Citation: Miao Jiang, Junying Chen, Yingwei Li. In situ doping brushite on zinc manganese oxide toward enhanced water oxidation performance: Mimicry of an oxygen-evolving complex[J]. Chinese Journal of Catalysis, ;2018, 39(6): 1017-1026. doi: 10.1016/S1872-2067(18)63075-X shu

In situ doping brushite on zinc manganese oxide toward enhanced water oxidation performance: Mimicry of an oxygen-evolving complex

State Key Laboratory of Pulp and Paper Engineering, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China

Received Date: 4 February 2018
Revised Date: 22 March 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (21436005, 21576095, 21706078), Fundamental Research Funds for the Central Universities (2017PY004, 2017MS088), the State Key Laboratory of Pulp and Paper Engineering (201710, 2017ZD04), China Postdoctoral Science Foundation (2016M590771, 2017T100625), Guangdong Natural Science Foundation (2016A050502004, 2016A030310413, 2017A030310029, 2017A030312005), and Science and Technology Program of Guangzhou (201804020009).

We report in situ doping of brushite on zinc manganese oxide (ZMO), fabricated by calcining a Mn(Ⅱ) oxalate-impregnated metal-organic framework. The doping process was conducted in combination with the photocatalytic water oxidation reaction which was catalyzed by ZMO in neutral phosphate-buffered aqueous solution containing[Ru(bpy)₃]²⁺-Na₂S₂O₈ and calcium(Ⅱ) triflate salt, exhibiting greatly enhanced water oxidation performance with optimized turnover frequency of 0.18 mmol_O2 mol_Mn^-1 s^-1. Different analytical techniques indicated that photodeposited calcium-phosphate (CaP) acted as a co-catalyst to promote the O₂evolution activity of ZMO. This system involved the use of manganese oxide and calcium ion, and the operation was conducted under ambient temperature and neutral conditions, thus, it efficiently mimicked the oxygen-evolving complex in photosystem Ⅱ.
- Zinc manganese oxide,
- Brushite,
- Metal-organic frameworks,
- Water oxidation,
- Oxygen-evolving complex
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
1. [1]
  Bizhu Shao , Huijun Dong , Yunnan Gong , Jianhua Mei , Fengshi Cai , Jinbiao Liu , Dichang Zhong , Tongbu Lu . Metal-Organic Framework-Derived Nickel Nanoparticles for Efficient CO₂ Electroreduction in Wide Potential Windows. Acta Physico-Chimica Sinica, 2024, 40(4): 2305026-0. doi: 10.3866/PKU.WHXB202305026
2. [2]
  Anqun LAI , Qiaoyu WU , Qingqing LIANG , Qiyong LI , Guowen DONG , Yongjie DING , Jia′nan CHEN , Qing YAN , Zhonghua PAN , Wangchuan XIAO . Electrocatalytic water oxidation properties of Nd-Co polynuclear complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2527-2535. doi: 10.11862/CJIC.20250151
3. [3]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
4. [4]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-0. doi: 10.3866/PKU.WHXB202408012
5. [5]
  Bin XU , Shufeng ZHANG , Feifan LANG , Chunyan NI , Bing WU , Jianping LANG . Photoreactive pyrene-based Zn?? metal-organic frameworks: Solid-state [2+2] cycloaddition and tunable luminescence. Chinese Journal of Inorganic Chemistry, 2026, 42(10): 2119-2126. doi: 10.11862/CJIC.20260140
6. [6]
  Ruige ZHANG , Zhe ZHANG , He ZHENG , Zhan SHI . Recent advances of metal-organic frameworks for alkaline electrocatalytic oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2011-2028. doi: 10.11862/CJIC.20250185
7. [7]
