Photocatalytic H₂ evolution,
- Cocatalyst,
- Mo₂C MXene,
- Heterojunction,
- d-orbital modulation
1. [1]
  S. Parwaiz, M. M. Khan, J. Environ. Chem. Eng. 12 (2024) 113175, https://doi.org/10.1016/j.jece.2024.113175. doi: 10.1016/j.jece.2024.113175
2. [2]
  H. Xie, K. Wang, S. Li, Z. Jin, Surf. Interfaces 42 (2023) 103353, https://doi.org/10.1016/j.surfin.2023.103353. doi: 10.1016/j.surfin.2023.103353
3. [3]
  Z. Jiang, B. Cheng, L. Zhang, Z. Zhang, C. Bie, Chin. J. Catal. 52 (2023) 32, https://doi.org/10.1016/S1872-2067(23)64502-4. doi: 10.1016/S1872-2067(23)64502-4
4. [4]
  F. Li, Z. Fang, Z. Xu, Q. Xiang, Energy Environ. Sci. 17 (2024) 497, https://doi.org/10.1039/D3EE03282E. doi: 10.1039/D3EE03282E
5. [5]
  J. Cai, C. Cheng, B. Liu, J. Zhang, C. Jiang, B. Cheng, Acta Phys. -Chim. Sin. 41 (2025) 100084, https://doi.org/10.1016/j.actphy.2025.100084. doi: 10.1016/j.actphy.2025.100084
6. [6]
  C. Ding, J. Shi, Z. Wang, C. Li, ACS Catal. 7 (2017) 675, https://doi.org/10.1021/acscatal.6b03107. doi: 10.1021/acscatal.6b03107
7. [7]
  T. Yang, X. Hu, J. Fan, T. Sun, E. Liu, Surf. Interfaces 42 (2023) 103352, https://doi.org/10.1016/j.surfin.2023.103352. doi: 10.1016/j.surfin.2023.103352
8. [8]
  R. Zhong, Y. Liang, F. Huang, S. Liang, S. Liu, Chin. J. Catal. 53 (2023) 109, https://doi.org/10.1016/S1872-2067(23)64513-9. doi: 10.1016/S1872-2067(23)64513-9
9. [9]
  C. Bie, L. Wang, J. Yu, Chem 8 (2022) 1567, https://doi.org/10.1016/j.chempr.2022.04.013. doi: 10.1016/j.chempr.2022.04.013
10. [10]
  J. Zhu, S. Zhang, R. He, Chin. J. Catal. 59 (2024) 4, https://doi.org/10.1016/s1872-2067(24)60011-2. doi: 10.1016/s1872-2067(24)60011-2
11. [11]
  T. Wang, H. Wang, J. Lin, J. Yang, F. Zhang, X. Lin, Y. Zhang, S. Jin, J. Li, Chin. J. Struct. Chem. 42 (2023) 100066, https://doi.org/10.1016/j.cjsc.2023.100066. doi: 10.1016/j.cjsc.2023.100066
12. [12]
  W. Yang, J. Zhang, Q. Xu, Y. Yang, L. Zhang, Acta Phys. -Chim. Sin. 40 (2024) 2312014, https://doi.org/10.3866/pku.whxb202312014. doi: 10.3866/pku.whxb202312014
13. [13]
  D. Liu, B. Sun, S. Bai, T. Gao, G. Zhou, Chin. J. Catal. 50 (2023) 273, https://doi.org/10.1016/S1872-2067(23)64462-6. doi: 10.1016/S1872-2067(23)64462-6
14. [14]
  C. Bie, C. Jiang, J. Yang, X. Sun, X. Zeng, J. Zhang, B. Zhu, J. Mater. Sci. Technol. 229 (2025) 48, https://doi.org/10.1016/j.jmst.2024.12.047. doi: 10.1016/j.jmst.2024.12.047
15. [15]
  H. Zhang, Z. Wang, J. Zhang, K. Dai, Chin. J. Catal. 49 (2023) 42, https://doi.org/10.1016/S1872-2067(23)64444-4. doi: 10.1016/S1872-2067(23)64444-4
16. [16]
  H. Zhang, X. Yao, W. Shan, Y. Liu, H. Tang, Sci. China Mater. 67 (2024) 532, https://doi.org/10.1007/s40843-023-2769-8. doi: 10.1007/s40843-023-2769-8
17. [17]
