Citation: Haipeng Fan, Zhengliang Qi, Dejun Sui, Fei Mao, Rizhi Chen, Jun Huang. Palladium nanoparticles in cross-linked polyaniline as highly efficient catalysts for Suzuki-Miyaura reactions[J]. Chinese Journal of Catalysis, ;2017, 38(3): 589-596. doi: 10.1016/S1872-2067(17)62772-4 shu

Palladium nanoparticles in cross-linked polyaniline as highly efficient catalysts for Suzuki-Miyaura reactions

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, Jiangsu, China

Received Date: 29 November 2016
Revised Date: 27 December 2016

Fund Project: This work was supported by the National Natural Science of Foundation of China (21676140), the fund from the State Key Laboratory of Materials-Oriented Chemical Engineering (ZK201402) and the Project of Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions.

Palladium nanoparticles supported on cross-linked polyaniline with bulky phosphorus ligands were developed. These catalysts showed high efficiency in the Suzuki-Miyaura reaction of aryl chlorides and bromides with phenylboronic acids. Aryl chlorides and bromides with functional groups, such as CN, MeO, CHO, MeCO and NO₂, were converted to the corresponding biphenyls in high yields with catalyst loading. Additionally, the catalysts combined high activity with good reusability; they could be used at least five times for the Suzuki-Miyaura coupling reaction.
- Palladium,
- Heterogeneous catalyst,
- Polyaniline,
- Suzuki-Miyaura coupling reactions,
- Biphenyls
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