Citation: Panpan Wang, Jiahao Duan, Jie Wang, Fuming Mei, Peng Liu. Elucidating structure-performance correlations in gas-phase selective ethanol oxidation and CO oxidation over metal-doped γ-MnO₂[J]. Chinese Journal of Catalysis, ;2020, 41(8): 1298-1310. doi: 10.1016/S1872-2067(20)63551-3 shu

Elucidating structure-performance correlations in gas-phase selective ethanol oxidation and CO oxidation over metal-doped γ-MnO₂

Key Laboratory of Material Chemistry for Energy Conversion and Storage(Ministry of Education), Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei, China

Received Date: 3 December 2019
Revised Date: 25 December 2019

Fund Project: This work was supported by the National Natural Science Foundation of China (21673088, 21972050).

Despite of considerable efforts on the MnO₂-based catalytic combustion, the different structural and component requirements of MnO₂ for gas-phase selective oxidation and complete oxidation largely remain unknown. By comparing four types of MnO₂ with different crystal structures (α, β, γ and δ), γ-MnO₂ was found to be the most efficient catalyst for both aerobic selective oxidation of ethanol and CO oxidation. The structural effect of γ-MnO₂ was further investigated by doping metal ions into the framework and by comparing the catalytic performance in the gas-phase aerobic oxidation of CO and ethanol. Among ten M-γ-MnO₂ catalysts, Zn-γ-MnO₂ showed the lowest temperature (160℃) for achieving 90% CO conversion. The CO oxidation activity of the M-γ-MnO₂ catalysts was found to be more relevant to the surface acidity-basicity than the reducibility. In contrast, surface reducibility has been demonstrated to be more crucial in the gas-phase ethanol oxidation. Cu-γ-MnO₂ with higher reducibility and more oxygen vacancies of Mn²⁺/Mn³⁺ species exhibited higher catalytic activity in the selective ethanol oxidation. Cu-γ-MnO₂ achieved the highest acetaldehyde yield (75%) and space-time-yield (5.4 g g_cat^-1 h^-1) at 200℃, which are even comparable to the results obtained by the state-of-the-art silver and gold-containing catalysts. Characterization results and kinetic studies further suggest that the CO oxidation follows the lattice oxygen-based Mars-van Krevelen mechanism, whereas both surface lattice oxygen and adsorbed oxygen species involve in the ethanol activation.
- MnO₂,
- Metal doping,
- Ethanol oxidation,
- Acetaldehyde,
- Catalytic CO oxidation
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
1. [1]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
2. [2]
  Lijun Yue , Siya Liu , Peng Liu . 不同晶相纳米MnO₂的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005
3. [3]
  Huiwei Ding , Bo Peng , Zhihao Wang , Qiaofeng Han . Advances in Metal or Nonmetal Modification of Bismuth-Based Photocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2305048-0. doi: 10.3866/PKU.WHXB202305048
4. [4]
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5. [5]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
6. [6]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
  Qiang Zhang , Yuanbiao Huang , Rong Cao . Imidazolium-Based Materials for CO₂ Electroreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306040-0. doi: 10.3866/PKU.WHXB202306040
11. [11]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-Based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-0. doi: 10.3866/PKU.WHXB202406029
12. [12]
  Mingjie Lei , Wenting Hu , Kexin Lin , Xiujuan Sun , Haoshen Zhang , Ye Qian , Tongyue Kang , Xiulin Wu , Hailong Liao , Yuan Pan , Yuwei Zhang , Diye Wei , Ping Gao . Accelerating the reconstruction of NiSe₂ by Co/Mn/Mo doping for enhanced urea electrolysis. Acta Physico-Chimica Sinica, 2025, 41(8): 100083-0. doi: 10.1016/j.actphy.2025.100083
13. [13]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
14. [14]
  Yan Kong , Wei Wei , Lekai Xu , Chen Chen . Electrochemical Synthesis of Organonitrogen Compounds from N-integrated CO₂ Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(8): 2307049-0. doi: 10.3866/PKU.WHXB202307049
15. [15]
  Yanhui Guo , Li Wei , Zhonglin Wen , Chaorong Qi , Huanfeng Jiang . Recent Progress on Conversion of Carbon Dioxide into Carbamates. Acta Physico-Chimica Sinica, 2024, 40(4): 2307004-0. doi: 10.3866/PKU.WHXB202307004
16. [16]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
17. [17]
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18. [18]
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19. [19]
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20. [20]
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沈阳化工大学材料科学与工程学院沈阳 110142

Elucidating structure-performance correlations in gas-phase selective ethanol oxidation and CO oxidation over metal-doped γ-MnO2

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通讯作者: 陈斌, bchen63@163.com

Elucidating structure-performance correlations in gas-phase selective ethanol oxidation and CO oxidation over metal-doped γ-MnO₂