  Y. Wang, S. Jiang, C. Sun, S. Song, J. Mater. Sci. Technol. 190 (2024) 210, https://doi.org/10.1016/j.jmst.2023.12.026. doi: 10.1016/j.jmst.2023.12.026
18. [18]
  Y. Yang, C. Zhou, W. Wang, W. Xiong, G. Zeng, D. Huang, C. Zhang, B. Song, W. Xue, X. Li, et al., Chem. Eng. J. 405 (2021) 126547, https://doi.org/10.1016/j.cej.2020.126547. doi: 10.1016/j.cej.2020.126547
19. [19]
  Y. Cao, P. Wang, X. Wang, F. Chen, H. Yu, J. Mater. Chem. C 12 (2024) 10152, https://doi.org/10.1039/D4TC01076K. doi: 10.1039/D4TC01076K
20. [20]
  Y. Lei, K. H. Ng, Y. Zhu, Y. Zhang, Z. Li, S. Xu, J. Huang, J. Hu, Z. Chen, W. Cai, et al., Chem. Eng. J. 452 (2023) 139325, https://doi.org/10.1016/j.cej.2022.139325. doi: 10.1016/j.cej.2022.139325
21. [21]
  K. R. G. Lim, A. D. Handoko, L. R. Johnson, X. Meng, M. Lin, G. S. Subramanian, B. Anasori, Y. Gogotsi, A. Vojvodic, Z. W. Seh, ACS Nano 14 (2020) 16140, https://doi.org/10.1021/acsnano.0c08671. doi: 10.1021/acsnano.0c08671
22. [22]
  X. Ke, P. Wang, X. Wang, F. Chen, H. Yu, Appl. Catal. B: Environ. Energy 365 (2025) 124936, https://doi.org/10.1016/j.apcatb.2024.124936. doi: 10.1016/j.apcatb.2024.124936
23. [23]
  H. -X. Yang, W. Xu, P. -W. Zhong, D. Zhang, Z. Yu, B. Li, H. Wang, Y. Cao, H. -F. Wang, H. Yu, J. Energy Chem. 105 (2025) 121, https://doi.org/10.1016/j.jechem.2025.01.048. doi: 10.1016/j.jechem.2025.01.048
24. [24]
  X. Ke, M. Pan, R. Liu, P. Wang, X. Wang, H. Yu, Sol. RRL 7 (2023) 2300669, https://doi.org/10.1002/solr.202300669. doi: 10.1002/solr.202300669
25. [25]
  X. Zhao, W. Sun, D. Geng, W. Fu, J. Dan, Y. Xie, P. R. C. Kent, W. Zhou, S. J. Pennycook, K. P. Loh, Adv. Mater 31 (2019) 1808343, https://doi.org/10.1002/adma.201808343. doi: 10.1002/adma.201808343
26. [26]
  H. Zou, M. Pan, P. Wang, F. Chen, X. Wang, H. Yu, Catal. Sci. Technol. 14 (2024) 5731, https://doi.org/10.1039/D4CY00882K. doi: 10.1039/D4CY00882K
27. [27]
  J. Halim, S. Kota, M. R. Lukatskaya, M. Naguib, M. -Q. Zhao, E. J. Moon, J. Pitock, J. Nanda, S. J. May, Y. Gogotsi, et al., Adv. Funct. Mater. 26 (2016) 3118, https://doi.org/10.1002/adfm.201505328. doi: 10.1002/adfm.201505328
28. [28]
  X. Tian, M. Xu, Y. Li, H. Liu, B. Cao, R. A. Soomro, P. Zhang, B. Xu, Chem. Eng. J. 489 (2024) 151510, https://doi.org/10.1016/j.cej.2024.151510. doi: 10.1016/j.cej.2024.151510
29. [29]
  Y. Deng, Y. Ge, M. Xu, Q. Yu, D. Xiao, S. Yao, D. Ma, Acc. Chem. Res. 52 (2019) 3372, https://doi.org/10.1021/acs.accounts.9b00182. doi: 10.1021/acs.accounts.9b00182
30. [30]
  S. Yuan, M. Xia, Z. Liu, K. Wang, L. Xiang, G. Huang, J. Zhang, N. Li, Chem. Eng. J. 430 (2022) 132697, https://doi.org/10.1016/j.cej.2021.132697. doi: 10.1016/j.cej.2021.132697
31. [31]
  Y. Zheng, Y. Jiao, M. Jaroniec, S. Z. Qiao, Angew. Chem., Int. Ed. 54 (2015) 52, https://doi.org/10.1002/anie.201407031. doi: 10.1002/anie.201407031
