Citation: Song Song, Dong Wang, Lu Di, Chuanming Wang, Weili Dai, Guangjun Wu, Naijia Guan, Landong Li. Robust cobalt oxide catalysts for controllable hydrogenation of carboxylic acids to alcohols[J]. Chinese Journal of Catalysis, ;2018, 39(2): 250-257. doi: 10.1016/S1872-2067(17)63003-1 shu

Robust cobalt oxide catalysts for controllable hydrogenation of carboxylic acids to alcohols

Song Song ^a, ,
Dong Wang ^c ,
Lu Di ^a ,
Chuanming Wang ^c ,
Weili Dai ^a ,
Guangjun Wu ^a ,
Naijia Guan ^a,b ,
Landong Li ^a,b

a School of Materials Science and Engineering & National Institute for Advanced Materials, Nankai University, Tianjin 300350, China;
b Key Laboratory of Advanced Energy Materials Chemistry of Ministry of Education, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, Tianjin 300071, China;
c SINOPEC, Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, China

Received Date: 6 October 2017
Revised Date: 21 November 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (21421001, 21573113) and Sinopec Corp.

The selective catalytic hydrogenation of carboxylic acids is an important process for alcohol production, while efficient heterogeneous catalyst systems are still being explored. Here, we report the selective hydrogenation of carboxylic acids using earth-abundant cobalt oxides through a reaction-controlled catalysis process. The further reaction of the alcohols is completely hindered by the presence of carboxylic acids in the reaction system. The partial reduction of cobalt oxides by hydrogen at designated temperatures can dramatically enhance the catalytic activity of pristine samples. A wide range of carboxylic acids with a variety of functional groups can be converted to the corresponding alcohols at a yield level applicable to large-scale production. Cobalt monoxide was established as the preferred active phase for the selective hydrogenation of carboxylic acids.
- Selective hydrogenation,
- Carboxylic acids,
- Alcohols,
- Cobalt oxides,
- Reaction-controlled catalysis
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