Citation: Kai Fan, Zhiliang Jin, Hong Yuan, Hongyan Hu, Yingpubi. Construction of CuO-modified zeolitic imidazolate framework-9 for photocatalytic hydrogen evolution[J]. Chinese Journal of Catalysis, ;2017, 38(12): 2056-2066. doi: 10.1016/S1872-2067(17)62969-3 shu

Construction of CuO-modified zeolitic imidazolate framework-9 for photocatalytic hydrogen evolution

Kai Fan ^a, ,
Zhiliang Jin ^a ,
Hong Yuan ^a ,
Hongyan Hu ^b ,
Yingpubi ^b

a School of Chemistry and Chemical Engineering, North Minzu University, Yinchuan 750021, Ningxia, China;
b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, China

Received Date: 1 October 2017
Revised Date: 31 October 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (21433007, 21603274, 41663012) and the Ningxia Low-Grade Resource High Value Utilization and Environmental Chemical Integration Technology Innovation Team Project, North Minzu University.

An efficient CuO-modified zeolitic imidazolate framework-9 (ZIF-9) photocatalyst is successfully prepared at room temperature under mild conditions. It is observed that the ZIF-9/CuO photocatalyst is effective for H₂ generation under visible light with sacrificial agent conditions. When the CuO is introduced, the photocatalytic properties of ZIF-9 are greatly improved and when the content of CuO is 40%, the photocatalytic activity reaches a maximum of 78.74 μmol after 5 h. This results from the 200-300 nm cube structure of ZIF-9 being able to adsorb more dye molecules and the CuO, which connects with ZIF-9, greatly improving the electronic transmission efficiency. Moreover, the interaction between the dye molecule Eosin Y (EY) and the catalyst is also studied by transient fluorescence spectroscopy. A series of characterizations, such as SEM, TEM, XPS, XRD, UV-vis, FTIR, transient fluorescence and photocurrent, are conducted, and the results are in good agreement with the experimental result. In addition, the possible reaction mechanism over EY-sensitized ZIF-9/CuO under visible light irradiation is proposed.
- ZIF-9,
- CuO,
- Eosin Y,
- Sensitized pathway,
- Hydrogen evolution,
- Reaction optimization
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
51. [51]
52. [52]
53. [53]
54. [54]
55. [55]
1. [1]
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