Citation: Xuan QU, Qin-fen WANG, Shuai YAN, Jun FENG, Jian-shu ZHANG, Rong ZHANG, Ji-cheng BI. The behavior of the different catalysts for model carbon hydrogasification[J]. Journal of Fuel Chemistry and Technology, ;2022, 50(1): 1-10. doi: 10.1016/S1872-5813(21)60136-6 shu

The behavior of the different catalysts for model carbon hydrogasification

Xuan QU ^1, ,
Qin-fen WANG ² ,
Shuai YAN ³ ,
Jun FENG ^{1, 4} ,
Jian-shu ZHANG ^2,, ,
Rong ZHANG ^1,, ,
Ji-cheng BI ¹

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
School of Chemistry and Chemical Engineering/Key Laboratory for Green Process of Chemical Engineering of Xinjiang Bingtuan-Provincial Ministry of Education to Build a National Key Laboratory Breeding Base, Shihezi University, Shihezi 832003, China
3.
Department of Energy and Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China
4.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Jian-shu ZHANG, zjschem@163.com Rong ZHANG, zrbd@sxicc.ac.cn
Received Date: 11 June 2021
Revised Date: 2 July 2021

Figures(10)

The catalytic hydrogasification of activated carbon/bituminous char/anthracite char with the different catalysts were performed in a pressurized thermogravimetry analysis (PTGA). The GC, BET were used to characterize the physical structure and chemical reaction process of carbon. The function principle of Co to the carbon-hydrogen reaction was preliminarily obtained. The results showed that the catalytic activity of transition metals (Fe, Co, Ni) was significantly better than that of alkali metals and alkaline earth metals during the process of activated carbon hydrogasification. There were two catalytic zones of low temperature (600−750 ℃) and high temperature (> 800 ℃) in the catalytic process. The emergence of the low temperature catalytic zone could be attributed to the interaction between the transition metal oxides and carbon. The transition metal was embedded in carbon layer structure during the activated carbon hydrogasification, then parts of carbon structure was activated, resulting in the cleavage of carbon-carbon bonds. The adequate active hydrogen could be supplied by Co at 850 ℃ when the pressure was beyond 1 MPa. Briefly, the reaction temperature was the crucial factor for the cleavage of carbon-carbon bonds. The model carbon with higher specific surface area and weaker carbon structure could be converted efficiently even with lower loading amount of catalyst.
- model carbon,
- catalytic hydrogasification,
- PTGA
1. [1]
  YAN Shuai, XIA Zi-hong, CHEN Cai-xia, QU Xuan, BI Ji-cheng. Research progress on the technology of coal catalytic hydrogasification[J]. Clean Coal Technol,2021,27(1):60−72.
2. [2]
  TAMAI Y, WATANABE H, TOMITA A. Catalytic gasification of carbon with steam carbon-dioxide and hydrogen[J]. Carbon,1977,15(2):103−106. doi: 10.1016/0008-6223(77)90024-0
3. [3]
  LEE S H, LEE J G, KIM J H, CHOI Y C. Hydrogasification characteristics of bituminous coals in an entrained-flow hydrogasifier[J]. Fuel,2006,85(5/6):803−806. doi: 10.1016/j.fuel.2005.08.039
4. [4]
  TOMITA A, HIGASHIYAMA K, TAMAI Y. Scanning electron-microscopic study on the catalytic gasification of coal[J]. Fuel,1981,60(2):103−114. doi: 10.1016/0016-2361(81)90003-X
5. [5]
  YUAN S F, ZHANG N, QU X, BI J C, CAO Q, WANG J L. Promoted catalysis of calcium on the hydrogasification reactivity of iron-loaded subbituminous coal[J]. Fuel,2017,200:153−161. doi: 10.1016/j.fuel.2017.03.066
6. [6]
  HAGA T, NISHIYAMA Y. Enhancements in nickel-catalyzed hydrogasification of carbon by surface treatments[J]. Carbon,1983,21(3):219−223. doi: 10.1016/0008-6223(83)90083-0
7. [7]
  SUZUKI T, IWASAKI J, TANKA K, OKAZAKI N, FUNAKI M, YAMADA T. Influence of calcium on the catalytic behavior of nickel in low temperature hydrogasification of wood char[J]. Fuel,1998,77(7):763−767. doi: 10.1016/S0016-2361(97)00240-8
8. [8]
  JIANG J T, LIU Q Y, LIU Z Y. Superior catalytic effect of calcium oxide on the hydrogasification of char for CH₄[J]. Fuel,2016,180:737−742. doi: 10.1016/j.fuel.2016.04.093
