Citation: Hua Liu, Mengqian Chai, Guangxian Pei, Xiaoyan Liu, Lin Li, Leilei Kang, Aiqin Wang, Tao Zhang. Effect of IB-metal on Ni/SiO₂ catalyst for selective hydrogenation of acetylene[J]. Chinese Journal of Catalysis, ;2020, 41(7): 1099-1108. doi: 10.1016/S1872-2067(20)63568-9 shu

Effect of IB-metal on Ni/SiO₂ catalyst for selective hydrogenation of acetylene

Hua Liu ^a,b, ,
Mengqian Chai ^a,b ,
Guangxian Pei ^a,b ,
Xiaoyan Liu ^a ,
Lin Li ^a ,
Leilei Kang ^a ,
Aiqin Wang ^a ,
Tao Zhang ^a,b

a CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 12 October 2019

Fund Project: We are grateful for the support from the National Key R&D Program of China (2016YFA0202801), the Strategic Priority Research Program of Chinese Academy of Sciences (XDB17020400), the National Natural Science Foundation of China (21776271), and the China Postdoctoral Science Foundation (2017M621171).

The IB metal (Au, Ag and Cu) alloyed Pd single atom catalysts had been proved to be efficient in promoting the selectivity for hydrogenation of acetylene to ethylene. As a base metal in the same group as Pd, the Ni-based catalysts are also active for hydrogenation reactions. Herein, the effects of the IB metals on the Ni/SiO₂ catalyst for the selective hydrogenation of acetylene were systematically studied. Different from the Pd/SiO₂ catalyst, the monometallic Ni/SiO₂ catalyst is not active at low temperatures. The addition of the IB metals to the Ni/SiO₂ catalysts can greatly enhance the activity. Besides, the catalytic activity of the AgNi_{x/SiO₂ and CuNix/SiO₂ catalysts increase with the reduction temperature, while the AgNi_x/SiO₂ catalysts are not sensitive to the pretreatment temperature. The origin of the effect of the different IB metals on the Ni-based catalysts for selective hydrogenation of acetylene is discussed based on the characterizations by XRD, TPR and microcalorimetric measurements.}
- Acetylene,
- Selective hydrogenation,
- Ethylene,
- Ni,
- IB metals
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Effect of IB-metal on Ni/SiO2 catalyst for selective hydrogenation of acetylene

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Effect of IB-metal on Ni/SiO₂ catalyst for selective hydrogenation of acetylene