Citation: Xueting Cao, Shuangshuang Cha, Ming Gong. 电催化反应中的界面双电层：理论、表征与应用[J]. Acta Physico-Chimica Sinica, ;2025, 41(5): 100041. doi: 10.1016/j.actphy.2024.100041 shu

电催化反应中的界面双电层：理论、表征与应用

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Fudan University, Shanghai 200438, China

Received Date: 25 October 2024
Revised Date: 18 November 2024
Accepted Date: 19 November 2024

Fund Project: The project was supported by the National Natural Science Foundation of China (22172036) and the Fundamental Research Funds for the Central Universities (20720220011).

界面双电层是电催化反应的核心区域。催化剂表面原子、反应物、中间体、产物、溶剂分子和离子等组分，共同构成了复杂的动态反应网络。这种特殊的组成和结构赋予界面双电层以特殊的性质，深刻地影响了电催化反应的路径与结果。本文将以电催化反应中的双电层为主要研究对象，围绕双电层理论模型及其历史沿革、双电层的实验表征方法和双电层对电催化反应的影响这三个方面，以若干电催化反应前沿研究为例，阐述双电层与电催化反应之间的关联，并介绍一些特定情形下电催化双电层研究的研究方法和研究逻辑。
- Electrocatalysis,
- Electrical double layer,
- Electrode/electrolyte interface,
- Theoretical model,
- In situ characterization technique
1. [1]
  Shao, Y. Y.; Markovic, N. M. Nano Energy 2016, 29, 1. doi: 10.1016/j.nanoen.2016.09.025
2. [2]
  Steinmann, S. N.; Seh, Z. W. Nat. Rev. Mater. 2021, 6 (4), 289. doi: 10.1038/s41578-021-00303-1
3. [3]
  Bockris, J. O’. M.; Reddy, A. K. N.; Gamboa-Aldeco, M. Modern Electrochemistry 2A: Fundamentals of Electrodics, 2nd ed.; Kluwer Academic Publishers: New York, NY, USA, 2000; pp. 771-775.
4. [4]
  Xu, Y. F.; Yang, H.; Chang, X. X.; Xu, B. J. Acta Phys. -Chim. Sin. 2023, 39, 2210025.
5. [5]
  Elliott, J. D.; Papaderakis, A. A.; Dryfe, R. A. W.; Carbone, P. J. Mater. Chem. C 2022, 10 (41), 15225. doi: 10.1039/D2TC01631A
6. [6]
  Ivanov, V. D. J. Solid State Electrochem. 2024, 28, 2487. doi: 10.1007/s10008-024-05850-5
7. [7]
  Gouy, G. J. Physique 1910, 9, 457. doi: 10.1051/jphystap:019100090045700
8. [8]
  Chapman, D. L. Phil. Mag. 1913, 25, 475. doi: 10.1080/14786440408634187
9. [9]
  Stern, H. O. Z. Electrochem. 1924, 30, 508. doi: 10.1002/bbpc.192400182
10. [10]
  Grahame, D. C. Chem. Rev. 1947, 41 (3), 441. doi: 10.1021/cr60130a002
11. [11]
  Hou, J. J.; Xu, B. J.; Lu, Q. Nat. Commun. 2024, 15 (1), 1926. doi: 10.1038/s41467-024-46318-4
12. [12]
  Boettcher, S. W.; Surendranath, Y. Nat. Catal. 2021, 4 (1), 4. doi: 10.1038/s41929-020-00570-1
13. [13]
  Lyu, D. Y.; Xu, J. C.; Wang, Z. Y. Front. Chem. 2023, 11, 1231886. doi: 10.3389/fchem.2023.1231886
14. [14]
  Fawcett, W. R. J. Solid State Electrochem. 2011, 15 (7-8), 1347. doi: 10.1007/s10008-011-1337-4
15. [15]
  Timmer, B.; Sluyters-Rehbach, M.; Sluyters, J. H. Surf. Sci. 1969, 18 (1), 44. doi: 10.1016/0039-6028(69)90266-0
16. [16]
  Bockris, J. O’. M.; Reddy, A. K. N.; Gamboa-Aldeco, M. Modern Electrochemistry 2A: Fundamentals of Electrodics, 2nd ed.; Kluwer Academic Publishers: New York, NY, USA, 2000; pp. 933-959, 1190-1201.
