Citation: Dongdong Yin, Hangxing Ren, Chuang Li, Jinxuan Liu, Changhai Liang. Highly selective hydrogenation of furfural to tetrahydrofurfuryl alcohol over MIL-101(Cr)-NH₂ supported Pd catalyst at low temperature[J]. Chinese Journal of Catalysis, ;2018, 39(2): 319-326. doi: 10.1016/S1872-2067(18)63009-8 shu

Highly selective hydrogenation of furfural to tetrahydrofurfuryl alcohol over MIL-101(Cr)-NH₂ supported Pd catalyst at low temperature

a Laboratory of Advanced Materials and Catalytic Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China;
b Purification Equipment Research Institute of CSIC, Handan 056027, Hebei, China;
c State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, Dalian University of Technology, Dalian 116024, Liaoning, China

Received Date: 10 November 2017
Revised Date: 26 December 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (21573031, 21673032), Program for Excellent Talents in Dalian City (2016RD09), the Fundamental Research Funds for the Central Universities (DUT17LK21), the State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University (201507).

An efficient heterogeneous catalyst, Pd@MIL-101(Cr)-NH₂, is prepared through a direct pathway of anionic exchange followed by hydrogen reduction with amino-containing MIL-101 as the host matrix. The composite is thermally stable up to 350℃ and the Pd nanoparticles uniformly disperse on the matal organic framework (MOF) support, which are attributed to the presence of the amino groups in the frameworks of MIL-101(Cr)-NH₂. The selective hydrogenation of biomass-based furfural to tetrahydrofurfuryl alcohol is investigated by using this multifunctional catalyst Pd@MIL-101(Cr)-NH₂ in water media. A complete hydrogenation of furfural is achieved at a low temperature of 40℃ with the selectivity of tetrahydrofurfuryl alcohol close to 100%. The amine-functionalized MOF improves the hydrogen bonding interactions between the intermediate furfuryl alcohol and the support, which is conducive for the further hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol in good coor-dination with the metal sites.
- Metal-organic frameworks,
- Amino functionalization,
- Pd nanoparticle,
- Biomass,
- Selective hydrogenation
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Highly selective hydrogenation of furfural to tetrahydrofurfuryl alcohol over MIL-101(Cr)-NH2 supported Pd catalyst at low temperature

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Highly selective hydrogenation of furfural to tetrahydrofurfuryl alcohol over MIL-101(Cr)-NH₂ supported Pd catalyst at low temperature