Citation: Shunji Xie, Haikun Zhang, Guodong Liu, Xuejiao Wu, Jinchi Lin, Qinghong Zhang, Ye Wang. Tunable localized surface plasmon resonances in MoO_3-x-TiO₂ nanocomposites with enhanced catalytic activity for CO₂ photoreduction under visible light[J]. Chinese Journal of Catalysis, ;2020, 41(7): 1125-1131. doi: 10.1016/S1872-2067(20)63566-5 shu

Tunable localized surface plasmon resonances in MoO_3-x-TiO₂ nanocomposites with enhanced catalytic activity for CO₂ photoreduction under visible light

State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China

Received Date: 24 September 2019

Fund Project: This work was supported by the National Key Research and Development Program of Ministry of Science and Technology (2017YFB0602201), the National Natural Science Foundation of China (21433008, 91545203, 21503176), and the China Postdoctoral Science Foundation (2015M570555, 2016T90597).

The photocatalytic reduction of CO₂ with H₂O to fuels and chemicals using solar energy is one of the most attractive but highly difficult routes. Thus far, only a very limited number of photocatalysts has been reported to be capable of catalyzing the photocatalytic reduction of CO₂ under visible light. The utilization of the localized surface plasmon resonance (LSPR) phenomenon is an attractive strategy for developing visible-light photocatalysts. Herein, we have succeeded in synthesizing plasmonic MoO_3-x-TiO₂ nanocomposites with tunable LSPR by a simple solvothermal method. The well-structured nanocomposite containing two-dimensional (2D) molybdenum oxide (MoO_3-x) nanosheets and one-dimensional (1D) titanium oxide nanotubes (TiO₂-NT) showed LSPR absorption band in the visible-light region, and the incorporation of TiO₂-NT significantly enhanced the LSPR absorption band. The MoO_3-x-TiO₂-NT nanocomposite is promising for application in the photocatalytic reduction of CO₂ with H₂O under visible light irradiation.
- Photocatalysis,
- Carbon dioxide,
- Visible light,
- Localized surface plasmon resonance,
- MoO_3-x-TiO₂ nanocomposite
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
1. [1]
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2. [2]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
3. [3]
  Hailian Cheng , Shuaiqiang Jia , Chunjun Chen , Haihong Wu , Buxing Han . Electrocatalytic CO₂ Conversion: A Key to Unlocking a Low-Carbon Future. University Chemistry, 2026, 41(2): 1-13. doi: 10.12461/PKU.DXHX202502023
4. [4]
  Jiayi Yang , Jianxiu Hao , Huacong Zhou , Quansheng Liu . “Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles. University Chemistry, 2026, 41(2): 178-189. doi: 10.12461/PKU.DXHX202502105
5. [5]
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6. [6]
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7. [7]
  Xinyu Xu , Jiale Lu , Bo Su , Jiayi Chen , Xiong Chen , Sibo Wang . Steering charge dynamics and surface reactivity for photocatalytic selective methane oxidation to ethane over Au/Ti-CeO₂. Acta Physico-Chimica Sinica, 2025, 41(11): 100153-0. doi: 10.1016/j.actphy.2025.100153
8. [8]
  Xiaolong Li , Shiqi Zhong , Xiangfeng Wei , Zhiqiang Liu , Pan Zhan , Jiehua Liu . Carbon Dioxide: From the Past to the Future. University Chemistry, 2026, 41(2): 242-247. doi: 10.12461/PKU.DXHX202503013
9. [9]
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10. [10]
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11. [11]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
12. [12]
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13. [13]
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14. [14]
  Ronghui LI . Photocatalysis performance of nitrogen-doped CeO₂ thin films via ion beam-assisted deposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1123-1130. doi: 10.11862/CJIC.20240440
15. [15]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
16. [16]
  Huiying ZHANG , Ping LI , Weixia DONG , Zhiwen HU , Qifu BAO , Qizheng DONG , Mingmin BAI , Wenqi LI . Photocatalytic performance of spheroidal nano Bi₄Ti₃O₁₂ prepared by surfactant-assisted hydrothermal reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 551-561. doi: 10.11862/CJIC.20250269
17. [17]
  Ze Luo , Yukun Zhu , Yadan Luo , Guangmin Ren , Yonghong Wang , Hua Tang . Photocatalytic selective oxidation of 5-hydroxymethylfurfural coupled with H₂ evolution over In₂O₃/ZnIn₂S₄ S-scheme heterojunction. Acta Physico-Chimica Sinica, 2026, 42(3): 100166-0. doi: 10.1016/j.actphy.2025.100166
18. [18]
  Jiayao Wang , Guixu Pan , Ning Wang , Shihan Wang , Yaolin Zhu , Yunfeng Li . Preparation of donor-π-acceptor type graphitic carbon nitride photocatalytic systems via molecular level regulation for high-efficient H₂O₂ production. Acta Physico-Chimica Sinica, 2025, 41(12): 100168-0. doi: 10.1016/j.actphy.2025.100168
19. [19]
  Honghong Zhang , Zhen Wei , Derek Hao , Lin Jing , Yuxi Liu , Hongxing Dai , Weiqin Wei , Jiguang Deng . 非均相催化CO₂与烃类协同催化转化的最新进展. Acta Physico-Chimica Sinica, 2025, 41(7): 100073-0. doi: 10.1016/j.actphy.2025.100073
20. [20]
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Tunable localized surface plasmon resonances in MoO3-x-TiO2 nanocomposites with enhanced catalytic activity for CO2 photoreduction under visible light

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通讯作者: 陈斌, bchen63@163.com

Tunable localized surface plasmon resonances in MoO_3-x-TiO₂ nanocomposites with enhanced catalytic activity for CO₂ photoreduction under visible light