17. [17]
  Chen, S.; Liu, Y.; Chen, J. Chem. Soc. Rev. 2014, 43 (15), 5372. doi: 10.1039/C4CS00087K
18. [18]
  Wu, J. X.; Wang, R.; Kang, Y. K.; Li, J. L.; Hao, Y. M.; Li, Y. F.; Liu, Z. P.; Gong, M. Angew Chem. Int, Ed. 2024, 63 (22), e202403466. doi: 10.1002/anie.202403466
19. [19]
  Bikerman J. J. Lond. Edinb. Phil. Mag. 1942, 33 (220), 384. doi: 10.1080/14786444208520813
20. [20]
  Webb, T. J. J. Am. Chem. Soc. 1926, 48 (10), 2589. doi: 10.1021/ja01421a013
21. [21]
  Conway, B. E.; Bockris, J. O’. M.; Ammar, I. A. Trans. Faraday Soc. 1951, 47, 756. doi: 10.1039/tf9514700756
22. [22]
  Bockris, J. O’. M.; Devanathan, M. A. V.; Müller, K.; Butler, J. A. V. Proc. R. Soc. Lond. A 1963, 274 (1356), 55. doi: 10.1098/rspa.1963.0114
23. [23]
  Bockris, J. O’. M.; Reddy, A. K. N.; Gamboa-Aldeco, M. Modern Electrochemistry 2A: Fundamentals of Electrodics, 2nd ed.; Kluwer Academic Publishers: New York, NY, USA, 2000; pp. 895-919.
24. [24]
  Li, P.; Jiang, Y. L.; Hu, Y. C.; Men, Y. N.; Liu, Y. W.; Cai, W. B.; Chen, S. L. Nat. Catal. 2022, 5 (10), 900. doi: 10.1038/s41929-022-00846-8
25. [25]
  Gonella, G.; Backus, E. H. G.; Nagata, Y.; Bonthuis, D. J.; Loche, P.; Schlaich, A.; Netz, R. R.; Kühnle, A.; McCrum, I. T.; Koper, M. T. M.; et al. Nat. Rev. Chem. 2021, 5 (7), 466. doi: 10.1038/s41570-021-00293-2
26. [26]
  Wang, Q.; Qu, Z. G.; Tian, D. Adv. Energy Mater. 2024, 2402974. doi: 10.1002/aenm.202402974
27. [27]
  Zhang, L. L.; Li, C. K.; Huang, J. J. Electrochem. 2022, 28 (2), 2108471.
28. [28]
  Horng, T. L.; Tsai, P. H.; Lin, T. C. Comput. Math. Biophys. 2017, 5 (1), 142. doi: 10.1515/mlbmb-2017-0010
29. [29]
  Blum, L. Mol. Phys. 1975, 30 (5), 1529. doi: 10.1080/00268977500103051
30. [30]
  Outhwaite, C. W.; Bhuiyan, L. B.; Levine, S. J. Chem. Soc. Faraday Trans. 2 1980, 76, 1388. doi: 10.1039/F29807601388
31. [31]
  Lück, J.; Latz, A. Phys. Chem. Chem. Phys. 2018, 20 (44), 27804. doi: 10.1039/C8CP05113E
32. [32]
  Drude, P. Ann. Phys. 1900, 306, 566. doi: 10.1002/andp.19003060312
33. [33]
  Schmickler, W.; Henderson, D. J. Chem. Phys. 1984, 80 (7), 3381. doi: 10.1063/1.447092
34. [34]
  Bockris, J. O’. M.; Reddy, A. K. N.; Gamboa-Aldeco, M. Modern Electrochemistry 2A: Fundamentals of Electrodics, 2nd ed.; Kluwer Academic Publishers: New York, NY, USA, 2000; pp. 919-968.