  Xiaogang YANG , Xinya ZHANG , Jing LI , Huilin WANG , Min LI , Xiaotian WEI , Xinci WU , Lufang MA . Synthesis, structure, and photoelectric properties of Zinc(Ⅱ)-triphenylamine based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2078-2086. doi: 10.11862/CJIC.20250167
8. [8]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
9. [9]
  Bo YAN , Wenjuan JI , Lu XU , Wenzhuang LEI , Haiying YANG , Yunlong FU . Highly sensitive electrochemical detection for 4-aminophenol based on pore-confined nitrogen-rich tetranuclear cobalt-oxo cluster metal-organic framework. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1175-1189. doi: 10.11862/CJIC.20250375
10. [10]
  Yinjie Xu , Suiqin Li , Lihao Liu , Jiahui He , Kai Li , Mengxin Wang , Shuying Zhao , Chun Li , Zhengbin Zhang , Xing Zhong , Jianguo Wang . Enhanced Electrocatalytic Oxidation of Sterols using the Synergistic Effect of NiFe-MOF and Aminoxyl Radicals. Acta Physico-Chimica Sinica, 2024, 40(3): 2305012-0. doi: 10.3866/PKU.WHXB202305012
11. [11]
  Yukai SHEN , Zhaochao YAN , Yangjun ZHOU , Mei HUANG . Nickel foam-supported NiFeP/NiFcDCA heterojunction electrocatalyst for efficient urea oxidation reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 237-246. doi: 10.11862/CJIC.20250257
12. [12]
  Enqi CHEN , Xinyi MA , Xiang HAN , Yutong YE , Kexin QIN , Shenghui LI , Changli ZHANG , Min YU , Changyun CHEN . Research progress on MOF-based electrocatalysts for the urea oxidation reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(9): 1871-1892. doi: 10.11862/CJIC.20260168
13. [13]
  Ping LI , Geng TAN , Xin HUANG , Fuxing SUN , Jiangtao JIA , Guangshan ZHU , Jia LIU , Jiyang LI . Green synthesis of metal-organic frameworks with open metal sites for efficient ammonia capture. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2063-2068. doi: 10.11862/CJIC.20250020
14. [14]
  Ri Peng , Yuxin Xie , Shuai Yuan , Ruwei Shen , Dunru Zhu . Metal-Organic Frameworks (2014-2024): A decade pursuit for top performance. Acta Physico-Chimica Sinica, 2026, 42(7): 100225-. doi: 10.1016/j.actphy.2025.100225
15. [15]
  Qiuxiang FANG , Xinyue CHEN , Yuyang GUO , Penghui XIE , Pengbiao GENG . Application of metal-organic framework derived materials in lithium-sulfur battery separators. Chinese Journal of Inorganic Chemistry, 2026, 42(9): 1910-1932. doi: 10.11862/CJIC.20260188
16. [16]
  Wen WANG , Ying XU , Gang XIONG , Lixin YOU , Yaguang SUN . Pd-NHC-functionalized La-metal-organic framework for efficient Suzuki-Miyaura cross-coupling reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1475-1484. doi: 10.11862/CJIC.20260025
17. [17]
  Yifang ZHANG , Zifeng SHAO , Hexuan JIN , Lijuan YANG , Runlong HAO , Jianfeng WANG , Ning LIU . Research progress in the application of metal-organic frameworks in electrocatalytic urea synthesis. Chinese Journal of Inorganic Chemistry, 2026, 42(10): 2051-2062. doi: 10.11862/CJIC.20260204
18. [18]
  Xiaobao LI , Chengjun ZHANG , Linzhi HUANG , Limei CHANG , Zhigang GU . Metal-organic frameworks as second-order nonlinear optical materials. Chinese Journal of Inorganic Chemistry, 2026, 42(11): 2311-2325. doi: 10.11862/CJIC.20260196
19. [19]
  Wenhao HUANG , Mingming XU , Peng CHENG , Wei SHI . Influence of metal center regulation in metal-organic frameworks on the sensing performance and sensing mechanism of perfluoroalkyl substances. Chinese Journal of Inorganic Chemistry, 2026, 42(11): 2353-2361. doi: 10.11862/CJIC.20260137
20. [20]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1331)
HTML views(109)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142