Citation: Jinhui Hao, Weidong Shi. Transition metal (Mo, Fe, Co, and Ni)-based catalysts for electrochemical CO₂ reduction[J]. Chinese Journal of Catalysis, ;2018, 39(7): 1157-1166. doi: 10.1016/S1872-2067(18)63073-6 shu

Transition metal (Mo, Fe, Co, and Ni)-based catalysts for electrochemical CO₂ reduction

Jinhui Hao ,
Weidong Shi

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu, China

Received Date: 22 February 2018
Revised Date: 7 April 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (21477050, 21522603, 21706101), the Henry Fok Education Founda-tion (141068), Six Talents Peak Project in Jiangsu Province (XCL-025), and the Chinese-German Cooperation Research Project (GZ1091), the China Postdoctoral Foundation (2017M611731).

The electrochemical conversion of CO₂ into value-added chemicals and fuels has attracted widespread concern since it realizes the recycling of greenhouse gases. Production of new materials lies at the very core of this technology as it enables the improvement of developmental efficiency and selectivity by chemical optimization of morphology and electronic structure. Transition metal-based catalysts are particularly appealing as their d bands have valence electrons which are close to the Fermi level and hence overcome the intrinsic activation barriers and reaction kinetics. The study of Mo, Fe, Co, and Ni-based materials in particular is a very recent research subject that offers various possibilities in electrochemical CO₂ reduction applications. Herein, we summarize the recent research progress of Mo, Fe, Co, and Ni-based catalysts and their catalytic behavior in electrochemical CO₂ reduction. We particularly focus on the relationship between structures and properties, with examples of the key features accounting for the high efficiency and selectivity of the CO₂ reduction process. The most significant experimental and theoretical improvements are highlighted. Finally, we concisely discuss the scientific challenges and opportunities for transition metal-based catalysts.
- Transition metal,
- Energy conversion,
- Electrocatalytic,
- CO₂
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Transition metal (Mo, Fe, Co, and Ni)-based catalysts for electrochemical CO₂ reduction