Citation: Fangfang Gao, Hailong Liu, Xun Hu, Jing Chen, Zhiwei Huang, Chungu Xia. Selective hydrogenolysis of furfuryl alcohol to 1,5-and 1,2-pentanediol over Cu-LaCoO₃ catalysts with balanced Cu⁰-CoO sites[J]. Chinese Journal of Catalysis, ;2018, 39(10): 1711-1723. doi: 10.1016/S1872-2067(18)63110-9 shu

Selective hydrogenolysis of furfuryl alcohol to 1,5-and 1,2-pentanediol over Cu-LaCoO₃ catalysts with balanced Cu⁰-CoO sites

Fangfang Gao ^a,b, ,
Hailong Liu ^a ,
Xun Hu ^a ,
Jing Chen ^a ,
Zhiwei Huang ^a ,
Chungu Xia ^a

a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics(LICP), Chinese Academy of Sciences, Lanzhou 730000, Gansu, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 7 April 2018
Revised Date: 25 May 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (21473224), Key Research Project of Frontier Science of Chinese Academy of Sciences (QYZDJ-SSW-SLH051), the Youth Innovation Promotion Association, CAS (2016371), and the Suzhou Science and Technology Development Plan (SYG201626).

Selective hydrogenolysis of biomass-derived furfuryl alcohol (FFA) to 1,5-and 1,2-pentanediol (PeD) was conducted over Cu-LaCoO₃ catalysts with different Cu loadings; the catalysts were derived from perovskite structures prepared by a one-step citrate complexing method. The catalytic performances of the Cu-LaCoO₃ catalysts were found to depend on the Cu loading and pretreatment conditions. The catalyst with 10 wt% Cu loading exhibited the best catalytic performance after prereduction in 5% H₂-95% N₂, achieving a high FFA conversion of 100% and selectivity of 55.5% for 1,5-pentanediol (40.3%) and 1,2-pentanediol (15.2%) at 413 K and 6 MPa H₂. This catalyst could be reused four times without a loss of FFA conversion but it resulted in a slight decrease in pentanediol selectivity. Correlation between the structural changes in the catalysts at different states and the simultaneous variation in the catalytic performance revealed that cooperative catalysis between Cu⁰ and CoO promoted the hydrogenolysis of FFA to PeDs, especially to 1,5-PeD, while Co⁰ promoted the hydrogenation of FFA to tetrahydrofurfuryl alcohol (THFA). Therefore, it is suggested that a synergetic effect between balanced Cu⁰ and CoO sites plays a critical role in achieving a high yield of PeDs with a high 1,5-/1,2-pentanediol selectivity ratio during FFA hydrogenolysis.
- Furfuryl alcohol,
- Selective hydrogenolysis,
- Pentanediol,
- Cu-LaCoO₃ catalyst,
- Perovskite structure
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Selective hydrogenolysis of furfuryl alcohol to 1,5-and 1,2-pentanediol over Cu-LaCoO3 catalysts with balanced Cu0-CoO sites

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通讯作者: 陈斌, bchen63@163.com

Selective hydrogenolysis of furfuryl alcohol to 1,5-and 1,2-pentanediol over Cu-LaCoO₃ catalysts with balanced Cu⁰-CoO sites