Citation: Jiahao Lu, Xin Ming, Yingjun Liu, Yuanyuan Hao, Peijuan Zhang, Songhan Shi, Yi Mao, Yue Yu, Shengying Cai, Zhen Xu, Chao Gao. 基于稳态电热法的石墨烯膜导热系数的精确可靠测量[J]. Acta Physico-Chimica Sinica, ;2025, 41(5): 100045. doi: 10.1016/j.actphy.2025.100045 shu

基于稳态电热法的石墨烯膜导热系数的精确可靠测量

Jiahao Lu ¹ ,
Xin Ming ¹ ,
Yingjun Liu ^1,2 ,
Yuanyuan Hao ¹ ,
Peijuan Zhang ¹ ,
Songhan Shi ¹ ,
Yi Mao ¹ ,
Yue Yu ¹ ,
Shengying Cai ³ ,
Zhen Xu ^1,2 ,
Chao Gao ^1,2

1.
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Zhejiang University, Hangzhou 310027, China;
2.
Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering, Taiyuan 030032, China;
3.
Center for Healthcare Materials, Shaoxing Institute, Zhejiang University, Shaoxing 312000, Zhejiang Province, China

Received Date: 4 July 2024
Revised Date: 22 August 2024
Accepted Date: 26 August 2024

Fund Project: The project was supported by the National Natural Science Foundation of China (52272046, 52090030, 52090031, 51973191, 52122301, 52303354), the Natural Science Foundation of Zhejiang Province (LR23E020003) and the Fundamental Research Funds for the Central Universities (226-2024-00074, 226-2023-00023, 226-2023-00082, 2023QZJH26), Shanxi-Zheda Institute of New Materials and Chemical Engineering (2022SZ-TD011, 2022SZ-TD012, 2021SZ-FR004).

高导热石墨烯膜是近年来备受关注的高功率电子器件用散热材料。导热系数作为一项评价其基础性能的重要参数，实现其精确测量对于理解材料基础物性、优化制备工艺以及实际工程应用都具有重要意义。然而，现有的商业化导热测试设备，囿于测试原理、样品尺寸等因素，难以同时实现高效、准确、可靠的测量。开发操作简便、测试快捷、精度优异、可跨尺度的测量方案仍是一个重要挑战。本文提出基于稳态电热法的石墨烯膜导热系数的精确可靠测量方法，结合实验测试与仿真模拟，基于原理分析、测试优化、数据处理等三个方面，显著提升导热测量的精度与效率。测量结果的准确性受到热损校正、样品尺寸、系统设计以及数据处理等四方面因素影响。实验结果表明，热辐射和热对流引起的热损失会影响样品的温度分布和测量结果，可通过控制样品尺寸和温升来控制。对实验数据进行筛选和预处理也可以有效提高测量精度。通过实验与仿真结合，我们提出了可行的操作指南与标准化的测试方案。通过优化，该方法测量误差低于3.0%，不确定性降至0.5%，响应时间达毫秒级。本工作为准确评估材料导热性能提供有益指导，也为导热材料的热管理工程应用提供技术支撑。
- Graphene film,
- Thermal conductivity,
- Steady-state technology,
- Finite element simulation
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