35. [35]
  Petrii, O. A. Electrochim. Acta 1996, 41 (14), 2307. doi: 10.1016/0013-4686(96)00060-6
36. [36]
  Wang, Z. Y.; Chen, J.; Ni, C. W.; Nie, W.; Li, D. F.; Ta, N.; Zhang, D. Y.; Sun, Y. M.; Sun, F. S.; Li, Q.; et al. Natl. Sci. Rev. 2023, 10 (9), nwad166. doi: 10.1093/nsr/nwad166
37. [37]
  Chmiola, J.; Yushin, G.; Gogotsi, Y.; Portet, C.; Simon, P.; Taberna, P. L. Science 2006, 313 (5794), 1760. doi: 10.1126/science.1132195
38. [38]
  Schmickler, W. J. Solid State Electrochem. 2020, 24 (9), 2175. doi: 10.1007/s10008-020-04597-z
39. [39]
  Fang, Y. H.; Liu, Z. P. Chin. J. Catal. 2019, 40 (s1), 90.
40. [40]
  Fang, Y. H.; Liu, Z. P. J. Electrochem. 2020, 26 (1), 32.
41. [41]
  Nørskov, J. K.; Rossmeisl, J.; Logadottir, A.; Lindqvist, L.; Kitchin, J. R.; Bligaard, T.; Jónsson, H. J. Phys. Chem. B 2004, 108 (46), 17886. doi: 10.1021/jp047349j
42. [42]
  Masood, Z.; Ge, Q. F. J. Phys. Chem. C 2023, 127 (48), 23170. doi: 10.1021/acs.jpcc.3c03796
43. [43]
  Zhang, X.; Zhou, Z. J. Phys. Chem. C 2022, 126 (8), 3820. doi: 10.1021/acs.jpcc.1c10870
44. [44]
  Hu, X.; Chen, S.; Chen, L.; Tian, Y.; Yao, S.; Lu, Z.; Zhang, X.; Zhou, Z. J. Am. Chem. Soc. 2022, 144 (39), 18144. doi: 10.1021/jacs.2c08743
45. [45]
  Chan, K.; Nørskov, J. K. J. Phys. Chem. Lett. 2015, 6 (14), 2663. doi: 10.1021/acs.jpclett.5b01043
46. [46]
  Jaugstetter, M.; Blanc, N.; Kratz, M.; Tschulik, K. Chem. Soc. Rev. 2022, 51 (7), 2491. doi: 10.1039/D1CS00789K
47. [47]
  Zhang, D.; Li, Hao. J. Mater. Chem. A, 2024, 12, 13742. doi: 10.1039/D4TA02285H
48. [48]
  Li, P.; Jiao. Y. Z.; Huang, J.; Chen, S. L. JACS Au 2023, 3(10), 2640. doi: 10.1021/jacsau.3c00410
49. [49]
  Hu, X.; Yao, S.; Chen, L. T.; Zhang, X.; Jiao, M. G.; Lu, Z. Y; Zhou, Z. J. Mater. Chem. A 2021, 9, 23515. doi: 10.1039/D1TA07791K
50. [50]
  Agrawal, A.; Choudhary, A. APL Mater. 2016, 4 (5), 053208. doi: 10.1063/1.4946894
51. [51]
  Huang, S. D.; Shang, C.; Kang, P. L.; Zhang, X. J.; Liu, Z. P. WIREs Comput. Mol. Sci. 2019, 9, e1415. doi: 10.1002/wcms.1415
52. [52]
  Naserifar, S.; Chen, Y. L.; Kwon, S.; Xiao, H.; Goddard, W. A. Matter 2021, 4 (1), 195. doi: 10.1016/j.matt.2020.11.010
53. [53]
  Schlüter, N.; Novák, P.; Schröder, D. Adv. Energy Mater. 2022, 12 (21), 2200708. doi: 10.1002/aenm.202200708
54. [54]
  Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications, 2nd ed.; Wiley: New York, NY, USA, 2001; pp. 156-417.
55. [55]
  Zhang, J. Q. Electrochemical Measurement Technology, 1st ed.; Chemical Industry Press: Beijing, 2010; pp. 73-300.
