Citation: Kaimin Du, Mengjia Hao, Zhinian Li, Wei Hong, Juanjuan Liu, Liping Xiao, Shihui Zou, Hisayoshi Kobayashi, Jie Fan. Tuning catalytic selectivity of propane oxidative dehydrogenation via surface polymeric phosphate modification on nickel oxide nanoparticles[J]. Chinese Journal of Catalysis, ;2019, 40(7): 1057-1062. doi: 10.1016/S1872-2067(18)63199-7 shu

Tuning catalytic selectivity of propane oxidative dehydrogenation via surface polymeric phosphate modification on nickel oxide nanoparticles

a Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, China;
b College of Materials & Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, Zhejiang, China;
c Department of Chemistry and Materials Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan

Received Date: 4 October 2018
Revised Date: 12 November 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (91545113, 21703050), the China Postdoctoral Science Foundation (2017M610363, 2018T110584), Shell Global Solutions International B. V. (PT71423, PT74557), the Fok Ying Tong Education Foundation (131015), and the Science & Technology Program of Ningbo (2017C50014).

Thermal stability has long been recognized as a major limitation for the application of ligand modification in high-temperature reactions. Herein, we demonstrate polymeric phosphate as an efficient and stable ligand to tune the selectivity of propane oxidative dehydrogenation. Beneficial from the weakened affinity of propene, NiO modified with polymeric phosphate shows a selectivity 2-3 times higher than NiO towards the production of propene. The success of this regulation verifies the feasibility of ligand modification in high-temperature gas-phase reactions and shines a light on its applications in other important industrial reactions.
- Nickel oxide nanoparticle,
- Surface polymeric phosphate,
- Propane oxidative dehydrogenation,
- Tuning selectivity,
- Adsorption
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