Citation: Xiao-xing WANG, Yong-hong DUAN, Jun-feng ZHANG, Yi-sheng TAN. Catalytic conversion of CO₂ into high value-added hydrocarbons over tandem catalyst[J]. Journal of Fuel Chemistry and Technology, ;2022, 50(5): 538-563. doi: 10.1016/S1872-5813(21)60181-0 shu

Catalytic conversion of CO₂ into high value-added hydrocarbons over tandem catalyst

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
China Petroleum and Chemical Industry Federation, Beijing 100723, China

Corresponding author: Yong-hong DUAN, duanyh@cpcif.org.cn Yi-sheng TAN, tan@sxicc.ac.cn
Received Date: 24 September 2021
Revised Date: 5 November 2021
Accepted Date: 5 November 2021
Available Online: 9 June 2022

Figures(17)

The conversion of CO₂, an abundant carbon resource, into high value-added chemicals or liquid fuels is an attractive way to mitigate carbonemissions, which is also a sustainable approach for the cyclic utilization of carbon resources. However, the selective activation and controllable conversion of CO₂ is challenging because of the inertness of CO₂ and high C–C coupling barrier. In recent years, some obvious breakthroughs on CO₂ hydrogenation to high value-added chemicals or liquid fuels have been made by construction of a tandem catalytic system. For the tandem catalysis, the matching of Fe-based catalyst or metal oxides and zeolites, the assembly between the two active sites, the pore structure and acidity of the zeolites, as well as the reaction conditions and atmosphere all have important effects on the product distribution. Herein, the critical factors affecting the CO₂ activation and conversion and the formation of the target products, as well as the stability over the tandem catalysts are summarized. Finally, an outlook is provided.
- CO₂ hydrogenation,
- catalytic conversion,
- high value-added hydrocarbons,
- tandem catalysis,
- active sites
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沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic conversion of CO2 into high value-added hydrocarbons over tandem catalyst

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通讯作者: 陈斌, bchen63@163.com

Catalytic conversion of CO₂ into high value-added hydrocarbons over tandem catalyst