56. [56]
  Scholz, F. ChemTexts 2015, 1 (4), 17. doi: 10.1007/s40828-015-0016-y
57. [57]
  Bockris, J. O’. M.; Reddy, A. K. N.; Gamboa-Aldeco, M. Modern Electrochemistry 2A: Fundamentals of Electrodics, 2nd ed.; Kluwer Academic Publishers: New York, NY, USA, 2000; pp. 859-869.
58. [58]
  Beck, T. R. J. Phys. Chem. 1969, 73 (2), 466. doi: 10.1021/j100722a045
59. [59]
  Fredlein, R. A.; Damjanovic, A.; Bockris, J. O’. M. Surf. Sci. 1971, 25 (2), 261. doi: 10.1016/0039-6028(71)90246-9
60. [60]
  Hamm, U. W.; Kramer, D.; Zhai, R. S.; Kolb, D. M. J. Electroanal. Chem. 1996, 414 (1), 85. doi: 10.1016/0022-0728(96)01006-6
61. [61]
  Bond, A. M.; Duffy, N. W.; Guo, S. X.; Zhang, J.; Elton, D. Anal. Chem. 2005, 77 (9), 186 A. doi: 10.1021/ac053370k
62. [62]
  Lucio, A. J.; Shaw, S. K.; Zhang, J.; Bond, A. M. J. Phys. Chem. C 2018, 122 (22), 11777. doi: 10.1021/acs.jpcc.8b00272
63. [63]
  Ojha, K.; Arulmozhi, N.; Aranzales, D.; Koper, M. T. M. Angew. Chem. Int. Ed. 2020, 59 (2), 711. doi: 10.1002/anie.201911929
64. [64]
  Lertanantawong, B.; O’Mullane, A. P.; Surareungchai, W.; Somasundrum, M.; Burke, L. D.; Bond, A. M. Langmuir 2008, 24 (6), 2856. doi: 10.1021/la702454k
65. [65]
  Lucio, A. J.; Shaw, S. K.; Zhang, J.; Bond, A. M. J. Phys. Chem. C 2017, 121 (22), 12136. doi: 10.1021/acs.jpcc.7b00287
66. [66]
  Pettit, C. M.; Goonetilleke, P. C.; Roy, D. J. Electroanal. Chem. 2006, 589 (2), 219. doi: 10.1016/j.jelechem.2006.02.012
67. [67]
  Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications, 2nd ed.; Wiley: New York, NY, USA, 2001; pp. 537-544.
68. [68]
  Tymoczko, J.; Colic, V.; Bandarenka, A. S.; Schuhmann, W. Surf. Sci. 2015, 631, 81. doi: 10.1016/j.susc.2014.04.014
69. [69]
  Yun, C.; Hwang, S. Int. J. Electrochem. Sci. 2021, 16 (3), 210355. doi: 10.20964/2021.03.50
70. [70]
  Bandarenka, A. S. Analyst 2013, 138 (19), 5540. doi: 10.1039/C3AN00791J
71. [71]
  Yang, Y.; Xiong, Y.; Zeng, R.; Lu, X.; Krumov, M.; Huang, X.; Xu, W.; Wang, H.; DiSalvo, F. J.; Brock, Joel. D.; et al. ACS Catal. 2021, 11 (3), 1136. doi: 10.1021/acscatal.0c04789
72. [72]
  Ji, Y.; Yin, Z. W.; Yang, Z.; Deng, Y. P.; Chen, H.; Lin, C.; Yang, L.; Yang, K.; Zhang, M.; Xiao, Q.; et al. Chem. Soc. Rev. 2021, 50 (19), 10743. doi: 10.1039/D1CS00629K
73. [73]
  Łukaszewski, M.; Siwek, H.; Czerwiński, A. J. Solid State Electrochem. 2010, 14 (7), 1279. doi: 10.1007/s10008-009-0926-y
74. [74]
  Bockris, J. O.; Gamboa-Aldeco, M.; Szklarczyk, M. J. Electroanal. Chem. 1992, 339 (1), 355. doi: 10.1016/0022-0728(92)80463-E
