Citation: Xin Zhao, Qing-Da An, Zuo-Yi Xiao, Shang-Ru Zhai, Zhan Shi. One-step preparation of Fe_xO_y/N-GN/CNTs heterojunctions as a peroxymonosulfate activator for relatively highly-efficient methylene blue degradation[J]. Chinese Journal of Catalysis, ;2018, 39(11): 1842-1853. doi: 10.1016/S1872-2067(18)63114-6 shu

One-step preparation of Fe_xO_y/N-GN/CNTs heterojunctions as a peroxymonosulfate activator for relatively highly-efficient methylene blue degradation

a Faculty of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, Liaoning, China;
b State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, Jilin, China

Received Date: 13 April 2018
Revised Date: 28 May 2018

Fund Project: This work was supported by the National Natural Science Foun-dation of China (21676039), Innovative talents in Liaoning universities and colleges (LR2017045), and the Opening Foundation of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University (2016-04).

Persulfate decontamination technologies utilizing radical-driven processes are powerful tools for the treatment of a broad range of impurities. However, the design of high-performance catalytic activators with multi-functionality remains a great challenge. Therefore, in this study, three-dimensional multifunctional Fe_xO_y/N-GN/CNTs (N-GN:nitrogen-doped graphene, CNTs:carbon nanotubes) heterojunctions, which can be employed as microwave absorbers and catalysts, were synthesized via a solvothermal method and applied to activate peroxymonosulfate for the degradation of methylene blue (MB). X-ray diffraction (XRD), Fourier transform infrared spectrometer (FTIR), scanning electron microscope (SEM), and X-ray photoelectron microscopy (XPS) analyses revealed that the Fe_xO_y were anchored in-situ onto the N-GN network. Using MB as the model organic dye, various factors, such as degradation systems, PMS loading, initial organic pollutant concentration, and catalyst dosage were optimized. The results revealed that the remarkable efficiency was attributable to the synergistic effects of carbon, nitrogen, and iron-based species. The oxidation system corresponded to the pseudo-first-order kinetic with a k value of~0.33 min^-1. It was demonstrated that both SO₄^·- and OH^· were the predominant reactive species through quenching experiments. Because these heterojunctions were employed as microwave absorbers and have a semiconductor-like texture, the Fe/N co-rich hierarchical porous carbon skeleton favored electron transport and storage. These heterojunctions increase the options for transitional metal catalysts and highlights the importance of designing other heterojunctions for specific applications, such as supercapacitors, energy storage, CO₂ capture, and oxygen reduction electrocatalysts.
- Heterojunctions,
- Organic pollutant degradation,
- Nitrogen-doped graphene,
- Synergistic collaboration
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

One-step preparation of FexOy/N-GN/CNTs heterojunctions as a peroxymonosulfate activator for relatively highly-efficient methylene blue degradation

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通讯作者: 陈斌, bchen63@163.com

One-step preparation of Fe_xO_y/N-GN/CNTs heterojunctions as a peroxymonosulfate activator for relatively highly-efficient methylene blue degradation