9. [9]
  MATSUMOTO S, SAKAGAMI S. Catalytic gasification activity of iron enhanced by spilt-over hydrogen[J]. Stud Surf Sci Catal,1993,77:409−412.
10. [10]
  HAGA T, NISHIYAMA Y. Promotion of iron-group catalysts by a calcium salt in hydrogasification of coal chars[J]. Ind Eng Chem Res,1989,28(6):724−728. doi: 10.1021/ie00090a013
11. [11]
  LIU X H, XIONG B, HUANG X H, DING H R, ZHENG Y, LIU Z H, ZHENG C G. Effect of catalysts on char structural evolution during hydrogasification under high pressure[J]. Fuel,2017,188:474−482. doi: 10.1016/j.fuel.2016.10.053
12. [12]
  MATSUMOTO S. Catalyzed hydrogasification of Yallourn char in the presence of supported hydrogenation nickel catalyst[J]. Energy Fuels,1991,5(1):60−63. doi: 10.1021/ef00025a009
13. [13]
  NISHIYAMA Y. Catalytic behaviour of iron and nickel in coal gasification[J]. Fuel,1986,65(10):1404−1409. doi: 10.1016/0016-2361(86)90114-6
14. [14]
  HONG B Q, WANG X J, ZHOU Z J, YU G S. A comparison of the gas-product-release characteristics from coal pyrolysis and hydrogasification[J]. Energy Technol,2013,1:449−456. doi: 10.1002/ente.201300052
15. [15]
  JIANG J T, LIU Z Y, LIU Q Y. Synergetic catalysis of calcium oxide and iron in hydrogasification of char[J]. Energy Fuels,2017,31:198−204. doi: 10.1021/acs.energyfuels.6b02026
16. [16]
  ZHAN Shu-peng, WANG Xing-jun, HONG Bing-qing, YU Guang-suo, WANG Fu-chen. Experimental study on catalytic hydrogasification of lignite[J]. J Fuel Chem Technol,2012,40(1):8−14. doi: 10.3969/j.issn.0253-2409.2012.01.002
17. [17]
  ZHANG Feng, SUN Hao, ZHANG Jian-shu, YAN Shuai, QU Xuan, ZHANG Rong, BI Ji-cheng. Effect of dispersion degree of iron on catalytic hydrogasification of coal char[J]. J Fuel Chem Technol,2019,47(4):402−410.
18. [18]
  HAGA T, NISHIYAMA Y. Promotion of iron-group catalysts by a calcium salt in hydrogasification of carbons at elevated pressures[J]. Ind Eng Chem Res,1987,26(6):1202−1206. doi: 10.1021/ie00066a023
19. [19]
  WU X T, TANG J, WANG J. A new active site/intermediate kinetic model for K₂CO₃-catalyzed steam gasification of ash-free coal char[J]. Fuel,2016,165:59−67. doi: 10.1016/j.fuel.2015.10.034
20. [20]
  ZOHEIDI H, MILLER D J. Role of oxygen surface groups in catalysis of hydrogasification of carbon black by potassium carbonate[J]. Carbon,1987,25(6):809−819. doi: 10.1016/0008-6223(87)90156-4
21. [21]
  OHTSUKA Y, TAMAI Y, TOMITA A. Iron-catalyzed gasification of brown coal at low temperatures[J]. Energy Fuels,1987,1(1):32−36. doi: 10.1021/ef00001a006
22. [22]
  TOMITA A, TAMAI Y. Hydrogenation of carbons catalyzed by transition metals[J]. J Catal,1972,27(2):293−300. doi: 10.1016/0021-9517(72)90271-0
23. [23]
  HAGA T, OZAKI J I, SUZUKI K, NISHIYAMA Y. Role of MgO and CaO promoters in Ni-catalyzed hydrogenation reactions of CO and carbon[J]. J Catal,1992,134(1):107−117. doi: 10.1016/0021-9517(92)90214-3
24. [24]
  YAN S, ZHANG J S, YAN X Q, PAN D F, REN H, QU X. Catalytic coal hydrogasification by cobalt-calcium catalyst in a pressurized fluidized bed: role of hydropyrolysis and catalysis Process[J]. J Anal Appl Pyrolysis,2018,135:251−259. doi: 10.1016/j.jaap.2018.08.028
25. [25]
  YAN Shuai. Fundamental study on coal catalytic hydrogasification in a pressurized fluidized bed[D]. Taiyuan: Institute of Coal Chemistry, Chinese Academy of Sciences, 2019.
26. [26]
  YUAN S F, QU X, ZHANG R, BI J C. Effect of calcium additive on product yields in hydrogasification of nickel-loaded Chinese sub-bituminous coal[J]. Fuel,2015,147:133−140. doi: 10.1016/j.fuel.2015.01.004
27. [27]
  YAN S, BI J C, QU X. The behavior of catalysts in hydrogasification of sub-bituminous coal in pressured fluidized bed[J]. Appl Energy,2017,206:401−412. doi: 10.1016/j.apenergy.2017.08.189
28. [28]
  SILVA I F, MCKEE D W, LOBO L S. A kinetic and in situ XRD study of carbon reactions catalyzed by nickel, cobalt, molybdenum, and their mixtures[J]. J Catal,1997,170(1):54−61. doi: 10.1006/jcat.1997.1723
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