75. [75]
  Su, H. S.; Chang, X. X.; Xu, B. J. Chinese J. Catal. 2022, 43 (11), 2757. doi: 10.1016/S1872-2067(22)64157-3
76. [76]
  Jiang, Z.; Zhang, Q.; Liang, Z. X.; Chen, J. G. G. Appl. Catal. B Environ. 2018, 234, 329. doi: 10.1016/j.apcatb.2018.04.052
77. [77]
  Zhu, S. Q; Jiang, B.; Cai, W. B.; Shao, M. H. J. Am. Chem. Soc. 2017, 139 (44), 15664. doi: 10.1021/jacs.7b10462
78. [78]
  Sun, Q.; Oliveira, N. J.; Kwon, S.; Tyukhtenko, S.; Guo, J. J.; Myrthil, N.; Lopez, S. A.; Kendrick, I.; Mukerjee, S.; Ma, L.; et al. Nat. Energy 2023, 8 (8), 859. doi: 10.1038/s41560-023-01302-y
79. [79]
  Wu, J. X.; Li, J. L.; Li, Y. F.; Ma, X. Y.; Zhang, W. Y.; Hao, Y. M.; Cai, W. B.; Liu, Z. P.; Gong, M. Angew. Chem. Int. Ed. 2022, 61 (11), e202113362. doi: 10.1002/anie.202113362
80. [80]
  Yang, K. L.; Kas, R.; Smith, W. A. J. Am. Chem. Soc. 2019, 141 (40), 15891. doi: 10.1021/jacs.9b07000.
81. [81]
  Wang, H.; Jiang, B.; Zhao, T. T.; Jiang, K.; Yang, Y. Y.; Zhang, J. W.; Xie, Z. X.; Cai, W. B. ACS Catal. 2017, 7, 2033. doi: 10.1021/acscatal.6b03108
82. [82]
  Liu, T.; Chen, Y. X.; Hao, Y. M.; Wu, J. X.; Wang, R.; Gu, L. M.; Yang, X. J.; Yang, Q.; Lian, C.; Liu, H. L.; Gong, M. Chem 2022, 8 (10), 2700. doi: 10.1016/j.chempr.2022.06.012
83. [83]
  Li, J. F.; Huang, Y. F.; Ding, Y.; Yang, Z. L.; Li, S. B.; Zhou, X. S.; Fan, F. R.; Zhang, W.; Zhou, Z. Y.; Wu, D. Y.; et al. Nature 2010, 464 (7287), 392. doi: 10.1038/nature08907
84. [84]
  Cho, K. H.; Park, S.; Seo, H.; Choi, S.; Lee, M. Y.; Ko, C.; Nam, K. T. Angew. Chem. Int. Ed. 2021, 60, 4673. doi: 10.1002/anie.202014551
85. [85]
  Hao, Y. M.; Li, Y. F.; Wu, J. X.; Meng, L. S.; Wang, J. L.; Jia, C. L.; Liu, T.; Yang, X. J.; Liu, Z. P.; Gong, M. J. Am. Chem. Soc. 2021, 143, 1493. doi: 10.1021/jacs.0c11307
86. [86]
  Moysiadou, A.; Lee, S.; Hsu, C. S.; Chen, H. M.; Hu, X. L. J. Am. Chem. Soc. 2020, 142, 11901. doi: 10.1021/jacs.0c04867
87. [87]
  Xu, Z. Z.; Liang, Z. B.; Guo, W. H.; Zou, R. Q. Coordin. Chem. Rev. 2021, 436, 213824. doi: 10.1016/j.ccr.2021.213824
88. [88]
  Wang, Y. H.; Zheng, S.; Yang, W. M.; Zhou, R. Y.; He, Q. F.; Radjenovic, P.; Dong, J. C.; Li, S.; Zheng, J.; Yang, Z. L.; et al. Nature 2021, 600 (7887), 81. doi: 10.1038/s41586-021-04068-z
89. [89]
  Bhattacharyya, D.; E. Videla, P.; Cattaneo, M.; S. Batista, V.; Lian, T.; P. Kubiak, C. Chem. Sci. 2021, 12 (30), 10131. doi: 10.1039/D1SC01876K
90. [90]
