Citation: Hui Hu, Qianqian Yan, Rile Ge, Yanan Gao. Covalent organic frameworks as heterogeneous catalysts[J]. Chinese Journal of Catalysis, ;2018, 39(7): 1167-1179. doi: 10.1016/S1872-2067(18)635057-8 shu

Covalent organic frameworks as heterogeneous catalysts

Hui Hu ^a, ,
Qianqian Yan ^a ,
Rile Ge ^b ,
Yanan Gao ^a,b

a Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources (Hainan University), Ministry of Education, Haikou 570228, Hainan, China;
b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received Date: 27 February 2018
Revised Date: 14 April 2018

Fund Project: The work was supported by the National Natural Science Foundation of China (21473196, 21406215), the State Key Laboratory of Fine Chemicals, Dalian University of Technology (KF1415) and the funding from Dalian Institute of Chemical Physics, Chinese Academy of Sciences (DICP_M201401).

Covalent organic frameworks (COFs), established as an emerging class of crystalline porous poly-mers with high surface area, structural diversity, and designability, attract much interest and exhibit potential applications in catalysis. In this review, we summarize the use of COFs as a versatile plat-form to develop heterogeneous catalysts for a variety of chemical reactions. Catalytic COFs are cat-egorized in accordance with the types of active sites, involving single functional active sites, bifunc-tional active sites, and metal nanoparticles (NPs) embedded in pores. Special emphasis is placed on the deliberate or incidental synthesis strategies, the stability, the heterogeneity, and the shape/size selectivity for COF catalysis. Moreover, a description of the application of COFs as photocatalysts and electrocatalysts is presented. Finally, the prospects of COFs in catalysis and remaining issues in this field are indicated.
- Covalent organic framework,
- Organic porous material,
- Catalyst,
- Catalyst support,
- Heterogeneous catalysis
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