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Citation: Tao Wang, Wenlong Wang, Yuan Lyu, Kai Xiong, Cunyao Li, Hao Zhang, Zhuangping Zhan, Zheng Jiang, Yunjie Ding. Porous Rh/BINAP polymers as efficient heterogeneous catalysts for asymmetric hydroformylation of styrene: Enhanced enantioselectivity realized by flexible chiral nanopockets[J]. Chinese Journal of Catalysis, ;2017, 38(4): 691-698. doi: 10.1016/S1872-2067(17)62790-6 shu

Porous Rh/BINAP polymers as efficient heterogeneous catalysts for asymmetric hydroformylation of styrene: Enhanced enantioselectivity realized by flexible chiral nanopockets

Tao Wang ^a,b, ,
Wenlong Wang ^a ,
Yuan Lyu ^a, ,
Kai Xiong ^c ,
Cunyao Li ^a,b ,
Hao Zhang ^d ,
Zhuangping Zhan ^c ,
Zheng Jiang ^d ,
Yunjie Ding ^a

a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China;
c Department of Chemistry, Xiamen University, Xiamen 361005, Fujian, China;
d Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201204, China

Received Date: 15 December 2016
Revised Date: 15 January 2017

Fund Project: This work was supported by the Strategic priority Research Program of the Chinese Academy of Sciences (XDB17020400).

A new chiral monomer, (S)-5,5'-divinyl-BINAP, was successfully synthesized and embedded into two different porous organic polymers (Poly-1 and Poly-2). After loading a Rh species, the catalysts were applied for the heterogeneous asymmetric hydroformylation of styrene. Compared with the homogeneous BINAP analogue, the enantioselectivity of Rh/Poly-1 catalyst was drastically increased by approximately 70%. The improved enantioselectivity of the porous Rh/BINAP polymers was attributed to the presence of flexible chiral nanopockets resulting from the increased bulk of the R groups near the catalytic center.
- Porous organic polymer,
- Heterogeneous catalysis,
- Asymmetric hydroformylation,
- Enhanced enatioselectivity,
- Chiral nanopocket
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