Citation: Ting Wang, Si Chen, Haiqiang Wang, Zhen Liu, Zhongbiao Wu. In-plasma catalytic degradation of toluene over different MnO₂ polymorphs and study of reaction mechanism[J]. Chinese Journal of Catalysis, ;2017, 38(5): 793-804. doi: 10.1016/S1872-2067(17)62808-0 shu

In-plasma catalytic degradation of toluene over different MnO₂ polymorphs and study of reaction mechanism

Ting Wang ^a,b, ,
Si Chen ^a,b ,
Haiqiang Wang ^a,b ,
Zhen Liu ^c ,
Zhongbiao Wu ^a,b

a. Key Laboratory of Environment Remediation and Ecological Health of Ministry of Education, College of Environmental & Resources Sciences, Zhejiang University, Hangzhou 310058, Zhejiang, China;
b. Zhejiang Provincial Engineering Research Center of Industrial Boiler & Furnace Flue Gas Pollution Control, Hangzhou 310027, Zhejiang, China;
c. Institute of Industrial Ecology and Environment, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310007, Zhejiang, China

Received Date: 21 January 2017
Revised Date: 4 March 2017

Fund Project: This work was supported by the National Key Research and Development Plan of China (2016YFC0204700), Zhejiang Provincial “151” Talents Program (2013), Key Project of Zhejiang Provincial Science and Technology Program, the Program for Zhejiang Leading Team of S&

α-, β-, γ- and δ-MnO₂ catalysts were synthesized by a one-step hydrothermal method, and were utilized for the catalytic oxidation of toluene in a combined plasma-catalytic process. The relationship between catalytic performance and MnO₂ crystal structures was investigated. It was noted that the toluene removal efficiency was 32.5% at the specific input energy of 160 J/L when non-thermal plasma was used alone. The α-MnO₂ catalyst showed the best activity among the investigated catalysts, yielding a toluene conversion of 78.1% at the specific input energy of 160 J/L. For β-MnO₂, γ-MnO₂ and δ-MnO₂, removal efficiencies of 47.4%, 66.1% and 50.0%, respectively, were achieved. By powder X-ray diffraction, Raman spectroscopy, transmission electron microscopy, scanning electron microscopy, Brunauer-Emmett-Teller, H₂ temperature-programmed reduction and X-ray photoelectron spectroscopy analyses, it was concluded that the tunnel structure, the stability of the crystal in plasma, the Mn–O bond strength of MnO₂and the surface-chemisorbed oxygen species played important roles in the plasma-catalytic degradation of toluene. Additionally, the degradation routes of toluene in non-thermal plasma and in the plasma-catalytic process were also studied. It was concluded that the introduction of MnO₂ catalysts enabled O₃, O₂, electrons and radical species in the gas to be adsorbed on the MnO₂ surface via a facile interconversion among the Mn⁴⁺, Mn³⁺and Mn²⁺states. These four species could then be transported to the toluene or intermediate organic by-products, which greatly improved the toluene removal efficiency and decreased the final output of by-products.
- Toluene,
- Catalytic oxidation,
- Non-thermal plasma,
- MnO₂,
- Crystal structure
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In-plasma catalytic degradation of toluene over different MnO2 polymorphs and study of reaction mechanism

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In-plasma catalytic degradation of toluene over different MnO₂ polymorphs and study of reaction mechanism