Citation: Yan Zhou, Aling Chen, Jing Ning, Wenjie Shen. Electronic and geometric structure of the copper-ceria interface on Cu/CeO₂ catalysts[J]. Chinese Journal of Catalysis, ;2020, 41(6): 928-937. doi: 10.1016/S1872-2067(20)63540-9 shu

Electronic and geometric structure of the copper-ceria interface on Cu/CeO₂ catalysts

State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received Date: 21 October 2019
Revised Date: 29 November 2019

Fund Project: This work was supported by the National Natural Science Foundation of China (21761132031, 21533009, 91645107, 21621063).

The atomic structure of the active sites in Cu/CeO₂ catalystsis intimately associated with the copper-ceria interaction. Both the shape of ceria and the loading of copper affect the chemical bonding of copper species on ceria surfaces and the electronic and geometric character of the relevant interfaces. Nanostructured ceria, including particles (polyhedra), rods, and cubes, provides anchoring sites for the copper species. The atomic arrangements and chemical properties of the (111), (110) and (100) facets, preferentially exposed depending on the shape of ceria, govern the copper-ceria interactions and in turn determine their catalytic properties. Also, the metal loading significantly influences the dispersion of copper species on ceria with a specific shape, forming copper layers, clusters, and nanoparticles. Lower copper contents result in copper monolayers and/or bilayers while higher copper loadings lead to multi-layered clusters and faceted particles. The active sites are usually generated via interactions between the copper atoms in the metal species and the oxygen vacancies on ceria, which is closely linked to the number and density of surface oxygen vacancies dominated by the shape of ceria.
- Cu/CeO₂ catalyst,
- Ceria shape,
- Oxygen vacancy,
- Copper particle,
- Copper-ceria interface
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
51. [51]
52. [52]
53. [53]
54. [54]
55. [55]
56. [56]
57. [57]
58. [58]
59. [59]
60. [60]
61. [61]
62. [62]
63. [63]
64. [64]
65. [65]
66. [66]
67. [67]
68. [68]
69. [69]
70. [70]
71. [71]
72. [72]
1. [1]
  Yushan Cai , Fang-Xing Xiao . Revisiting MXenes-based Photocatalysis Landscape: Progress, Challenges, and Future Perspectives. Acta Physico-Chimica Sinica, 2024, 40(8): 2306048-0. doi: 10.3866/PKU.WHXB202306048
2. [2]
  Jinglin CHENG , Xiaoming GUO , Tao MENG , Xu HU , Liang LI , Yanzhe WANG , Wenzhu HUANG . NiAlNd catalysts for CO₂ methanation derived from the layered double hydroxide precursor. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1592-1602. doi: 10.11862/CJIC.20240152
3. [3]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
4. [4]
  Gaopeng Liu , Lina Li , Bin Wang , Ningjie Shan , Jintao Dong , Mengxia Ji , Wenshuai Zhu , Paul K. Chu , Jiexiang Xia , Huaming Li . Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(7): 2306041-0. doi: 10.3866/PKU.WHXB202306041
5. [5]
  Kezhen Qi , Bei Cheng , Kaiqiang Xu . Ultrafast interfacial charge transfer promoted by the LSPR of Au nanoparticles for photocatalytic H₂ evolution. Acta Physico-Chimica Sinica, 2026, 42(3): 100205-0. doi: 10.1016/j.actphy.2025.100205
6. [6]
  Congqi Zhu , Bo Liu , Ruchun Li . Dual active sites enhancing alkaline H₂-production performance. Acta Physico-Chimica Sinica, 2025, 41(11): 100146-0. doi: 10.1016/j.actphy.2025.100146
7. [7]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
8. [8]
  Xiaorui Chen , Xuan Luo , Tongming Su , Xinling Xie , Liuyun Chen , Yuejing Bin , Zuzeng Qin , Hongbing Ji . Ga-doped Cu/γ-Al₂O₃ bifunctional interface sites promote the direct hydrogenation of CO₂ to DME. Acta Physico-Chimica Sinica, 2025, 41(10): 100126-0. doi: 10.1016/j.actphy.2025.100126
9. [9]
  Peng Li , Yuanying Cui , Zhongliao Wang , Graham Dawson , Chunfeng Shao , Kai Dai . Efficient interfacial charge transfer of CeO₂/Bi₁₉Br₃S₂₇ S-scheme heterojunction for boosted photocatalytic CO₂ reduction. Acta Physico-Chimica Sinica, 2025, 41(6): 100065-0. doi: 10.1016/j.actphy.2025.100065
10. [10]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
11. [11]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
12. [12]
  Jie WEI , Qing ZHOU , Dandan DING , Xiang JING , Fei LI . Photothermal toxicity of Prussian blue nanoparticles to cervical cancer cells. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2345-2357. doi: 10.11862/CJIC.20240435
13. [13]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
14. [14]
  Min ZHAO , Tingxu LIU , Ye WANG , Xianghe CHEN , Buhui LIU , Manman XIE , Cuiping HAN . Antioxidant activity of ultra-small quercetin nanoprobes under imaging guidance. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1495-1504. doi: 10.11862/CJIC.20260016
15. [15]
  Zuoyong Li , Haoxiang Tu , Mingwei Ding , Meijun Liu , Ting Yang . Innovative Teaching Reform Study on the Synthesis of Silver Nanoparticles Based on Machine Learning and Microfluidic Technology. University Chemistry, 2026, 41(1): 64-75. doi: 10.12461/PKU.DXHX202505088
16. [16]
  Xinyu Xu , Changjin Ou , Chunxia Kong , Weiliang Tian , Huaming Wang , Haijiao Wang , Tao Tao . 近红外有机纳米粒子的合成及性质研究虚拟仿真实验. University Chemistry, 2026, 41(8): 350-362. doi: 10.12461/PKU.DXHX202507032
17. [17]
  Weihao LI , Fangzhou JIA , Ying SONG , Yunsong XU , Guifeng LU , Xinzhi WANG , Zhongping YAO . Micro/nano hierarchical MoS₂/Ni₃S₂@nickel foam porous composite photothermal material: Preparation and interfacial evaporation performance. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1190-1202. doi: 10.11862/CJIC.20250365
18. [18]
  Gang Lang , Jing Feng , Bo Feng , Junlan Hu , Zhiling Ran , Zhiting Zhou , Zhenju Jiang , Yunxiang He , Junling Guo . Supramolecular phenolic network-engineered C–CeO₂ nanofibers for simultaneous determination of isoniazid and hydrazine in biological fluids. Chinese Chemical Letters, 2024, 35(6): 109113-. doi: 10.1016/j.cclet.2023.109113
19. [19]
  Runran WANG , Qiyue JIAO , Ruifang LI , Hong WANG , Hongwei WANG , Yali BAO , Qi WANG , Xiaoyan WANG . Influence of the loading methods of Ni species in Ni/CeO₂ catalysts on the performance of CO methanation. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 1026-1038. doi: 10.11862/CJIC.20250364
20. [20]
  Zhixuan Li , Xinying Wang , Han Wu , Qingxiang Guan . Advances in preparation and modification strategies of CeO₂ nanozymes and potential clinical applications. Chinese Chemical Letters, 2026, 37(7): 111671-. doi: 10.1016/j.cclet.2025.111671

Get Citation

PDF

XML

Metrics

PDF Downloads(51)
Abstract views(2790)
HTML views(533)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Electronic and geometric structure of the copper-ceria interface on Cu/CeO2 catalysts

Metrics

通讯作者: 陈斌, bchen63@163.com

Electronic and geometric structure of the copper-ceria interface on Cu/CeO₂ catalysts