Citation: Xiaolong Wang, Guojun Lan, Zaizhe Cheng, Wenfeng Han, Haodong Tang, Huazhang Liu, Ying Li. Carbon-supported ruthenium catalysts prepared by a coordination strategy for acetylene hydrochlorination[J]. Chinese Journal of Catalysis, ;2020, 41(11): 1683-1691. doi: 10.1016/S1872-2067(20)63616-6 shu

Carbon-supported ruthenium catalysts prepared by a coordination strategy for acetylene hydrochlorination

Institute of Industrial Catalysis, Zhejiang University of Technology, Hangzhou 310032, Zhejiang, China

Received Date: 13 February 2020
Revised Date: 24 March 2020

Fund Project: This work was supported by the National Natural Science Foundation of China (21908197).

The development of efficient and stable non-mercury catalysts for the chlor-alkali industry is desirable but remains a great challenge. Herein, we design a series of ruthenium catalysts for acetylene hydrochlorination by regulating the electronic structure of ruthenium ions through coordination with various ligands (thiourea, phenanthroline, and L-lactic). The turnover frequencies (TOFs) and apparent activation energies for the acetylene hydrochlorination have a linear relationship with the binding energy of Ru³⁺ in the ruthenium catalysts. The synergetic effect of the ruthenium ion and ligands plays an important role in acetylene hydrochlorination. The Ru-Thi/AC catalyst with thiourea as the ligand shows the highest TOF and stability in acetylene hydrochlorination. The present study provides a rational method to regulate the electronic structure of supported metal catalysts with high catalytic performance exhibited by the carbon-supported heterogeneous catalysts.
- Ruthenium catalyst,
- Ligand,
- Electronic structure,
- Synergetic effect,
- Acetylene hydrochlorination
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
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