  Chang, X. X.; Xiong, H. C.; Xu, Y. F.; Zhao, Y. R.; Xu, B. J. Catal. Sci. Technol., 2021, 11, 6825. doi: 10.1039/D1CY01090E
91. [91]
  Yang, L. J.; Zhang, W. K.; Bian, H. T.; Ma, G. Biointerphases 2022, 17 (5), 051201. doi: 10.1116/6.0002007
92. [92]
  Zhang, N. N.; Zou, Y. Q.; Tao, L.; Chen, W.; Zhou, L.; Liu, Z. J.; Zhou, B.; Huang, G.; Lin, H. Z.; Wang, S. Y. Angew. Chem. Int. Ed. 2019, 58 (44), 15895. doi: 10.1002/anie.201908722
93. [93]
  Ge, A.; Rudshteyn, B.; Videla, P. E.; Miller, C. J.; Kubiak, C. P.; Batista, V. S.; Lian, T. Q. Acc. Chem. Res. 2019, 52 (5), 1289. doi: 10.1021/acs.accounts.9b00001
94. [94]
  Bhattacharyya, D.; Videla, P. E.; Palasz, J. M.; Tangen, I.; Meng, J. H.; Kubiak, C. P.; Batista, V. S.; Lian, T. Q. J. Am. Chem. Soc. 2022, 144 (31), 14330. doi: 10.1021/jacs.2c05563
95. [95]
  Xu, P. T.; von Rueden, A. D.; Schimmenti, R.; Mavrikakis, M.; Suntivich, J. Nat. Mater. 2023, 22 (4), 503. doi: 10.1038/s41563-023-01474-8
96. [96]
  Harlow, G. S.; Lundgren, E.; Escudero-Escribano, M. Curr. Opin. Electrochem. 2020, 23, 162. doi: 10.1016/j.coelec.2020.08.005
97. [97]
  Hung, S. F. Pure Appl. Chem. 2020, 92 (5), 733. doi: 10.1515/pac-2019-1006
98. [98]
  Favaro, M.; Jeong, B.; Ross, P. N.; Yano, J.; Hussain, Z.; Liu, Z.; Crumlin, E. J. Nat. Commun. 2016, 7 (1), 12695. doi: 10.1038/ncomms12695
99. [99]
  Wang, Y. Q.; Skaanvik, S. A.; Xiong, X. Y.; Wang, S. Y.; Dong, M. D. Matter 2021, 4 (11), 3483. doi: 10.1016/j.matt.2021.09.024
100. [100]
  Santos, C. S.; Jaato, B. N.; Sanjuán, I.; Schuhmann, W.; Andronescu, C. Chem. Rev. 2023, 123 (8), 4972. doi: 10.1021/acs.chemrev.2c00766
101. [101]
  Liang, Y. C.; Pfisterer, J. H. K.; McLaughlin, D.; Csoklich, C.; Seidl, L.; Bandarenka, A. S.; Schneider, O. Small Methods 2019, 3 (8), 1800387. doi: 10.1002/smtd.201800387
102. [102]
  Bae, S. E.; Stewart, K. L.; Gewirth, A. A. J. Am. Chem. Soc. 2007, 129 (33), 10171. doi: 10.1021/ja071330n
103. [103]
  Tong, L.; Yu, Z.; Gao, Y. J.; Li, X. C.; Zheng, J. F.; Shao, Y.; Wang, Y. H.; Zhou, X. S. Nat. Commun. 2023, 14 (1), 3397. doi: 10.1038/s41467-023-39206-w
104. [104]
  Polcari, D.; Dauphin-Ducharme, P.; Mauzeroll, J. Chem. Rev. 2016, 116 (22), 13234. doi: 10.1021/acs.chemrev.6b00067
105. [105]
  Barman, K.; Askarova, G.; Jia, R.; Hu, G. X.; Mirkin, M. V. J. Am. Chem. Soc. 2023, 145 (10), 5786. doi: 10.1021/jacs.2c12775
106. [106]
  Monteiro, M. C. O.; Jacobse, L.; Touzalin, T.; Koper, M. T. M. Anal. Chem. 2020, 92 (2), 2237. doi: 10.1021/acs.analchem.9b04952
107. [107]
