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Citation: Jiahui YU, Jixian DONG, Yutong ZHAO, Fuping ZHAO, Bo GE, Xipeng PU, Dafeng ZHANG. The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO4:Yb3+,Er3+ photocatalyst[J]. Journal of Fuel Chemistry and Technology, ;2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1 shu

The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO4:Yb3+,Er3+ photocatalyst

  • School of Materials Science and Engineering, Liaocheng University, Liaocheng 252000, China

  • Corresponding author: Dafeng ZHANG, dafengzh@hotmail.com
  • Received Date: 1 September 2024
    Revised Date: 7 November 2024
    Accepted Date: 11 November 2024
    Available Online: 24 March 2025

Figures(10)

  • By adjusting the pH value of the precursor solution, different morphologies of BiVO4:Yb3+,Er3+-X (BYE-X) were successfully synthesized via a facile microwave hydrothermal method. Tetracycline was employed as a model pollutant to evaluate the full-spectrum photocatalytic activity of BYE-X samples. The experimental results revealed that when the pH ranged from 3 to 8, BYE showed pure monoclinic BiVO4 phase. At pH values of 10−12, the synthesized samples had mixed phases of Bi2O(OH)(VO4), Bi2O3, and BiVO4. A notable variation in the morphological characteristics of BYE was observed with the increasing pH values. The samples of different pH values showed obvious up-conversion luminescence. Due to the up-conversion of Er3+ and Yb3+, the near-infrared (NIR) light was effectively utilized, successfully broadening the light response range. Under the visible or NIR light irradiation, BYE-5 demonstrated the optimal photodegradation activity. Based on the experimental results, a mechanism for full-spectrum photocatalysis was proposed. This work provides a feasible approach to improving the utilization of solar light by semiconductor catalysts, thereby achieving efficient full-spectrum photocatalytic activity.
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