32. [32]
  S. Trasatti, J. Electroanal. Chem. Interfacial Electrochem. 39 (1972) 163, https://doi.org/10.1016/S0022-0728(72)80485-6. doi: 10.1016/S0022-0728(72)80485-6
33. [33]
  J. Wang, Y. Zhang, S. Jiang, C. Sun, S. Song, Angew. Chem., Int. Ed. 62 (2023) e202307808, https://doi.org/10.1002/anie.202307808. doi: 10.1002/anie.202307808
34. [34]
  H. Long, D. Gao, P. Wang, X. Wang, F. Chen, H. Yu, Appl. Catal., B 340 (2024) 123270, https://doi.org/10.1016/j.apcatb.2023.123270. doi: 10.1016/j.apcatb.2023.123270
35. [35]
  Y. Wu, L. Wang, T. Bo, Z. Chai, J. K. Gibson, W. Shi, Adv. Funct. Mater. 33 (2023) 2214375, https://doi.org/10.1002/adfm.202214375. doi: 10.1002/adfm.202214375
36. [36]
  G. Qu, Y. Zhou, T. Wu, G. Zhao, F. Li, Y. Kang, C. Xu, ACS Appl. Energy Mater. 1 (2018) 7206, https://doi.org/10.1021/acsaem.8b01642. doi: 10.1021/acsaem.8b01642
37. [37]
  M. Yi, S. Hu, N. Li, H. Wang, J. Zhang, J. Energy Chem. 72 (2022) 453, https://doi.org/10.1016/j.jechem.2022.05.040. doi: 10.1016/j.jechem.2022.05.040
38. [38]
  M. Pan, P. Wang, X. Wang, F. Chen, H. Yu, ACS Sustainable Chem. Eng. 11 (2023) 13222, https://doi.org/10.1021/acssuschemeng.3c04308. doi: 10.1021/acssuschemeng.3c04308
39. [39]
  X. Ke, P. Wang, X. Wang, F. Chen, H. Yu, Chem. Eng. J. 495 (2024) 153477, https://doi.org/10.1016/j.cej.2024.153477. doi: 10.1016/j.cej.2024.153477
40. [40]
  X. Ke, P. Wang, X. Wang, F. Chen, H. Yu, Small 20 (2024) 2405378, https://doi.org/10.1002/smll.202405378. doi: 10.1002/smll.202405378
41. [41]
  R. Liu, P. Wang, X. Wang, F. Chen, H. Yu, Small 21 (2025) 2408330, https://doi.org/10.1002/smll.202408330. doi: 10.1002/smll.202408330
42. [42]
  J. Xu, B. Zhao, X. Wang, X. Wu, H. Yu, Chem. Eng. J. 506 (2025) 160107, https://doi.org/10.1016/j.cej.2025.160107. doi: 10.1016/j.cej.2025.160107
43. [43]
  J. Xu, X. Zhang, X. Wang, J. Zhang, J. Yu, H. Yu, ACS Catal. 14 (2024) 15444, https://doi.org/10.1021/acscatal.4c03916. doi: 10.1021/acscatal.4c03916
44. [44]
  D. Gao, W. Zhong, X. Zhang, P. Wang, H. Yu, Small 20 (2024) 2309123, https://doi.org/10.1002/smll.202309123. doi: 10.1002/smll.202309123
45. [45]
  C. Bie, Z. Meng, B. He, B. Cheng, G. Liu, B. Zhu, J. Mater. Sci. Technol. 173 (2024) 11, https://doi.org/10.1016/j.jmst.2023.07.019. doi: 10.1016/j.jmst.2023.07.019
46. [46]
  M. Chen, C. Song, C. Liang, B. Zhang, Y. Sun, S. Li, L. Lin, P. Xu, Inorg. Chem. Front. 9 (2022) 2575, https://doi.org/10.1039/D2QI00543C. doi: 10.1039/D2QI00543C
47. [47]
  D. Majchrzak, K. Kulinowski, W. Olszewski, R. Kuna, D. Hlushchenko, A. Piejko, M. Grodzicki, D. Hommel, R. Kudrawiec, ACS Appl. Mater. Interfaces 16 (2024) 59567, https://doi.org/10.1021/acsami.4c13225. doi: 10.1021/acsami.4c13225
