Citation: Bing Zhang, Danping Hui, Yingxuan Li, He Zhao, Chuanyi Wang. Synthesis and photocatalytic hydrogen production activity of the Ni-CH₃CH₂NH₂/H_1.78Sr_0.78Bi_0.22Nb₂O₇ hybrid layered perovskite[J]. Chinese Journal of Catalysis, ;2017, 38(12): 2039-2047. doi: 10.1016/S1872-2067(17)62953-X shu

Synthesis and photocatalytic hydrogen production activity of the Ni-CH₃CH₂NH₂/H_1.78Sr_0.78Bi_0.22Nb₂O₇ hybrid layered perovskite

Bing Zhang ^a,c, ,
Danping Hui ^b ,
Yingxuan Li ^a,b ,
He Zhao ^a,c ,
Chuanyi Wang ^a,b

a Laboratory of Environmental Sciences and Technology, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, Urumqi 830011, Xinjiang, China;
b School of Environmental Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, Shanxi, China;
c University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 21 September 2017
Revised Date: 30 October 2017

Fund Project: This work was supported by the National Natural Science Foundation of China (U1403193, 21643012).

The nickel-based complex Ni-CH₃CH₂NH₂-intercalated niobate layered perovskite Ni-CH₃CH₂NH₂/H_1.78Sr_0.78Bi_0.22Nb₂O₇ was synthesized via a facile in situ chemical reaction method. Using ultrathin H_1.78Sr_0.78Bi_0.22Nb₂O₇ nanosheets and nickel acetate as precursors. The composition, structure, photophysical properties, and photocatalytic activity for H₂ production of Ni-CH₃CH₂NH₂/H_1.78Sr_0.78Bi_0.22Nb₂O₇ were studied systematically. The photocatalyst loaded with 0.5 wt% Ni exhibited the highest H₂ evolution rate of 372.67 μmo/h. This was 0.54 times higher than the activity of the H_1.78Sr_0.78Bi_0.22Nb₂O₇ nanosheets. The activity of the optimized Ni-CH₃CH₂NH₂/H_1.78Sr_0.78Bi_0.22Nb₂O₇ was comparable to that of the Pt-loaded sample under the same reaction conditions. The photocatalytic activity of the Ni-CH₃CH₂NH₂/H_1.78Sr_0.78Bi_0.22Nb₂O₇ was mainly attributed to the excellent separation of photogenerated carriers, after formation of the intercalated complex Ni-CH₃CH₂NH₂. This study provides a facile strategy to synthesize a non-precious metal-loaded photocatalyst for H₂ production.
- Ni-CH₃CH₂NH₂/H_1.78Sr_0.78Bi_0.22Nb₂O₇,
- Intercalation,
- Photocatalysis,
- Hydrogen evolution,
- Nanosheets
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Synthesis and photocatalytic hydrogen production activity of the Ni-CH3CH2NH2/H1.78Sr0.78Bi0.22Nb2O7 hybrid layered perovskite

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通讯作者: 陈斌, bchen63@163.com

Synthesis and photocatalytic hydrogen production activity of the Ni-CH₃CH₂NH₂/H_1.78Sr_0.78Bi_0.22Nb₂O₇ hybrid layered perovskite