  Kim, D.; Yu, S.; Zheng, F.; Roh, I.; Li, Y. F.; Louisia, S.; Qi, Z. Y.; Somorjai, G. A.; Frei, H.; Wang, L. W. W.; et al. Nat. Energy 2020, 5 (12), 1032. doi: 10.1038/s41560-020-00730-4
108. [108]
  Wu, Q. B.; Liang, J. W.; Xiao, M. J.; Long, C.; Li, L.; Zeng, Z. H.; Mavrič, A.; Zheng, X.; Zhu, J.; Liang, H. W.; et al. Nat. Commun. 2023, 14 (1), 997. doi: 10.1038/s41467-023-36718-3
109. [109]
  Lim, C. Y. J.; Yilmaz, M.; Arce-Ramos, J. M.; Handoko, A. D.; Teh, W. J.; Zheng, Y.; Khoo, Z. H. J.; Lin, M.; Isaacs, M.; Tam, T. L. D.; et al. Nat. Commun. 2023, 14 (1), 335. doi: 10.1038/s41467-023-35912-7
110. [110]
  Wang, T.; Zhang, Y. R.; Huang, B. T.; Cai, B.; Rao, R. R.; Giordano, L.; Sun, S. G.; Shao-Horn, Y. Nat. Catal. 2021, 4 (9), 753. doi: 10.1038/s41929-021-00668-0
111. [111]
  Huang, W. Z.; Li, J. T.; Liao, X. B.; Lu, R. H.; Ling, C. H.; Liu, X.; Meng, J. S.; Qu, L. B.; Lin, M. T.; Hong, X. F.; et al. Adv. Mater. 2022, 34 (18), 2200270. doi: 10.1002/adma.202200270
112. [112]
  Li, F. W.; Li, Y. G. C.; Wang, Z. Y.; Li, J.; Nam, D. H.; Lum, Y.; Luo, M. C.; Wang, X.; Ozden, A.; Hung, S. F.; et al. Nat. Catal. 2020, 3 (1), 75. doi: 10.1038/s41929-019-0383-7
113. [113]
  Omura, J.; Yano, H.; Watanabe, M.; Uchida, H. Langmuir 2011, 27 (10), 6464. doi: 10.1021/la200694a
114. [114]
  Monteiro, M. C. O.; Dattila, F.; Hagedoorn, B.; García-Muelas, R.; López, N.; Koper, M. T. M. Nat. Catal. 2021, 4 (8), 654. doi: 10.1038/s41929-021-00655-5
115. [115]
  Monteiro, M. C. O.; Dattila, F.; López, N.; Koper, M. T. M. J. Am. Chem. Soc. 2022, 144 (4), 1589. doi: 10.1021/jacs.1c10171
116. [116]
  Ringe, S.; Clark, E. L.; Resasco, J.; Walton, A.; Seger, B.; Bell, A. T.; Chan, K. Energy Environ. Sci. 2019, 12 (10), 3001. doi: 10.1039/C9EE01341E
117. [117]
  Resasco, J.; Chen, L. D.; Clark, E.; Tsai, C.; Hahn, C.; Jaramillo, T. F.; Chan, K.; Bell, A. T. J. Am. Chem. Soc. 2017, 139 (32), 11277. doi: 10.1021/jacs.7b06765
118. [118]
  Malkani, A. S.; Li, J.; Oliveira, N. J.; He, M.; Chang, X.; Xu, B.; Lu, Q. Sci. Adv. 2020, 6 (45), eabd2569. doi: 10.1126/sciadv.abd2569
119. [119]
  Zhao, Y.; Xu, J. P.; Huang, K.; Ge, W. X.; Liu, Z.; Lian, C.; Liu, H. L.; Jiang, H. L.; Li, C. Z. J. Am. Chem. Soc. 2023, 145 (11), 6516. doi: 10.1021/jacs.3c00565
120. [120]
  Nam, D. H.; De Luna, P.; Rosas-Hernández, A.; Thevenon, A.; Li, F.; Agapie, T.; Peters, J. C.; Shekhah, O.; Eddaoudi, M.; Sargent, E. H. Nat. Mater. 2020, 19 (3), 266. doi: 10.1038/s41563-020-0610-2
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