Citation: Jinwang Wu, Qijing Xie, Chengliang Zhang, Haifeng Shi. 自旋极化增强ZnFe_1.2Co_0.8O₄/BiVO₄ S型异质结光催化性能降解四环素[J]. Acta Physico-Chimica Sinica, ;2025, 41(5): 100050. doi: 10.1016/j.actphy.2025.100050 shu

自旋极化增强ZnFe_1.2Co_0.8O₄/BiVO₄ S型异质结光催化性能降解四环素

1.
School of Science, Jiangnan University, Wuxi 214122, Jiangsu Province, China;
2.
Hangzhou Dianzi University, Hangzhou 310018, China;
3.
National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China

Received Date: 5 November 2024
Revised Date: 16 December 2024
Accepted Date: 24 December 2024

Fund Project: The project was supported by the National Natural Science Foundation of China (52271175), National Laboratory of Solid State Microstructures, Nanjing University (M34047). Prof. Haifeng Shi was indebted to the financial support from the Qing Lan Project of Jiangsu Province.

最近，电子自旋极化作为抑制光生电荷快速复合的一种策略受到了广泛的关注。然而，自旋极化调控主要关注于单个光催化材料，光生电荷分离的效率依然有待进一步提高。于此，本文构建了ZnFe_1.2Co_0.8O₄(ZFCO)/BiVO₄(BVO)异质结，通过S型异质结和自旋极化作用协同促进光生电荷分离，在外部磁场下进一步促进了光催化去除有机物污染物的性能。实验结果表明，在光照下，ZB-1.5 (ZFCO : BVO = 3 : 2)表现出最佳性能，四环素(TC)降解的反应速率常数(k)为0.0146 min^-1。在光照和磁场条件下，ZB-1.5的TC降解反应速率常数(k)为0.0175 min^-1，其光催化性能得到了进一步提升。研究表明这是由于电子自旋极化和S型电荷分离机制协同促进了光生电荷分离。DFT计算表明，ZFCO在费米能级附近出现了明显的自旋极化现象。光致发光光谱(PL)表明，S型异质结提高了电荷分离效率。此外，评估了可能的降解路径和毒性，表明成功实现了脱毒。这项工作为利用S型异质结开发具有高效光生电荷分离的光催化剂提供了一种研究思路。
- Electron spin-polarization,
- Ferromagnetic photocatalyst,
- S-scheme heterojunction,
- Magnetic field
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自旋极化增强ZnFe_1.2Co_0.8O₄/BiVO₄ S型异质结光催化性能降解四环素