48. [48]
  S. Jin, Z. Shi, H. Jing, L. Wang, Q. Hu, D. Chen, N. Li, A. Zhou, ACS Appl. Energy Mater. 4 (2021) 12754, https://doi.org/10.1021/acsaem.1c02456. doi: 10.1021/acsaem.1c02456
49. [49]
  S. Kim, C. Choi, J. Hwang, J. Park, J. Jeong, H. Jun, S. Lee, S. Kim, J. H. Jang, Y. Jung, et al., ACS Nano 14 (2020) 4988, https://doi.org/10.1021/acsnano.0c01285. doi: 10.1021/acsnano.0c01285
50. [50]
  Y. Guo, S. Jin, L. Wang, P. He, Q. Hu, L. Fan, A. Zhou, Ceram. Int. 46 (2020) 19550, https://doi.org/10.1016/j.ceramint.2020.05.008. doi: 10.1016/j.ceramint.2020.05.008
51. [51]
  J. Li, Y. Li, X. Wang, Z. Yang, G. Zhang, Chin. J. Catal. 51 (2023) 145, https://doi.org/10.1016/S1872-2067(23)64484-5. doi: 10.1016/S1872-2067(23)64484-5
52. [52]
  Z. Chen, P. Wang, X. Wang, H. Yu, Surf. Interfaces 51 (2024) 104684, https://doi.org/10.1016/j.surfin.2024.104684. doi: 10.1016/j.surfin.2024.104684
53. [53]
  Y. Zhang, Z. Zhang, J. Mater. Sci. Technol. 171 (2024) 147, https://doi.org/10.1016/j.jmst.2023.06.048. doi: 10.1016/j.jmst.2023.06.048
54. [54]
  B. Liu, J. Cai, J. Zhang, H. Tan, B. Cheng, J. Xu, Chin. J. Catal. 51 (2023) 204, https://doi.org/10.1016/S1872-2067(23)64466-3. doi: 10.1016/S1872-2067(23)64466-3
55. [55]
  H. Long, X. Zhang, Z. Zhang, J. Zhang, J. Yu, H. Yu, Nat. Commun. 16 (2025) 946, https://doi.org/10.1038/s41467-025-56306-x. doi: 10.1038/s41467-025-56306-x
56. [56]
  S. Cao, B. Zhong, C. Bie, B. Cheng, F. Xu, Acta Phys. -Chim. Sin. 40 (2024) 2307016, https://doi.org/10.3866/pku.Whxb202307016. doi: 10.3866/pku.Whxb202307016
57. [57]
  Z. Yu, C. Guan, X. Yue, Q. Xiang, Chin. J. Catal. 50 (2023) 361, https://doi.org/10.1016/S1872-2067(23)64448-1. doi: 10.1016/S1872-2067(23)64448-1
58. [58]
  Z. Zhu, X. Xing, Q. Qi, W. Shen, H. Wu, D. Li, B. Li, J. Liang, X. Tang, J. Zhao, et al., Chin. J. Struct. Chem. 42 (2023) 100194, https://doi.org/10.1016/j.cjsc.2023.100194. doi: 10.1016/j.cjsc.2023.100194
59. [59]
  P. Sun, J. Zhang, Y. Song, Z. Mo, Z. Chen, H. Xu, Acta Phys. -Chim. Sin. 40 (2024) 2311001, https://doi.org/10.3866/PKU.WHXB202311001. doi: 10.3866/PKU.WHXB202311001
60. [60]
  B. Liu, K. Meng, B. Cheng, L. Wang, G. Liang, C. Bie, J. Mater. Sci. Technol. 231 (2025) 286, https://doi.org/10.1016/j.jmst.2025.02.013. doi: 10.1016/j.jmst.2025.02.013
61. [61]
  K. Huang, B. Feng, X. Wen, L. Hao, D. Xu, G. Liang, R. Shen, X. Li, Chin. J. Struct. Chem. 42 (2023) 100204, https://doi.org/10.1016/j.cjsc.2023.100204. doi: 10.1016/j.cjsc.2023.100204
62. [62]
  F. Yan, Y. Zhang, S. Liu, R. Zou, J. B. Ghasemi, X. Li, Chin. J. Catal. 51 (2023) 124, https://doi.org/10.1016/S1872-2067(23)64475-4. doi: 10.1016/S1872-2067(23)64475-4
63. [63]
