Citation: Xiaobo He, Fengxiang Yin, Hao Wang, Biaohua Chen, Guoru Li. Metal-organic frameworks for highly efficient oxygen electrocatalysis[J]. Chinese Journal of Catalysis, ;2018, 39(2): 207-227. doi: 10.1016/S1872-2067(18)63017-7 shu

Metal-organic frameworks for highly efficient oxygen electrocatalysis

Xiaobo He ^a,b,e, ,
Fengxiang Yin ^a,b,c,d,e ,
Hao Wang ^a,c ,
Biaohua Chen ^c ,
Guoru Li ^a,b,e

a State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;
b Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University, Changzhou 213164, Jiangsu, China;
c College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
d Beijing Key Laboratory of Energy Environmental Catalysis, Beijing 100029, China;
e Changzhou Institute of Advanced Materials, Beijing University of Chemical Technology, Changzhou 213164, Jiangsu, China

Received Date: 30 October 2017
Revised Date: 26 December 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (21706010), the Natural Science Foundation of Jiangsu Province of China (BK20161200), the Fundamental Research Funds for the Central Universities (buctrc201526 and PYCC1706), the Changzhou Sci & Tech Program (CJ20160007), the support from Advanced Catalysis and Green Manufacturing Collaborative Innovation Center and Changzhou University (ACGM2016-06-02 and ACGM2016-06-03).

Metal-organic frameworks (MOFs) are a series of highly porous crystalline materials, which are built from inorganic metal nodes and organic linkers through coordination bonds. Their unique porous structural features (such as high porosity, high surface areas, and highly ordered nanoporous structures) and designable structures and compositions have facilitated their use in gas capture, separation, catalysis, and energy storage and conversion. Recently, the design and synthesis of pure MOFs and their derivatives have opened new routes to develop highly efficient electrocatalysts toward oxygen reduction reactions (ORR) and oxygen evolution reactions (OER), which are the core electrode reactions in many energy storage and conversion techniques, such as metal-air batteries and fuel cells. This review first discusses recent progress in the synthesis and the electrocatalytic applications of pure MOF-based electrocatalysts toward ORR or OER, including pure MOFs, MOFs decorated with active species, and MOFs incorporated with conductive materials. The following section focuses on the advancements of the design and preparation of various MOF-derived materials-such as inorganic nano-(or micro-) structures/porous carbon composites, pure porous carbons, pure inorganic nano-(or micro-) structured materials, and single-atom electrocatalysts-and their applications in oxygen electrocatalysis. Finally, we present a conclusion and an outlook for some general design strategies and future research directions of MOF-based oxygen electrocatalysts.
- Metal-organic frameworks,
- Porous materials,
- Electrocatalysis,
- Oxygen reduction reaction,
- Oxygen evolution reaction,
- Energy storage and conversion
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