  S. Wan, W. Wang, B. Cheng, G. Luo, Q. Shen, J. Yu, J. Zhang, S. Cao, L. Zhang, Nat. Commun. 15 (2024) 9612, https://doi.org/10.1038/s41467-024-53951-6. doi: 10.1038/s41467-024-53951-6
64. [64]
  F. Jin, B. Yang, X. Wang, T. Li, N. Tsubaki, Z. Jin, Chin. J. Struct. Chem. 42 (2023) 100198, https://doi.org/10.1016/j.cjsc.2023.100198. doi: 10.1016/j.cjsc.2023.100198
65. [65]
  Z. Zhou, H. Yao, Y. Wu, T. Li, N. Tsubaki, Z. Jin, Acta Phys. -Chim. Sin. 40 (2024) 2312010, https://doi.org/10.3866/pku.whxb202312010. doi: 10.3866/pku.whxb202312010
66. [66]
  M. Gu, J. Zhang, I. V. Kurganskii, A. S. Poryvaev, M. V. Fedin, B. Cheng, J. Yu, L. Zhang, Adv. Mater 37 (2025) 2414803, https://doi.org/10.1002/adma.202414803. doi: 10.1002/adma.202414803
67. [67]
  J. Xia, S. Xing, T. Sun, H. Ma, T. Gao, E. Liu, Renew. Energ. 237 (2024) 121773, https://doi.org/10.1016/j.renene.2024.121773. doi: 10.1016/j.renene.2024.121773
68. [68]
  J. Tian, C. Guan, Q. Zhang, T. Sun, H. Hu, E. Liu, J. Mater. Sci. Technol. 231 (2025) 308, https://doi.org/10.1016/j.jmst.2024.12.102 doi: 10.1016/j.jmst.2024.12.102
1. [1]
  Jiaqi Yang , Xuqiang Hao , Jiejie Jing , Yuqiang Hao , Zhiliang Jin . 3D/2D ReSe₂/ZnCdS S-scheme photocatalyst with efficient interfacial charge separation for optimized hydrogen production. Acta Physico-Chimica Sinica, 2025, 41(10): 100131-0. doi: 10.1016/j.actphy.2025.100131
2. [2]
  Jiawei Hu , Kai Xia , Ao Yang , Zhihao Zhang , Wen Xiao , Chao Liu , Qinfang Zhang . Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(5): 2305043-0. doi: 10.3866/PKU.WHXB202305043
3. [3]
  Jinhui Jiang , Jiaqi Sun , Yongyi Chen , Lei Zhang , Pengyu Dong . W₁₈O₄₉/Al-doped SrTiO₃ S-scheme heterojunction aided by the LSPR effect for full-spectrum solar light-driven photocatalytic hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(11): 100145-0. doi: 10.1016/j.actphy.2025.100145
4. [4]
  Yajuan Xing , Hui Xue , Jing Sun , Niankun Guo , Tianshan Song , Jiawen Sun , Yi-Ru Hao , Qin Wang . Cu₃P-Induced Charge-Oriented Transfer and Surface Reconstruction of Ni₂P to Achieve Efficient Oxygen Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(3): 2304046-0. doi: 10.3866/PKU.WHXB202304046
5. [5]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
6. [6]
  Min WANG , Dehua XIN , Wei ZHANG , Haiying YANG , Yuchun WANG , Zhaorong LIU , Meng SHI , Le SHI . Preparation and full-spectrum catalytic degradation performance of nitrogen vacancy g-C₃N₄/Bi/BiOBr/BiOI heterojunction material. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2283-2298. doi: 10.11862/CJIC.20250109
7. [7]
  Jingjing Liu , Aoqi Wei , Hao Zhang , Shuwang Duo . SnS₂-based heterostructures: advances in photocatalytic and gas-sensing applications. Acta Physico-Chimica Sinica, 2025, 41(12): 100185-0. doi: 10.1016/j.actphy.2025.100185
8. [8]
  Mian Wei , Chang Cheng , Bowen He , Bei Cheng , Kezhen Qi , Chuanbiao Bie . Inorganic-organic CdS/YBTPy S-scheme photocatalyst for efficient hydrogen production and its mechanism. Acta Physico-Chimica Sinica, 2025, 41(12): 100158-0. doi: 10.1016/j.actphy.2025.100158
9. [9]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
10. [10]
  Yukai SHEN , Zhaochao YAN , Yangjun ZHOU , Mei HUANG . Nickel foam-supported NiFeP/NiFcDCA heterojunction electrocatalyst for efficient urea oxidation reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 237-246. doi: 10.11862/CJIC.20250257
11. [11]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
12. [12]
  Tong WANG , Qinyue ZHONG , Qiong HUANG , Weimin GUO , Xinmei LIU . Mn-doped carbon quantum dots/Fe-doped ZnO flower-like microspheres heterojunction: Construction and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1589-1600. doi: 10.11862/CJIC.20250011
13. [13]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-0. doi: 10.3866/PKU.WHXB202402016
14. [14]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
15. [15]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . Hierarchical MoS₂/Ti₃C₂T_x heterostructure with excellent photothermal conversion performance for solar-driven vapor generation. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-0. doi: 10.1016/j.actphy.2025.100053
16. [16]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016
17. [17]
  Zhiwen HU , Huiying ZHANG , Jiayan ZHOU , Yulong YANG , Ping LI , Zelong CHEN , Weixia DONG , Qifu BAO . Time evolution of in-situ synthesized Bi₁₂TiO₂₀/BaTiO₃ heterojunctions and catalytic mechanisms. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 65-77. doi: 10.11862/CJIC.20250172
18. [18]
  Jiali Lei , Juan Wang , Wenhui Zhang , Guohong Wang , Zihui Liang , Jinmao Li . TiO₂/CdIn₂S₄ S-scheme heterojunction photocatalyst promotes photocatalytic hydrogen evolution coupled vanillyl alcohol oxidation. Acta Physico-Chimica Sinica, 2025, 41(12): 100174-0. doi: 10.1016/j.actphy.2025.100174
19. [19]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
20. [20]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Construction of ZnCoP/CdLa₂S₄ Schottky Heterojunctions for Enhancing Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-0. doi: 10.3866/PKU.WHXB202404030

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1019)
HTML views(141)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Work-function-engineered Mo 4d electronic structure modulation in Mo2C MXene cocatalyst for efficient photocatalytic H2 evolution

Metrics

通讯作者: 陈斌, bchen63@163.com

Work-function-engineered Mo 4d electronic structure modulation in Mo₂C MXene cocatalyst for efficient photocatalytic H₂ evolution